RESUMO
The diffusive motion of the conducting electrons in the one-dimensional organic conductor FA2PF6 (FA, Fluoranthene) is studied with the ESR pulse-gradient spin-echo (PGSE) signal combined with spatial density ESR imaging. A local measurement of the short restricted regions reveals diffraction patterns in the local PGSE data. A model calculation adapted to the local measurements provides a highly accurate quantitative description of the results. The appearance of these patterns provides information about the diffusive motion of the charge at the crystal boundaries.
RESUMO
A (FA)(2)PF(6) crystal from the family of the quasi-one-dimensional organic conductors was selectively damaged by a beam of Helium ions with a slitted mask placed in the beam's trajectory. Pulsed ESR density weighted imaging of the damaged crystal revealed the appearance of regions where the ESR signal was absent. The one-dimensional motion of the charge carriers was thus restricted to the undamaged sections. The local charge carrier spin dynamics in these restricted areas was probed by combined k-space q-space pulsed ESR imaging. The local expected appearance of the restricted pulsed gradient spin echo (PGSE) "diffusive diffraction" effect is shown. The position of the diffraction minima is compatible with the density imaging results.
RESUMO
Novel implementation of the Fourier imaging technique on conduction electron spins in the one-dimensional organic conductors (FA)2PF6 (FA: fluoranthene) is reported. Two-dimensional spatial imaging of resolution 30 &mgr;m(2) is combined with the pulsed-gradient spin-echo technique, to derive maps revealing the local properties of the electron spin density and mobility. The maps generally show pronounced inhomogeneity of both density and mobility on the scale of approximately 30-300 &mgr;m. Highly mobile regions were identified to exist, and the mobility in these was quantitatively evaluated by a basic theoretical model of restricted diffusion.
RESUMO
Three-dimensional pulsed ESR imaging was performed on a (FA)(2)PF(6) crystal using a three-dimensional Fourier imaging sequence. The best resolution achieved was of 20 microm(3). Comparison with images obtained using the filtered back-projection method shows the superiority of this method under the given conditions.