Green low-cost synthesis of zero-valent iron nanoparticles from Palm Petiole Extract for Cr(VI) removal from water.

One of the hottest research topics over the last decades was the valorization or/and recycling of agro-industrial wastes into different valuable liquid or solid products, which is considered a sustainable and low-cost approach. In this study, we developed zero-valent iron nanoparticles from Palm Petiole Extract (P-NZVI) using a green and straightforward approach. The as-synthesized P-NZVI was used to adsorb Cr(VI) in water. The physico-chemical characterizations of P-NZVI, including the particle size, crystalline structure, surface area, morphology, and functional groups, were investigated via several techniques such as UV-vis spectroscopy, SEM, TEM, XRD, FTIR, AFM, DLS, pHZPC measurement, and BET analysis. The adsorption performance of P-NZVI was studied under different operational parameters, including pollutant concentration, pH, temperature, and adsorbent mass. The adsorption rate was found to be 89.3% within 40 min, corresponding to the adsorption capacity of 44.47 mg/g under the following conditions: initial Cr(VI) concentration of 40 mg/L, pH 5, and a P-NZVI dosage of 1 g/L. It was found that the adsorption pattern follows the Langmuir and the pseudo-second-order kinetic models, indicating a combination of monolayer adsorption and chemisorption mechanisms. The thermodynamic study shows that the adsorption process is endothermic and spontaneous. The reusability of P-NZVI was carried out four times, showing a slight decrease from 89.3 to 87%. These findings highlight that P-NZVI's could be an effective green adsorbent for removing Cr(VI) or other types of toxic pollutants from water.

Sustainable and Green Synthesis of Iron Nanoparticles Supported on Natural Clays via Palm Waste Extract for Catalytic Oxidation of Crocein Orange G Mono Azoic Dye.

In this study, the removal of Crocein Orange G dye (COG) from aqueous solution was investigated using an innovative green catalyst to overcome problems with chemical techniques. Clay bentonite El Hamma (HB)-supported nanoscale zero-valent iron (NZVI) was used as a heterogeneous Fenton-like catalyst for the oxidation of harmful COG. Palm waste extract was herein used as a reducing and capping agent to synthesize NZVI, and HB clay was employed, which was obtained from the El Hamma bentonite deposit in the Gabes province of Tunisia. HB and HB-NZVI were characterized by various techniques such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer, Emmett, and Teller (BET), Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), X-ray diffraction (XRD), and zeta potential. Under optimal conditions, total degradation of COG was attained within 180 min. Kinetic studies showed that the dye degradation rate followed well the pseudo-second-order model. The apparent activation energy was 33.11 kJ/mol, which is typical of a physically controlled reaction. The degradation pathways and mineralization study revealed that the adsorption-Fenton-like reaction was the principal mechanism that demonstrated 100% degradation efficiency of COG even after three successive runs. Obtained results suggest that HB-NZVI is an affective heterogeneous catalyst for the degradation of COG by H2O2 and may constitute a sustainable green catalyst for azoic dye removal from industrial wastewaters.