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In this work, we study the contributions that different molecular blocks have in the wavelength-dependence of the refractive index in ionic liquids. The ionic liquids chosen for this work are combinations of the bis(trifluoromethylsulfonyl)imide anion with cations based on four different heterocycles with different extents of charge delocalization. The analysis is performed in terms of the experimental electronic polarizability, which is obtained by combining measurements of refractive index curves and densities via the Lorentz-Lorenz equation. Exploiting the additivity of electronic polarizability in ionic liquids, the contribution of the anion and the heterocycles of the cations is separated from that of the alkyl chains. Our results show important differences in these contributions, revealing a key influence of the charge delocalization in the cationic rings on the behavior of the refractive index dispersion. The understanding of how different parts of ionic liquids affect their refractive index dependence on wavelength would allow to gain precise control of this magnitude, enabling the development of customized optical materials for diverse applications in photonics and sensing technologies.
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The continuous membrane stiffness of a deformable mirror propagates the deformation of the actuators beyond their neighbors. When phase-retrieval algorithms are used to determine the desired shape of these mirrors, this cross-coupling-also known as influence function (IF)-is generally disregarded. We study this problem via simulations and bench tests for different target shapes to gain further insight into the phenomenon. Sound modeling of the IF effect is achieved as highlighted by the concurrence between the modeled and experimental results. In addition, we observe that the actuators IF is a key parameter that determines the accuracy of the output light pattern. Finally, it is shown that in some cases it is possible to achieve better shaping by modifying the input irradiance of the phase-retrieval algorithm. The results obtained from this analysis open the door to further improvements in this type of beam-shaping systems.
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The availability and performance of laser-based adaptive optics (AO) systems are strongly dependent on the power and quality of the laser beam before being projected to the sky. Frequent and time-consuming alignment procedures are usually required in the laser systems with free-space optics to optimize the beam. Despite these procedures, significant distortions of the laser beam have been observed during the first two years of operation of the Gemini South multi-conjugate adaptive optics system (GeMS). A beam shaping concept with two deformable mirrors is investigated in order to provide automated optimization of the laser quality for astronomical AO. This study aims at demonstrating the correction of quasi-static aberrations of the laser, in both amplitude and phase, testing a prototype of this two-deformable mirror concept on GeMS. The paper presents the results of the preparatory study before the experimental phase. An algorithm to control amplitude and phase correction, based on phase retrieval techniques, is presented with a novel unwrapping method. Its performance is assessed via numerical simulations, using aberrations measured at GeMS as reference. The results predict effective amplitude and phase correction of the laser distortions with about 120 actuators per mirror and a separation of 1.4 m between the mirrors. The spot size is estimated to be reduced by up to 15% thanks to the correction. In terms of AO noise level, this has the same benefit as increasing the photon flux by 40%.
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The light path function (LPF) of an Offner spectrometer is presented. The evaluation of the LPF of this spectrometer enables its imaging properties to be studied for arbitrary object and image positions, while avoiding the more complicated analysis of intermediate images generated by the diffraction grating, which is often involved. A power series expansion of the LPF on the grating coordinates directly determines pupil aberrations of the generated spectrum and facilitates the search for configurations with small low-order aberrations. This analysis not only confirms the possibility of reducing low-order aberrations in Rowland-type mounts, namely astigmatism and coma, as predicted in previous studies, but also proves that all third-order terms in the series expansion of the aberration function can be canceled at the image of the design point and for the corresponding design wavelength, when the design point is located on a plane orthogonal to the optical axis. Furthermore, fourth-order terms are computed and shown to represent the most relevant contribution to image blurring. Third- and fourth-order aberrations are also evaluated for Rowland mounts with the design point located outside the aforementioned plane. The study described in this manuscript is not restricted to small angles of incidence, and, therefore, it goes beyond Seidel and Buchdahl aberrations.
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We aim to show that Dyson imaging spectrometers can be easily designed by applying the concept of the Rowland circle to refracting surfaces. This allows us to conceive an analytical procedure that is based on the removal of astigmatism at two wavelengths. Following this procedure, high-optical-quality spectrometers can be designed even for high speeds. Root-mean-square spot radii less than 2.5 µm are obtained for speeds as high as f/1.5, slit lengths of 15 mm, and wavelength ranges of 0.4-1.7 µm. Design examples are presented for classical Dyson spectrometers in which the detector is glued to the glass plane surface and for spectrometers with an air gap between this surface and the image plane.
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In this paper, the imaging performance of an Offner concentric imaging spectrometer is analyzed when the spectrometer entrance slit is disposed arbitrarily on the plane that is parallel to the grating grooves and contains the common center of curvature. Astigmatism-corrected designs are obtained for off-plane incidence on the grating if one point on the slit is located on the Rowland circle of the primary mirror. In this case, the combined system of primary mirror plus diffraction grating provides two astigmatic line images oriented parallel and orthogonal to the plane of diffraction, with the former located on the same plane as the slit. Consequently, these images can be brought to a single focus on this plane by the tertiary mirror if its radius of curvature is chosen properly. In addition, coma aberration is simultaneously removed. These results can be applied to the design of two-mirror or three-mirror spectrometers, generalizing the concept of the best imaging circle and providing solutions to get anastigmatic imaging for two object points and two wavelengths.
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This is a proposal and description of a new spectrometer based on the Schwarzschild optical system. The proposed design contains two Schwarzschild optical systems. Light diverging from the spectrometer entrance slit is collimated by the first one; the collimated light beam hits a planar diffraction grating and the light dispersed from the grating is focused by the second system, which is concentric with the first. A very simple procedure obtains designs that are anastigmatic for the center of the slit and for a particular wavelength. A specific example shows the performance of this type of spectrometer.
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High-quality Dyson imaging spectrometers are designed by applying a telecentric condition for off-axis image points. By imposing this condition for two different wavelengths, designs presenting low aberrations for the whole spectral range of the system are obtained. A UV-TO-NIR fast design (f/1.5) exhibiting excellent optical performance is presented.
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This is a proposal and description of a new configuration for an Offner imaging spectrometer based on the theory of aberrations of off-plane classical-ruled spherical diffraction gratings. This new spectrometer comprises a concave mirror used in double reflection and a convex reflection grating operating in quadrature, in a concentric layout. A very simple procedure obtains designs that are anastigmatic for a given point on the entrance slit and a given wavelength. Specific examples show that the performance of this type of system improves the performance of analogous conventional in-plane systems, when compactness and/or high spectral resolution is of fundamental importance.
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We review the theory of spherical diffraction gratings with regard to their imaging properties in off-plane arrangements. Our study is restricted to gratings with equally spaced grooves, and it is focused on the quadrature configuration, where the incident and diffraction planes are orthogonal to each other. We identify regions of low astigmatism and propose some monochromator mounts.