Material flow and environmental performance of the source segregated biowaste composting system.

Life cycle assessment (LCA) is performed to investigate the environmental impacts of two alternative approaches in a biowaste management system. The system inventory is based on actual data and on-site sampling for two consecutive years at the mechanical and biological treatment (MBT) facility at the prefecture of Chania (Greece). The facility pertains as MBT for household waste and material recycling (MR) for the recyclable fractions in two different process lines. The mass balances and environmental performance are assessed from waste generation to end-use. The LCA and ReCiPe 2016 methodology estimate the endpoint environmental impacts on human health, ecosystem quality and resource scarcity. The results show that biowaste source segregation in an integrated waste management system not only significantly benefits its recoverability potential it also improves its environmental performance. Impacts on human health (HH) have reduced by 4.6 times, on freshwater ecosystem quality (EQf) by 6.3 times and resource scarcity (RS) usage by 2.5 times when biowaste is combined with compost production and use, material recovery and reprocessing for fertilizer and raw material substitution.

Valorisation of soil contaminated by petroleum hydrocarbons and toxic metals in geopolymer mortar formation.

Until the complete transition to a renewable energy sources based economy, the potential environmental hazards associated with petroleum refinery industries affecting water, air and soil seek sustainable solutions. In the present study contaminated soil from a refinery is used as an alternative source for producing useful building materials by geopolymerization. To this end, soil remediation by thermal desorption was initially applied. Thermal treatment was performed between 60 and 250 °C for short time intervals (10-30 min) in order to remove organic pollutants (Total Petroleum Hydrocarbons, TPHs and Polycyclic Aromatic Hydrocarbons, PAHs). Physical, chemical analyses, mineral phase composition, as well as thermogravimetric analysis were employed to characterize the sample. Moreover, removal efficiency of TPHs and PAHs was evaluated. Subsequently, the treated soil presenting the maximum elimination of TPH and PAHs was used in geopolymer mortar formation aiming to stabilize the toxic metals (TMs) and produce a possible profitable material. For geopolymer synthesis the substitution of metakaolin (MT) by treated soil at 0, 50, 70 and 100% was tested. The produced specimens were evaluated based on the 28 day compressive strength and metals leaching. Results showed that the geopolymer constructed by 50% MT-50% remediated soil at 250 °C for 30 min, had negligible content of organic pollutants, TMs were immobilized and exhibited increased strength thus giving significant recycling benefits. Valorisation of industrial residues to produce building materials is a promising solution for sustainable waste management.

The degree and source of plastic recyclates contamination with polycyclic aromatic hydrocarbons.

In this research, the degree and source of recyclates contamination with polycyclic aromatic hydrocarbons (PAH) was studied in eight different polyolefin recyclate samples; four originating from post-consumer packaging waste and four originating from a mixed source (post-industrial, post-commercial, and post-consumer). The aim was to assess the applicability of these recyclates in the different products' categories. Furthermore, the impact of previous contamination with PAH was excluded by analysing pure plastics before and after undergoing simulated recycling processes. Polythene recyclates originating from post-consumer plastic packaging waste had lower concentrations of the 16-US-EPA PAH (922.15 ± 420.75 µg kg-1) in comparison to the ones of a mixed origin (2155.43 ± 991.85 µg kg-1), r = -0.35, p > 0.05. The degree of recyclates contamination with PAH was always within the REACH limits for consumer products (<1.0 mg kg-1). On the other hand, only polythene recyclate sample originating from post-commercial waste did not comply with the REACH limits for children articles (0.5 mg kg-1). Hence, the source of plastic waste defines the quality of recyclates. All in all, the results indicated that the contamination of polyolefin recyclates with PAH is attributed to the material's previous contamination, or the sorption of plastics to organic compounds from the surrounding environment. Exposing plastics containing PAH additives to heat during extrusion could result in further accumulation of PAH in plastics.

Assessment of tetrabromobisphenol-A (TBBPA) content in plastic waste recovered from WEEE.

Due to the variability of additives and polymer types used in electrical and electronic equipment (EEE), and in accordance with the European Directive 2012/19/EU, an implementation of sound management practices is necessary. This work focuses on assessing the content of tetrabromobisphenol-A (TBBPA) in acrylonitrile-butadiene-styrene (ABS), polypropylene (PP), polycarbonate (PC) and their polymer blends (i.e. PC/ABS). A total of 36 plastic housing samples originating from microwave ovens, electric irons, vacuum cleaners and DVD/CD players were subjected to microwave-assisted-extraction (MAE) and/or ultrasound-assisted-extraction (UAE). Maximum mean concentration values of TBBPA measured in DVD/CD players and vacuum cleaners ranged between 754-1146 µg/kg, and varied per polymer type, as follows: 510-2515 µg/kg in ABS and 55-3109 µg/kg in PP. The results indicated that MAE was more sufficient than UAE in the extraction of TBBPA from ABS. To optimize the UAE procedure, various solvents were tested. Higher amounts of TBBPA were obtained from ABS and PP using a binary mixture of a polar-non-polar solvent, isopropanol:n-hexane (1:1), whereas the sole use of isopropanol exhibited incomplete extraction.

Use and assessment of "e-plastics" as recycled aggregates in cement mortar.

In this study we investigated the physical and mechanical properties of cement mortars, partially replaced with plastic (recycled plastic aggregate, RPA) recovered from WEEE (namely, "e-plastics"). The plastic housing of 14 LCD screens was sampled and, subsequently, compositionally and elementally analysed. Acrylonitrile-butadiene-styrene (ABS), being the most commonly found polymer in WEEE, was used as aggregate in the cement mortar. The replacement percentages (RPs) used were 2.5%, 5%, 7.5%, 10% and 12.5%, while the water to cement (w/c) ratio was maintained constant at 0.5 in all tests. The basic properties (e.g. compressive strength (CS), modulus of elasticity (MoE), density (ρ), porosity (Φ) and water absorption (WA)) of the created specimens were investigated. The obtained results, for all RPs, (especially those of 7.5% and 10%) exhibited an increase in the CS of the specimens by 15.4% and 7.8%, respectively, with the MoE decreased in both cases by 18.1% and 23.8%, respectively. The rest of the examined specimens' physical properties measured (ρ, Φ, and WA) indicated, also, greater strength but lower ductility than the reference (standard) specimen. Concluding, the use of recovered plastics from WEEE as recycled aggregates (RAs) in cement could potentially be proved a useful downcycling alternative for waste plastics.

Evaluation and comparison of pre-treatment techniques for recovering indium from discarded liquid crystal displays.

Over the last years, emerging incentives for secondary production of high tech-metals, found in e-waste, are created because of their increasing demand and economic issues associated with their primary production. Due to the very low share of these metals in e-waste, pre-treatment methods can result in an output fraction rich in the metals of interest and may, therefore, be essential. To this scope, the present article evaluates and compares the efficiency of four different pre-treatment approaches containing various steps for recovering indium (In) from liquid crystal displays (LCDs) in laptop computers. The pre-treatment steps, used in various combinations, are (a) dry mechanical crushing and sieving, (b) pyrolysis, (c) thermal shock and (d) gravimetric process. Also, in all approaches, liquid crystals were removed from the samples, before applying the mechanical crushing step, as these are toxic and potentially harmful to human health and the environment. The removal was achieved by ultrasonic irradiation or mild agitation and optimized in terms of time, temperature and solvent type and concentration. Then, the feasibility of each pre-treatment approach was evaluated based on two parameters: (a) the content of In in the resulting sample after pre-treatment and (b) the separated mass share (%) with larger indium content as compared to the original LCD panel. The results showed that In is highly liberated in the fractions consisting of finest particles (<25 µm and <53 µm) after dry mechanical crushing and sieving with a maximum content of 234 mg/kg, which is twice as much as in the raw material. However, these particles represented only about 14 wt% of the original LCD panel mass. On the contrary, thermal shock results indicated that this was the most efficient pre-treatment approach, as both the content of In and the separated LCD mass (%) remained in high levels. Finally, some economic aspects associated with the processes are presented.

Energy efficient production of glass-ceramics using photovoltaic (P/V) glass and lignite fly ash.

This study investigates an innovative approach for the valorization of specific wastes generated from the energy sector and the production of glass-ceramics. The wastes used were photovoltaic (P/V) glass, produced from the renewable energy sector, and lignite fly ash, produced from the conventional energy sector. The process first involved the production of glass after melting specific mixtures of wastes, namely (i) 70% P/V glass and 30% lignite fly ash, and (ii) 80% P/V glass and 20% lignite fly ash, at 1200 °C for 1 h as revealed by the use of a heating microscope. The results indicated that the P/V glass, as a sodium-potassium-rich inorganic waste, reduces energy requirements of the melting process. The produced glass was then used for the production of glass-ceramics. Dense and homogeneous glass-ceramics, exhibiting high chemical stability and no toxicity, were produced after controlled thermal treatment of glass at 800 °C. The mechanical (compressive strength, Vickers hardness) and physical (open porosity, bulk density and water absorption) properties of the produced glass-ceramics were evaluated. X-ray diffraction (XRD) and Energy Dispersive X-ray fluorescence (ED-XRF) were used for the characterization of the raw materials and the produced glass-ceramics. Scanning electron microscopy (SEM) provided further insights on the microstructure of the final products. The properties of the produced glass-ceramics, namely water absorption and compressive strength, render them suitable for applications in the construction industry. The waste valorization approach followed in this study is in line with the principles of circular economy.

Slaughterhouse by-products treatment using anaerobic digestion.

The objective of the present study is to evaluate the use of animal by-products (ABP) as substrates for anaerobic digestion, aiming at methane production. Specifically, four ABP of Category 2 and 3, namely (i) stomach and rumen, (ii) stomach contents, (iii) breasts and reproductive organs and (iv) bladders and intestines with their contents, were selected. The methane potential of each ABP was initially determined, while the feasibility of anaerobic co-digestion of ABP with two agroindustrial waste, i.e. orange peels and olive leaves was also studied. To this purpose, Biochemical Methane Potential (BMP), as well as semi-continuous assays were respectively conducted. In the latter, the effect of the variation in the organic loading rate (OLR) on methane production was investigated. Results obtained from BMP assays showed that the samples containing breasts and reproductive organs, bladders and intestine, and stomach and rumen, had higher methane potentials of 815, 787 and 759 mLCH4,STP/gVS, respectively. Moreover, according to the results of the semi-continuous assays, maximum methane yields between 253 and 727mLCH4/gVSfed were obtained at an OLR of 0.8gVS/L/d. The only case in which methanogenesis inhibition phenomena, due to increased ammonia concentrations, were observed, was the assay being fed with a mixture of breasts and reproductive organs and orange peels, at the highest OLR. This inhibition phenomenon was attributed to an inappropriate C/N ratio.

Chemical pretreatment of lignocellulosic agroindustrial waste for methane production.

This study investigates the effect of different chemical pretreatments on the solubilization and the degradability of different solid agroindustrial waste, namely winery waste, cotton gin waste, olive pomace and juice industry waste. Eight different reagents were investigated, i.e. sodium hydroxide (NaOH), sodium bicarbonate (NaHCO3), sodium chloride (NaCl), citric acid (H3Cit), acetic acid (AcOH), hydrogen peroxide (H2O2), acetone (Me2CO) and ethanol (EtOH), under three condition sets resulting in treatments of varying intensity, depending on process duration, reagent dosage and temperature. Results indicated that chemical pretreatment under more severe conditions is more effective on the solubilization of lignocellulosic substrates, such as those of the present study and among the investigated reagents, H3Cit, H2O2 and EtOH appeared to be the most effective to this regard. At the same time, although chemical pretreatment in general did not improve the methane potential of the substrates, moderate to high severity conditions were found to generally be the most satisfactory in terms of methane production from pretreated materials. In fact, moderate severity treatments using EtOH for winery waste, H3Cit for olive pomace and H2O2 for juice industry waste and a high severity treatment with EtOH for cotton gin waste, resulted in maximum specific methane yield values. Ultimately, the impact of pretreatment parameters on the different substrates seems to be dependent on their characteristics, in combination with the specific mode of action of each reagent. The overall energy balance of such a system could probably be improved by using lower operating powers and higher solid to liquid ratios.

Anaerobic digestion of solid agroindustrial waste in semi-continuous mode: Evaluation of mono-digestion and co-digestion systems.

The present study aimed at investigating the anaerobic digestion of four agroindustrial waste, namely cotton gin waste, winery waste, olive pomace and juice industry waste, in semi-continuous mode, conducting mono-digestion and co-digestion assays, using an artificial organic fraction sample as co-substrate. These assays were divided into two groups, in which different conditions were applied. Group I investigated the variation in two operational parameters, i.e. the organic loading rate (OLR) and the hydraulic retention time (HRT), while in Group II, the assays were fed with different substrates in a sequential order. Results showed more elevated specific methane yields for co-digestion assays compared with mono-digestion assays. Maximum yields were achieved at an OLR of 1.0gVS/(L·d) and a HRT reduced to half of the initial. Further reduction of the HRT coupled to an increase of the OLR generally caused a significant decrease of specific methane yields, as well as one case of severe overloading, i.e. the mono-digestion of juice industry waste, which resulted in instability and ultimately system failure. Sequential feeding with different substrates led to a more equilibrated operation, especially for co-digestion systems, with higher specific methane yields being observed during the phases corresponding to winery waste and juice industry waste substrates. Overall more positive results were obtained in the cases in which the latter substrates were fed to the reactors at process startup.

Magnesium oxide production from chrysotile asbestos detoxification with oxalic acid treatment.

This article describes the detoxification of pure chrysotile (Chr) asbestos by following an acid leaching treatment with oxalic acid dihydrate (Oxac) (H2C2O4·2H2O). Oxac was chosen due to its low environmental impact (or toxicity) and cost. We demonstrate the effectiveness of different concentrations of Oxac as proposed formulations. The results from FTIR, XRD and optical microscopy analyses indicated that all the applied treatments destructed the Chr structure while a new biomaterial, Glushinskite (Gls) was formed by the reaction between Oxac with the outer Brucite (Brc) (MgO2) layer surface of Chr. Oxac 0.05M was selected as the optimal concentration for an eight-day treatment for the detoxification. The heating of the supernatant of the above-treated solution at 480°C, yielded MgO in a considerable concentration (8.29% w/w). According to the energy consumption study the whole applied procedure is viable with an economic profit up to 4.3% and a low cost method of detoxification on the operation of a potential asbestos waste management site.

Toxicity assessment and feasible recycling process for amorphous silicon and CIS waste photovoltaic panels.

End-of-Life (EoL) photovoltaic (P/V) modules, which are recently included in the 2012/19/EU recast, require sound and sustainable treatment. Under this perspective, this paper deals with 2nd generation P/V waste modules, known as thin-film, via applying chemical treatment techniques. Two different types of modules are examined: (i) tandem a-Si:H/µc-Si:H panel and, (ii) Copper-Indium-Selenide (CIS) panel. Panels' pretreatment includes collection, manual dismantling and shredding; pulverization and digestion are further conducted to identify their chemical composition. A variety of elements is determined in the samples leachates' after both microwave-assisted total digestion and Toxicity Characteristic Leaching Procedure (TCLP test) using Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) analysis. The analysis reveals that several elements are detected in the two of panels, with no sample exceeds the TCLP test. Concentrations of precious and critical metals are also measured, which generates great incentives for recovery. Then, further experiments, for P/V recycling investigation, are presented using different acids or acid mixtures under a variety of temperatures and a stable S/L ratio, with or without agitation, in order to determine the optimal recycling conditions. The results verify that chemical treatment in P/V shredded samples is efficient since driving to ethylene-vinyl acetate (EVA) resin's dissolution, as well as valuable structural materials recovery (P/V glass, ribbons, cells, P/V intermediate layers). Among the solvents used, sulfuric acid and lactic acid demonstrate the most efficient and strongest performance on panels' treatment at gentle temperatures providing favorably low energy requirements.

Performance of electroremediation in real contaminated sediments using a big cell, periodic voltage and innovative surfactants.

The present work focused on evaluating the electrokinetic (EK) treatment of real contaminated sediments with toxic metals and polycyclic aromatic hydrocarbons (PAHs), using a big laboratory EK cell, periodic voltage and recently tested non-ionic surfactants. The results indicated that the "day on-night off" application mode of voltage, in conjunction with the selected solubilising agents, favoured the overall EK process. Arsenic, nickel and chromium exhibited the highest removal percentages, obtaining 83%, 67% and 63%, respectively, while zinc and lead attained 54% and 41% at the maximum. Furthermore, in the experiments where the non-ionic surfactants were introduced in the electrolyte chambers, there was a major uniformly removal of PAHs from the entire sediment across the EK cell, indicating the high solubilisation capacity of the enhancing agents. Essentially, transport and in some cases removal of PAHs (particularly from sections adjacent to the electrolyte compartments) also occurred in the unenhanced EK run, mainly due their negative charge, their potential weak bonds to the soil matrix and to the periodic application of voltage. Maximum removal was obtained by the use of Nonidet P40 where app. 1/3 (ca. 6498µg out of 20145µg) of the total initial amount of PAHs were removed from the cell.

Effect of alkaline pretreatment on anaerobic digestion of olive mill solid waste.

The present study evaluates the influence of alkaline (NaOH) pretreatment on anaerobic digestion of olive pomace. Batch hydrolysis experiments with different NaOH dosages, process durations and temperatures were conducted, in which the variation of olive pomace solubilization in the liquid phase was investigated. The effect of pretreatment on anaerobic digestion was studied through biochemical methane potential assays. The results demonstrated the effectiveness of the NaOH pretreatment in improving olive pomace solubilization as well as its biodegradability. Maximum specific methane yields were achieved at different NaOH dosages depending on the pretreatment temperature. Consequently, it was concluded that the two operating parameters of the pretreatment stage (NaOH dosage and temperature) may exert a joint effect on substrate biodegradability and methane yields. The highest methane yield (242NmLCH4/gVS) was obtained for the material pretreated at 90°C, at a dosage of 1mmol/gVS (4% of VS).

Consecutive anaerobic-aerobic treatment of the organic fraction of municipal solid waste and lignocellulosic materials in laboratory-scale landfill-bioreactors.

The scope of this study is to evaluate the use of laboratory-scale landfill-bioreactors, operated consecutively under anaerobic and aerobic conditions, for the combined treatment of the organic fraction of municipal solid waste (OFMSW) with two different co-substrates of lignocellulosic nature, namely green waste (GW) and dried olive pomace (DOP). According to the results such a system would represent a promising option for eventual larger scale applications. Similar variation patterns among bioreactors indicate a relatively defined sequence of processes. Initially operating the systems under anaerobic conditions would allow energetic exploitation of the substrates, while the implementation of a leachate treatment system ultimately aiming at nutrient recovery, especially during the anaerobic phase, could be a profitable option for the whole system, due to the high organic load that characterizes this effluent. In order to improve the overall effectiveness of such a system, measures towards enhancing methane contents of produced biogas, such as substrate pretreatment, should be investigated. Moreover, the subsequent aerobic phase should have the goal of stabilizing the residual materials and finally obtain an end material eventually suitable for other purposes.

Application of ecological risk indicators for the assessment of Greek surficial sediments contaminated by toxic metals.

Τhe present research investigates the partitioning of six selected toxic metals (Ni, Cr, Pb, Zn, Cu, and As) in eight sediment samples; half of them were collected from Elefsis Gulf, and the other half were taken from Koumoundourou Lake, Athens, Greece. Each one of them was treated by applying Tessier's five-step sequential extraction procedure. Regarding gulf sediments, the results indicated that Cu exhibits a strong affinity to the organic matter with percentages ranging from 65 to 78 %. Considerable amount of Zn (32-40 %) is bound to the Fe-Mn fraction and the non-residual fraction, while Cr and Ni are bound to the organic fraction, an observation that suits all toxic metals examined. Regarding lake sediments, Pb is the predominant metal bound to Fe-Mn (48-51 %). It is also noteworthy that the percentage of Zn bound to carbonated fraction (5-15 %), indicating biological availability. In conclusion, the application of several ecological risk indicators demonstrated that Elefsis Gulf sediments correspond to a moderate pollution level, with Pb and Ni being less bioavailable than in the lake's samples, in contrast to Zn which is more bioavailable. Finally, Koumoundourou Lakes' basin is characterized of "low risk."

Chrysotile asbestos detoxification with a combined treatment of oxalic acid and silicates producing amorphous silica and biomaterial.

This study was primarily imposed by the ever increasing need for detoxification of asbestos and asbestos containing materials (ACM), with potential application onsite. The present work investigates potential detoxification of pure chrysotile (Chr) asbestos via a combined treatment of oxalic acid dihydrate (Oxac) (Η2C2Ο4·2Η2Ο) with silicates, such as tetraethoxysilane (TEOS) (SiH20C8O4) and pure water glass (WG) (potassium silicate) (K2SiO3). These reagents used in the experimental procedure, do not cause adverse effects on the environment and are cost effective. The results of FTIR, XRD, optical and scanning microscopy coupled with EDS analyses indicated that all of the applied treatments destructed the Chr structure and yielded silica of amorphous phase and the biomaterial glushinskite from the Oxac reacted with brucite [Mg(OH)2] layer. Each of the proposed formulations can be applied for the detoxification of asbestos, according to priorities related to the specific products of the recovery treatment. Therefore, Oxac acid leaching followed by the TEOS addition is preferred in cases of glushinskite recovery; TEOS treatment of asbestos with subsequent Oxac addition produced amorphous silica production; finally Oxac acid leaching followed by WG encapsulated the asbestos fibers and can be used in cases of onsite asbestos and ACM detoxification.

Leaching capacity of metals-metalloids and recovery of valuable materials from waste LCDs.

The purpose of Directive 2012/19/EU which is related to WEEE (Waste Electrical and Electronic Equipment), also known as "e-waste", is to contribute to their sustainable production and consumption that would most possibly be achieved by their recovery, recycling and reuse. Under this perspective, the present study focused on the recovery of valuable materials, metals and metalloids from LCDs (Liquid Crystal Displays). Indium (In), arsenic (As) and stibium (Sb) were selected to be examined for their Leaching Capacity (R) from waste LCDs. Indium was selected mainly due to its rarity and preciousness, As due to its high toxicity and wide use in LCDs and Sb due to its recent application as arsenic's replacement to improve the optimal clarity of a LCD screen. The experimental procedure included disassembly of screens along with removal and recovery of polarizers via thermal shock, cutting, pulverization and digestion of the shredded material and finally leaching evaluation of the aforementioned elements. Leaching tests were conducted under various temperatures, using various solid:liquid (S/L) ratios and solvents (acid mixtures), to determine the optimal conditions for obtaining the maximum leaching capacities. The examined elements exhibited different leaching behaviors, mainly due to the considerable diversity in their inherent characteristic properties. Indium demonstrated the highest recovery percentages (approximately 60%), while the recovery of As and Sb was unsuccessful, obtaining poor leaching percentages (0.16% and 0.5%, respectively).

Comparative assessment of compost and zeolite utilisation for the simultaneous removal of BTEX, Cd and Zn from the aqueous phase: Batch and continuous flow study.

The present study focuses on the comparison of two materials, compost from municipal solid waste and natural zeolite for the simultaneous removal of petroleum hydrocarbons (benzene, toluene, ethylbenzene, xylenes - BTEX) and toxic metals from groundwater. First, batch experiments were conducted to identify the optimal removal conditions. All of the kinetic experiments were fitted to the pseudo-second-order kinetic model; equilibrium was reached within approximately 8 h for the zeolite and 12 h for the compost. An increase in the adsorbent dose and the pH value as well as a decrease in the initial concentration enhanced the pollutants' removal. The removal selectivity of both materials with slight differences follows the order Cd > Zn & toluene > ethylbenzene > m- & p-xylene > o-xylene > benzene. According, to the results derived from the continuous flow experiments the maximum adsorption capacity of the compost (90%) referred to Cd (0.88 mmol/g) whereas the minimum refers to benzene (65%) with a capacity up to 0.065 mmol/g. Zeolite had lower efficiencies for the studied pollutants with a higher performance corresponding to Cd (0.26 mmol/g), whereas the minimum zeolite capacity (63%) corresponds to toluene (0.045 mmol/g). Thus, this paper provides evidence that compost, a low cost material produced from waste, is capable for the simultaneous removal of both organic and inorganic pollutants from wastewater, and its performance is superior to zeolite.

Optimization of electrocoagulation (EC) process for the purification of a real industrial wastewater from toxic metals.

In the present work, the efficiency evaluation of electrocoagulation (EC) in removing toxic metals from a real industrial wastewater, collected from Aspropyrgos, Athens, Greece was investigated. Manganese (Mn), copper (Cu) and zinc (Zn) at respective concentrations of 5 mg/L, 5 mg/L and 10 mg/L were present in the wastewater (pH=6), originated from the wastes produced by EBO-PYRKAL munitions industry and Hellenic Petroleum Elefsis Refineries. The effect of operational parameters such as electrode combination and distance, applied current, initial pH and initial metal concentration, was studied. The results indicated that Cu and Zn were totally removed in all experiments, while Mn exhibited equally high removal percentages (approximately 90%). Decreasing the initial pH and increasing the distance between electrodes, resulted in a negative effect on the efficiency and energy consumption of the process. On the other hand, increasing the applied current, favored metal removal but resulted in a power consumption increase. Different initial concentrations did not affect metal removal efficiency. The optimal results, regarding both cost and EC efficiency, were obtained with a combination of iron electrodes, at 2 cm distance, at initial current of 0.1 A and pH=6. After 90 min of treatment, maximum removal percentages obtained were 89% for Mn, 100% for Cu and 100% for Zn, at an energy consumption of 2.55 kWh/m(3).