Disentangling degenerate solutions from primary transit and secondary eclipse spectroscopy of exoplanets.

Infrared transmission and emission spectroscopy of exoplanets, recorded from primary transit and secondary eclipse measurements, indicate the presence of the most abundant carbon and oxygen molecular species (H2O, CH4, CO and CO2) in a few exoplanets. However, efforts to constrain the molecular abundances to within several orders of magnitude are thwarted by the broad range of degenerate solutions that fit the data. Here, we explore, with radiative transfer models and analytical approximations, the nature of the degenerate solution sets resulting from the sparse measurements of 'hot Jupiter' exoplanets. As demonstrated with simple analytical expressions, primary transit measurements probe roughly four atmospheric scale heights at each wavelength band. Derived mixing ratios from these data are highly sensitive to errors in the radius of the planet at a reference pressure. For example, an uncertainty of 1% in the radius of a 1000 K and H2-based exoplanet with Jupiter's radius and mass causes an uncertainty of a factor of approximately 100-10,000 in the derived gas mixing ratios. The degree of sensitivity depends on how the line strength increases with the optical depth (i.e. the curve of growth) and the atmospheric scale height. Temperature degeneracies in the solutions of the primary transit data, which manifest their effects through the scale height and absorption coefficients, are smaller. We argue that these challenges can be partially surmounted by a combination of selected wavelength sampling of optical and infrared measurements and, when possible, the joint analysis of transit and secondary eclipse data of exoplanets. However, additional work is needed to constrain other effects, such as those owing to planetary clouds and star spots. Given the current range of open questions in the field, both observations and theory, there is a need for detailed measurements with space-based large mirror platforms (e.g. James web space telescope) and smaller broad survey telescopes as well as ground-based efforts.

Possible tropical lakes on Titan from observations of dark terrain.

Titan has clouds, rain and lakes--like Earth--but composed of methane rather than water. Unlike Earth, most of the condensable methane (the equivalent of 5 m depth globally averaged) lies in the atmosphere. Liquid detected on the surface (about 2 m deep) has been found by radar images only poleward of 50° latitude, while dune fields pervade the tropics. General circulation models explain this dichotomy, predicting that methane efficiently migrates to the poles from these lower latitudes. Here we report an analysis of near-infrared spectral images of the region between 20° N and 20° S latitude. The data reveal that the lowest fluxes in seven wavelength bands that probe Titan's surface occur in an oval region of about 60 × 40 km(2), which has been observed repeatedly since 2004. Radiative transfer analyses demonstrate that the resulting spectrum is consistent with a black surface, indicative of liquid methane on the surface. Enduring low-latitude lakes are best explained as supplied by subterranean sources (within the last 10,000 years), which may be responsible for Titan's methane, the continual photochemical depletion of which furnishes Titan's organic chemistry.

Water in exoplanets.

Exoplanets--planets orbiting around stars other than our own Sun--appear to be common. Significant research effort is now focused on the observation and characterization of exoplanet atmospheres. Species such as water vapour, methane, carbon monoxide and carbon dioxide have been observed in a handful of hot, giant, gaseous planets, but cooler, smaller planets such as Gliese 1214b are now analysable with current telescopes. Water is the key chemical dictating habitability. The current observations of water in exoplanets from both space and the ground are reviewed. Controversies surrounding the interpretation of these observations are discussed. Detailed consideration of available radiative transfer models and linelists are used to analyse these differences in interpretation. Models suggest that there is a clear need for data on the pressure broadening of water transitions by H(2) at high temperatures. The reported detections of water appear to be robust, although final confirmation will have to await the better quality observational data provided by currently planned dedicated space missions.

A ground-based near-infrared emission spectrum of the exoplanet HD 189733b.

Detection of molecules using infrared spectroscopy probes the conditions and compositions of exoplanet atmospheres. Water (H(2)O), methane (CH(4)), carbon dioxide (CO(2)), and carbon monoxide (CO) have been detected in two hot Jupiters. These previous results relied on space-based telescopes that do not provide spectroscopic capability in the 2.4-5.2 microm spectral region. Here we report ground-based observations of the dayside emission spectrum for HD 189733b between 2.0-2.4 microm and 3.1-4.1 microm, where we find a bright emission feature. Where overlap with space-based instruments exists, our results are in excellent agreement with previous measurements. A feature at approximately 3.25 microm is unexpected and difficult to explain with models that assume local thermodynamic equilibrium (LTE) conditions at the 1 bar to 1 x 10(-6) bar pressures typically sampled by infrared measurements. The most likely explanation for this feature is that it arises from non-LTE emission from CH(4), similar to what is seen in the atmospheres of planets in our own Solar System. These results suggest that non-LTE effects may need to be considered when interpreting measurements of strongly irradiated exoplanets.

Exploring extrasolar worlds: from gas giants to terrestrial habitable planets.

Almost 500 extrasolar planets have been found since the discovery of 51 Peg b by Mayor and Queloz in 1995. The traditional field of planetology has thus expanded its frontiers to include planetary environments not represented in our Solar System. We expect that in the next five years space missions (Corot, Kepler and GAIA) or ground-based detection techniques will both increase exponentially the number of new planets discovered and lower the present limit of a approximately 1.9 Earth-mass object [e.g. Mayor et al., Astron. Astrophys., 2009, 507, 487]. While the search for an Earth-twin orbiting a Sun-twin has been one of the major goals pursued by the exoplanet community in the past years, the possibility of sounding the atmospheric composition and structure of an increasing sample of exoplanets with current telescopes has opened new opportunities, unthinkable just a few years ago. As a result, it is possible now not only to determine the orbital characteristics of the new bodies, but moreover to study the exotic environments that lie tens of parsecs away from us. The analysis of the starlight not intercepted by the thin atmospheric limb of its planetary companion (transit spectroscopy), or of the light emitted/reflected by the exoplanet itself, will guide our understanding of the atmospheres and the surfaces of these extrasolar worlds in the next few years. Preliminary results obtained by interpreting current atmospheric observations of transiting gas giants and Neptunes are presented. While the full characterisation of an Earth-twin might requires a technological leap, our understanding of large terrestrial planets (so called super-Earths) orbiting bright, later-type stars is within reach by current space and ground telescopes.

Global circulation as the main source of cloud activity on Titan.

Clouds on Titan result from the condensation of methane and ethane and, as on other planets, are primarily structured by circulation of the atmosphere. At present, cloud activity mainly occurs in the southern (summer) hemisphere, arising near the pole and at mid-latitudes from cumulus updrafts triggered by surface heating and/or local methane sources, and at the north (winter) pole, resulting from the subsidence and condensation of ethane-rich air into the colder troposphere. General circulation models predict that this distribution should change with the seasons on a 15-year timescale, and that clouds should develop under certain circumstances at temperate latitudes ( approximately 40 degrees ) in the winter hemisphere. The models, however, have hitherto been poorly constrained and their long-term predictions have not yet been observationally verified. Here we report that the global spatial cloud coverage on Titan is in general agreement with the models, confirming that cloud activity is mainly controlled by the global circulation. The non-detection of clouds at latitude approximately 40 degrees N and the persistence of the southern clouds while the southern summer is ending are, however, both contrary to predictions. This suggests that Titan's equator-to-pole thermal contrast is overestimated in the models and that its atmosphere responds to the seasonal forcing with a greater inertia than expected.

Evidence for the exposure of water ice on Titan's surface.

The smoggy stratosphere of Saturn's largest moon, Titan, veils its surface from view, except at narrow wavelengths centered at 0.83, 0.94, 1.07, 1.28, 1.58, 2.0, 2.9, and 5.0 micrometers. We derived a spectrum of Titan's surface within these "windows" and detected features characteristic of water ice. Therefore, despite the hundreds of meters of organic liquids and solids hypothesized to exist on Titan's surface, its icy bedrock lies extensively exposed.

Direct detection of variable tropospheric clouds near Titan's south pole.

Atmospheric conditions on Saturn's largest satellite, Titan, allow the possibility that it could possess a methane condensation and precipitation cycle with many similarities to Earth's hydrological cycle. Detailed imaging studies of Titan have hitherto shown no direct evidence for tropospheric condensation clouds, although there has been indirect spectroscopic evidence for transient clouds. Here we report images and spectra of Titan that show clearly transient clouds, concentrated near the south pole, which is currently near the point of maximum solar heating. The discovery of these clouds demonstrates the existence of condensation and localized moist convection in Titan's atmosphere. Their location suggests that methane cloud formation is controlled seasonally by small variations in surface temperature, and that the clouds will move from the south to the north pole on a 15-year timescale.