RESUMO
The detection of enantiopurity for small sample quantities is crucial, particularly in the pharmaceutical industry; however, existing methodologies rely on specific chiral recognition elements, or complex optical systems, limiting its utility. A nanoscale chirality sensor, for continuously monitoring molecular chirality using an electric circuit readout, is presented. This device design represents an alternative real-time scalable approach for chiral recognition of small quantity samples (less than 103 adsorbed molecules). The active device component relies on a gold nanofloret hybrid structure, i.e., a high aspect ratio semiconductor-metal hybrid nanosystem in which a SiGe nanowire tip is selectively decorated with a gold metallic cap. The tip mechanically touches a counter electrode to generate a nanojunction, and upon exposure to molecules, a metal-molecule-metal junction is formed. Adsorption of chiral molecules at the gold tip induces chirality in the localized plasmonic resonance at the electrode-tip junction and manifests in an enantiospecific current response.
Assuntos
Nanofios , Ressonância de Plasmônio de Superfície , Eletrônica , Ouro , EstereoisomerismoRESUMO
We report a generic theoretical framework for accurate simulation of the temporal and spatial evolution of fused fiber-optic components, fabricated by the "heat and pull" technique. The methodology is based on the solution of quasi-3D incompressible Navier-Stokes equations formulated for immiscible two-phase flow. The two-phase interface is resolved by employing an interface tracking approach combined with the immersed boundary method. The model facilitates accurate spatiotemporal prediction of the evolution of both the external shape of the optical component and the internal dopant concentration during fabrication. Validation of the model was obtained by extensive comparison to experimental results. The model was found to be a convenient theoretical tool that may reliably facilitate the design and fabrication process of a wide spectrum of optic components.
RESUMO
Spark plasma sintering (SPS) is an advanced one-stage, rapid, near-net shape densification technique combining uniaxial pressure with resistive heating. Various transparent ceramics have been successfully fabricated by SPS, despite the existence of inherent carbon contamination and residual pores. Due to the disk-shape of SPS-processed samples, the technique may be suited for producing thin-disk ceramic laser materials. Nevertheless, an in-depth study of these materials has never been reported. With that goal in mind, the major focus of this study was to characterize the laser performance of Nd:YAG ceramics fabricated by one-stage SPS under conventional (60 MPa) and high (300 MPa) applied pressures. In addition to measuring the lasing slope efficiency and threshold, the passive losses associated with each sample were also evaluated. Surprisingly, it was found that in-line transmittance spectra do not provide accurate predictions of laser performance due to the nature of residual porosity. Moreover, homogeneity and beam quality were assessed, and comparisons were drawn between conventional and high-pressure SPS ceramics. This study lays the groundwork for the future of laser materials fabricated by SPS or similar pressure-assisted techniques.
RESUMO
An all-fiber clad pumped Raman fiber laser (FL) oscillator with a CW power of 1.2 kW and an efficiency of 85% is presented. To the best of our knowledge, this laser is the highest power and the highest efficiency Raman FL demonstrated in any configuration with brightness enhancement (BE). To the best of our knowledge, it is also the first greater than kilowatt FL of any kind that does not utilize rare-earth doping in the oscillator fiber (all passive fiber). The beam quality (BQ) of the Raman laser was M2=2.75 at 1 kW, and the pump-Stokes BE factor was approximately 7. The laser consists of a specially designed triple-clad fiber which confines the low BQ pump power into the multi-mode inner clad, while generating the Raman signal in the large-mode-area core. The second Stokes is inhibited by selecting the appropriate inner clad-to-core area ratio and by the oscillator's selective fiber Bragg grating reflectors.
RESUMO
We present new results demonstrating the capability of performing computed tomography (CT) using broadband Bessel terahertz (THz) beams. Nondiffractive beams such as these exhibit propagation-invariant lines of focus with an extended depth-of-field compared to conventional Gaussian beams. Using this property, we demonstrate a considerable improvement in the 3D reconstruction image of a synthetic sample through the backprojection algorithm. Only when THz Bessel beams are used, a full reconstruction of the object structure is made. Moreover, we use phase-contrast mechanism which improves the spatial resolution and reconstructed images. Our results highlight the potential in using nondiffractive Bessel beams to significantly improve 3D-image reconstruction of THz CT.
RESUMO
A Nd:YAG laser crystal was pumped at 946 nm and lased at 1064 nm. This pump-lase format was investigated in order to reduce the quantum defect between the pump and laser photons as compared to other pump schemes of this material. To the best of our knowledge, this is the first realization of this scheme. A room temperature absorption coefficient and linewidth of approximately 0.075 cm(-1) and approximately 1 nm for 1% at. Nd(+3) concentrations were measured for the 946 nm absorption line. Those parameters impose both narrow-bandwidth pumping and a long absorption path. By increasing the laser crystal temperature above room temperature, the absorption cross sections at 946 and 938 nm increase due to enhanced thermal population of the upper energy level of the ground manifold. The possibility of exploiting this phenomenon to enhance the pump absorption is also discussed.