Pattern of volatile aldehydes and aromatic hydrocarbons in the largest urban rainforest in the Americas.

Atmospheric concentrations of aldehydes and monoaromatic hydrocarbons were determined in Tijuca Forest, the largest urban tropical forest in the Americas. The forest is a protected area, surrounded by the city of Rio de Janeiro. Data were also obtained in a commercial and a residential area for comparison. A total of 160 aldehyde samples and 60 BTEX (benzene, toluene, ethyl-benzene and xylenes) samples were collected from four locations between January and August of 2008. The aldehydes were collected using C18 resin cartridges coated with 2,4-dinitrophenylhydrazine and analyzed by high performance liquid chromatography (HPLC) with a diode array UV-Vis detector, while the BTEX samples were collected using tubes of coconut charcoal, which were then extracted with dichloromethane and analyzed by gas chromatography (GC). Within Tijuca Forest, formaldehyde and acetaldehyde levels were in the range of

Comparative study of automotive, aircraft and biogenic emissions of aldehydes and aromatic compounds.

Air samples were collected in three well characterized locations in the city of Rio de Janeiro, Brazil: downtown, the idle and taxi way areas of the national airport and an urban forest, where the main emissions are from vehicular, aircraft and biogenic sources, respectively. Aldehydes and BTEX concentrations show a characteristic profile which may be attributed to the emission sources. Formaldehyde/acetaldehyde ratios, in the early morning, were 1.39, 0.62 and 2.22 in downtown, airport and forest, respectively. Toluene/benzene ratios, for downtown, airport and forest areas, were 1.11, 1.82 and 1.06, respectively. The results show that the impact of the urban emissions on the forest is negligible as well as the impact of aircraft emissions over the urban area.