Truncated mass divergence in a Mott metal.

The Mott metal-insulator transition represents one of the most fundamental phenomena in condensed matter physics. Yet, basic tenets of the canonical Brinkman-Rice picture of Mott localization remain to be tested experimentally by quantum oscillation measurements that directly probe the quasiparticle Fermi surface and effective mass. By extending this technique to high pressure, we have examined the metallic state on the threshold of Mott localization in clean, undoped crystals of NiS2. We find that i) on approaching Mott localization, the quasiparticle mass is strongly enhanced, whereas the Fermi surface remains essentially unchanged; ii) the quasiparticle mass closely follows the divergent form predicted theoretically, establishing charge carrier slowdown as the driver for the metal-insulator transition; iii) this mass divergence is truncated by the metal-insulator transition, placing the Mott critical point inside the insulating section of the phase diagram. The inaccessibility of the Mott critical point in NiS2 parallels findings at the threshold of ferromagnetism in clean metallic systems, in which criticality at low temperature is almost universally interrupted by first-order transitions or novel emergent phases such as incommensurate magnetic order or unconventional superconductivity.

Superconductivity beyond the Conventional Pauli Limit in High-Pressure CeSb_{2}.

We report the discovery of superconductivity at a pressure-induced magnetic quantum phase transition in the Kondo lattice system CeSb_{2}, sustained up to magnetic fields that exceed the conventional Pauli limit eightfold. Like CeRh_{2}As_{2}, CeSb_{2} is locally noncentrosymmetric around the Ce site, but the evolution of critical fields and normal state properties as CeSb_{2} is tuned through the quantum phase transition motivates a fundamentally different explanation for its resilience to applied field.

Fermi Surface and Mass Renormalization in the Iron-Based Superconductor YFe_{2}Ge_{2}.

Interaction-enhanced carrier masses are central to the phenomenology of iron-based superconductors. Quantum oscillation measurements in the new unconventional superconductor YFe_{2}Ge_{2} resolve all four Fermi surface pockets expected from band structure calculations, which predict an electron pocket in the Brillouin zone corner and three hole pockets enveloping the centers of the top and bottom of the Brillouin zone. Carrier masses reach up to 20 times the bare electron mass and are among the highest ever observed in any iron-based material, accounting for the enhanced heat capacity Sommerfeld coefficient ≃100 mJ/mol K^{2}. Mass renormalization is uniform across reciprocal space, suggesting predominantly local correlations, as in the Hund's metal scenario.

Unconventional Bulk Superconductivity in YFe_{2}Ge_{2} Single Crystals.

Sharp superconducting transition anomalies observed in a new generation of single crystals establish that bulk superconductivity is intrinsic to high purity YFe_{2}Ge_{2}. Low temperature heat capacity measurements suggest a disorder and field dependent residual Sommerfeld coefficient, consistent with disorder-induced in-gap states as expected for a sign-changing order parameter. The sevenfold reduction in disorder scattering in these new crystals to residual resistivities ≃0.45 µΩ cm was achieved using a new liquid transport growth technique, paving the way for multiprobe experiments investigating the normal and superconducting states of YFe_{2}Ge_{2}.

Strong coupling superconductivity in a quasiperiodic host-guest structure.

We examine the low-temperature states supported by the quasiperiodic host-guest structure of elemental bismuth at high pressure, Bi-III. Our electronic transport and magnetization experiments establish Bi-III as a rare example of type II superconductivity in an element, with a record upper critical field of ~ 2.5 T, unusually strong electron-phonon coupling, and an anomalously large, linear temperature dependence of the electrical resistivity in the normal state. These properties may be attributed to the peculiar phonon spectrum of incommensurate host-guest structures, which exhibit additional quasi-acoustic sliding modes, suggesting a pathway toward strong coupling superconductivity with the potential for enhanced transition temperatures and high critical fields.

Unconventional Superconductivity in the Layered Iron Germanide YFe(2)Ge(2).

The iron-based intermetallic YFe_{2}Ge_{2} stands out among transition metal compounds for its high Sommerfeld coefficient of the order of 100 mJ/(mol K^{2}), which signals strong electronic correlations. A new generation of high quality samples of YFe_{2}Ge_{2} show superconducting transition anomalies below 1.8 K in thermodynamic, magnetic, and transport measurements, establishing that superconductivity is intrinsic in this layered iron compound outside the known superconducting iron pnictide or chalcogenide families. The Fermi surface geometry of YFe_{2}Ge_{2} resembles that of KFe_{2}As_{2} in the high pressure collapsed tetragonal phase, in which superconductivity at temperatures as high as 10 K has recently been reported, suggesting an underlying connection between the two systems.

Pressure- and composition-induced structural quantum phase transition in the cubic superconductor (Sr, Ca)3Ir4Sn13.

We show that the quasi-skutterudite superconductor Sr(3)Ir(4)Sn(13) undergoes a structural transition from a simple cubic parent structure, the I phase, to a superlattice variant, the I' phase, which has a lattice parameter twice that of the high temperature phase. We argue that the superlattice distortion is associated with a charge density wave transition of the conduction electron system and demonstrate that the superlattice transition temperature T(*) can be suppressed to zero by combining chemical and physical pressure. This enables the first comprehensive investigation of a superlattice quantum phase transition and its interplay with superconductivity in a cubic charge density wave system.

Patterned anvils for high pressure measurements at low temperature.

Multiprobe high pressure measurements require electrical leads in the sample chamber. Compared to conventional wire-based techniques, metallic tracks patterned onto the anvil surface improve reliability and ease of use, and enable novel and more demanding measurements under high pressure. We have developed new anvil designs based on sputter-deposited tracks on alumina and moissanite anvils. These anvils allow convenient and reliable measurements of electrical transport properties or of the magnetic susceptibility under hydrostatic conditions, as demonstrated by test measurements on Pb and Ca(3)Ru(2)O(7).