Environmental impact assessment of biomass supported electricity generation for sustainable rural energy systems - A case study of Grenada County, Mississippi, USA.

Fossil fuels have been the major source of electricity supply in the United States of America (USA) for many decades. While a significant shift has occurred from coal-dominated supply to natural gas and renewable source based supplies in recent decades, there is still large potential to improve biomass supported electricity contribution in rural communities, which depend majorly on forest-related activities. Wood waste, an underutilized renewable resource, has the potential for electricity generation in rural areas to reduce the contribution of electricity generated from fossil fuels and assist in greenhouse gas savings. In this study, a life cycle assessment approach was used to estimate the emissions of electricity generated by wood residues in a rural community (Grenada County, Mississippi (MS), USA) and compared with those emissions from the recent electricity mix (2018), a previous electricity mix (2010) supply, along with natural gas (NG) and coal (Bituminous Coal, BC) based electricity generation options. A significant reduction (85.9-94.6%) in global warming impact was observed when compared with BC, NG and grid supplied electricity for years 2010 and 2018. When compared to the current electricity mix at the grid (2018), acidification, eutrophication, respiratory effects and smog formation showed higher emissions ranging from 30.8% to 72.4%. The sensitivity analysis showed an improvement in emissions savings with increased biomass to power conversion efficiency (40%), lower moisture content of the biomass (0%, bone dry biomass), and reduced transportation distance (35 km). This study showed an improvement in the electricity mix supplied to Grenada county, MS, which implies sustainable development opportunities for promoting energy security in rural communities with forest-based industries.

Transitioning Wastewater Treatment Plants toward Circular Economy and Energy Sustainability.

Aging infrastructure, increasing environmental regulations, and receiving water environment issues stem the need for advanced wastewater treatment processes across the world. Advanced wastewater treatment systems treat wastewater beyond organic carbon removal and aim to remove nutrients and recover valuable products. While the removal of major nutrients (carbon, nitrogen, and phosphorus) is essential for environmental protection, this can only be achieved through energy-, chemical-, and cost-intensive processes in the industry today, which is an unsustainable trend, considering the global population growth and rapid urbanization. Two major routes for developing more sustainable and circular-economy-based wastewater treatment systems would be to (a) innovate and integrate energy- and resource-efficient anaerobic wastewater treatment systems and (b) enhance carbon capture to be diverted to energy recovery schemes. This Mini-Review provides a critical evaluation and perspective of two potential process routes that enable this transition. These process routes include a bioelectrochemical energy recovery scheme and codigestion of organic sludge for biogas generation in anaerobic digesters. From the analysis, it is imperative that integrating both concepts may even result in more energy- and resource-efficient wastewater treatment systems.

Preparing for outbreaks - Implications for resilient water utility operations and services.

Recent outbreaks have constantly disrupted our global economy and public health in numerous ways, impacting efficiency and prosperity across all sectors. This article focuses on the impacts of outbreaks (epidemics and pandemics) on water - wastewater utilities and water infrastructure and critically evaluates the issues underlining their impact on economic development and highlights the need for preparedness. A perspective on water infrastructure and industry-related impact on our society and economic development in the wake of the pandemic, COVID-19, is presented. Methods that could potentially institute safe, reliable, and efficient procedures for better preparedness and rapid recovery have been explored at length. The purpose of this article is therefore threefold: 1) to discuss the economic and public health impact of outbreaks on water and wastewater utilities and utility workforce; 2) to present case studies demonstrating utilities' preparedness and response to COVID-19, and 3) to review various alternatives for education and training as well as innovative processes and strategies for productivity during and after outbreaks. Strategies discussed in this article could be used as valuable tools for developing resiliency efforts, especially from the context of continuing water and wastewater utility operations and services in emergencies.

Resource recovery from low strength wastewater in a bioelectrochemical desalination process.

In this research, low strength synthetic wastewaters with chemical oxygen demand less than 300 mg L-1 were treated at different concentrations in a bioelectrochemical desalination process. A process optimization model was utilized to study the performance of the photosynthetic bioelectrochemical desalination process. The variables include substrate (chemical oxygen demand) concentration, total dissolved solids, and microalgae biomass concentration in the cathode chamber. Relationships between the chemical oxygen demand concentration, microalgae, and salt concentrations were evaluated. Power densities and potential energy benefits from microalgal biomass growth were discussed. The results from this study demonstrated the reliability and reproducibility of the photosynthetic microbial desalination process performance followed by a response surface methodology optimization. This study also confirms the suitability of bioelectrochemical desalination process for treating low substrate wastewaters such as agricultural wastewaters, anaerobic digester effluents, and septic tank effluents for net energy production and water desalination.

Wetlands for environmental protection.

This article presents an update on the research and practical demonstration of wetland-based treatment technologies for protecting water resources and environment covering papers published in 2019. Wetland applications in wastewater treatment, stormwater management, and removal of nutrients, metals, and emerging pollutants including pathogens are highlighted. A summary of studies focusing on the effects of vegetation, wetland design and operation strategies, and process configurations and modeling, for efficient treatment of various municipal and industrial wastewaters, is included. In addition, hybrid and innovative processes with wetlands as a platform treatment technology are presented.

Wetlands for wastewater treatment.

This article presents an update on the research and practical demonstration of wetland treatment technologies for wastewater treatment. Applications of wetlands in wastewater treatment (as an advanced treatment unit or a decentralized system) and stormwater management or treatment for nutrient and pollutant removal (metals, industrial and emerging pollutants including pharmaceutical compounds and pathogens) are highlighted. A summary of studies involving the effects of vegetation, wetland design and operation, and configurations for efficient treatment of various municipal and industrial wastewaters is also included. PRACTITIONER POINTS: Provides an update on current research and development of wetland technologies for wastewater treatment. Effects of vegetation, pathogens removal, heavy metals and emerging pollutants removal are included. Wetland design and operation is a key factor to improve water quality of wetland effluent.

Accomplishing a N-E-W (nutrient-energy-water) synergy in a bioelectrochemical nitritation-anammox process.

This study reports an investigation of the concept, application and performance of a novel bioelectrochemical nitritation-anammox microbial desalination cell (MDC) for resource-efficient wastewater treatment and desalination. Two configurations of anammox MDCs (anaerobic-anammox cathode MDC (AnAmoxMDC) and nitration-anammox cathode MDC (NiAmoxMDC)) were compared with an air cathode MDC (CMDC), operated in fed-batch mode. Results from this study showed that the maximum power density produced by NiAmoxMDC (1,007 mW/m3) was higher than that of AnAmoxMDC (444 mW/m3) and CMDC (952 mW/m3). More than 92% of ammonium-nitrogen (NH4+-N) removal was achieved in NiAmoxMDC, significantly higher than AnAmoxMDC (84%) and CMDC (77%). The NiAmoxMDC performed better than CMDC and AnAmoxMDC in terms of power density, COD removal and salt removal in desalination chamber. In addition, cyclic voltammetry analysis of anammox cathode showed a redox peak centered at -140 mV Vs Ag/AgCl confirming the catalytic activity of anammox bacteria towards the electron transfer process. Further, net energy balance of the NiAmoxMDC was the highest (NiAmoxMDC-0.022 kWh/m3 >CMDC-0.019 kWh/m3 >AnAmoxMDC-0.021 kWh/m3) among the three configurations. This study demonstrated, for the first time, a N-E-W synergy for resource-efficient wastewater treatment using nitritation-anammox process.

Wetlands for Wastewater Treatment.

An update on the current research and development of wetland treatment technologies for wastewater treatment is provided in this paper. This article focuses on wetland applications in wastewater treatment (as an advanced treatment unit or a decentralized system), and nutrient and pollutant removal (metals, industrial and emerging pollutants including pharmaceutical compounds). A summary of studies involving the effects of vegetation, wetland design and operation, modeling, hybrid and innovative systems, landfill leachate treatment, and pathogen removal is also included.

Wetlands for Wastewater Treatment.

This article provides an update on the wastewater treatment technologies, which utilize natural processes or passive components to remove various pollutants. The focus is on the wetland systems and their applications in wastewater treatment (as an advanced treatment unit or a decentralized system), and nutrient and pollutant removal (heavy and hazardous metals, industrial and emerging pollutants including pharmaceutical and personal care products and endocrine disrupting chemicals). A summary of studies involving the effects of vegetation, wetland design and operation, modeling, hybrid and innovative systems, storm water treatment, sludge treatment, landfill leachate treatment, and pathogen removal is also included.

Desalination and sustainability - An appraisal and current perspective.

Desalination technologies have evolved and advanced rapidly along with increasing water demands around the world since 1950s. Many reviews have focused on the techno-economic and environmental and ecological issues of the desalination technologies and emphasized the feasibility of desalination industry as an alternative to meet the water demands in many water scarce regions. Despite these efforts, many perceptions about desalination processes hinder their applications for potential water supplies. This article has two specific aims: 1) provide an overview of the desalination trends around the world and discuss the sustainability components of desalination processes in comparison with other water supply alternatives; and 2) discuss case studies for desalination, and drivers and factors that influence sustainable desalination and other alternative water sources for desalination to increase our current understanding on the sensitive and futuristic issues of water supply and resource management options for drought facing regions. Although some of the facts and recent developments discussed here show that desalination can be affordable and potentially sustainable, contributions that meaningfully address socio-economic and ecological and environmental issues of desalination processes are urgently required in this critical era of severe water stress for the present context and the future development of desalination technologies.

Wetlands for Wastewater Treatment.

This paper provides a review of the treatment technologies, which utilize natural processes or passive components in wastewater treatment. In particular, this paper primarily focuses on wetland systems and their applications in wastewater treatment (as an advanced treatment unit or decentralized system), nutrient and pollutant removal (single and multiple pollutants, and metals), and emerging pollutant removal (pharmaceuticals). A summary of studies involving the plant (vegetation) effects, wetland design and modeling, hybrid and innovative systems, storm water treatment and pathogen removal is also included.

Transesterification of waste vegetable oil under pulse sonication using ethanol, methanol and ethanol-methanol mixtures.

This study reports on the effects of direct pulse sonication and the type of alcohol (methanol and ethanol) on the transesterification reaction of waste vegetable oil without any external heating or mechanical mixing. Biodiesel yields and optimum process conditions for the transesterification reaction involving ethanol, methanol, and ethanol-methanol mixtures were evaluated. The effects of ultrasonic power densities (by varying sample volumes), power output rates (in W), and ultrasonic intensities (by varying the reactor size) were studied for transesterification reaction with ethanol, methanol and ethanol-methanol (50%-50%) mixtures. The optimum process conditions for ethanol or methanol based transesterification reaction of waste vegetable oil were determined as: 9:1 alcohol to oil ratio, 1% wt. catalyst amount, 1-2 min reaction time at a power output rate between 75 and 150 W. It was shown that the transesterification reactions using ethanol-methanol mixtures resulted in biodiesel yields as high as >99% at lower power density and ultrasound intensity when compared to ethanol or methanol based transesterification reactions.

Extractive-transesterification of algal lipids under microwave irradiation with hexane as solvent.

This study describes the use of microwaves (MW) for enhanced extractive-transesterification of algal lipids from dry algal biomass (Chlorella sp.). Two different single-step extractive-transesterification methods under MW irradiation were evaluated: (1) with ethanol as solvent/reactant and sodium hydroxide catalyst; and (2) with ethanol as reactant and hexane as solvent (sodium hydroxide catalyst). Biodiesel (fatty-acid-ethyl-esters, FAEE) yields from these two methods were compared with the conventional Bligh and Dyer (BD) method which followed a two-step extraction-transesterification process. The maximum lipid yields for MW, MW with hexane and BD methods were 20.1%, 20.1%, and 13.9%, respectively; while the FAEE conversion of the algal lipids were 96.2%, 94.3%, and 78.1%, respectively. The algae-biomass:ethanol molar ratio of 1:250-500 and 2.0-2.5% catalyst with reaction times around 6min were determined as optimum conditions for both methods. This study confers that the single-step non-conventional methods can contribute to higher algal lipid and FAEE yields.

Photosynthetic microbial desalination cells (PMDCs) for clean energy, water and biomass production.

Current microbial desalination cell (MDC) performances are evaluated with chemical catalysts such as ferricyanide, platinum catalyzed air-cathodes or aerated cathodes. All of these methods improve power generation potential in MDCs, however, they are not preferable for large scale applications due to cost, energy and environmental toxicity issues. In this study, performance of microbial desalination cells with an air cathode and an algae biocathode (Photosynthetic MDC - PMDC) were evaluated, both under passive conditions (no mechanical aeration or mixing). The results indicate that passive algae biocathodes perform better than air cathodes and enhance COD removal and utilize treated wastewater as the growth medium to obtain valuable biomass for high value bioproducts. Maximum power densities of 84 mW m(-3) (anode volume) or 151 mW m(-3) (biocathode volume) and a desalination rate of 40% were measured with 0.9 : 1 : 0.5 volumetric ratios of anode, desalination and algae biocathode chambers respectively. This first proof-of-concept study proves that the passive mechanisms can be beneficial in enhancing the sustainability of microbial desalination cells.

Potable water recovery from As, U, and F contaminated ground waters by direct contact membrane distillation process.

In this study, the feasibility of the direct contact membrane distillation (DCMD) process to recover arsenic, uranium and fluoride contaminated saline ground waters was investigated. Two types of membranes (polypropylene, PP; and polytetrafluoroethylene, PTFE) were tested to compare the permeate production rates and contaminant removal efficiencies. Several experiments were conducted to study the effect of salts, arsenic, fluoride and uranium concentrations (synthetic brackish water with salts: 1000-10,000 ppm; arsenic and uranium: 10-400 ppb; fluoride: 1-30 ppm) on the desalination efficiency. The effect of process variables such as feed flow rate, feed temperature and pore size was studied. The experimental results proved that the DCMD process is able to achieve over 99% rejection of the salts, arsenic, fluoride and uranium contaminants and produced a high quality permeate suitable for many beneficial uses. The ability to utilize the low grade heat sources makes the DCMD process a viable option to recover potable water from a variety of impaired ground waters.

Optimization of microwave-assisted transesterification of dry algal biomass using response surface methodology.

The effect of microwave irradiation on the simultaneous extraction and transesterification (in situ transesterification) of dry algal biomass to biodiesel was investigated. A high degree of oil/lipid extraction from dry algal biomass and an efficient conversion of the oils/lipids to biodiesel were demonstrated in a set of well-designed experimental runs. A response surface methodology (RSM) was used to analyze the influence of the process variables (dry algae to methanol (wt/vol) ratio, catalyst concentration, and reaction time) on the fatty acid methyl ester conversion. Based on the experimental results and RSM analysis, the optimal conditions for this process were determined as: dry algae to methanol (wt/vol) ratio of around 1:12, catalyst concentration about 2 wt.%, and reaction time of 4 min. The algal biodiesel samples were analyzed with GC-MS and thin layer chromatography (TLC) methods. Transmission electron microscopy (TEM) images of the algal biomass samples before and after the extraction/transesterification reaction are also presented.

Optimization of direct conversion of wet algae to biodiesel under supercritical methanol conditions.

This study demonstrated a one-step process for direct liquefaction and conversion of wet algal biomass containing about 90% of water to biodiesel under supercritical methanol conditions. This one-step process enables simultaneous extraction and transesterification of wet algal biomass. The process conditions are milder than those required for pyrolysis and prevent the formation of by-products. In the proposed process, fatty acid methyl esters (FAMEs) can be produced from polar phospholipids, free fatty acids, and triglycerides. A response surface methodology (RSM) was used to analyze the influence of the three process variables, namely, the wet algae to methanol (wt./vol.) ratio, the reaction temperature, and the reaction time, on the FAMEs conversion. Algal biodiesel samples were analyzed by ATR-FTIR and GC-MS. Based on the experimental analysis and RSM study, optimal conditions for this process are reported as: wet algae to methanol (wt./vol.) ratio of around 1:9, reaction temperature and time of about 255 °C, and 25 min respectively. This single-step process can potentially be an energy efficient and economical route for algal biodiesel production.