Extreme precipitation stable isotopic compositions reveal unexpected summer monsoon incursions in the Qilian Mountains.

Isotope composition and moisture sources of precipitation are important for understanding water cycles and reconstructing paleoclimate. Based on 15-years' precipitation stable Isotope composition (δ18O and δ2H) from four stations of the Qilian Mountains, we found unique δ18O and δ2H features associated with the incursion of the summer monsoon over the Qilian Mountains, northwestern China. In 12 of the 15 years, similar seasonal variations of δ18O and δ2H confirmed a dominant source of moisture from Westerly circulation, and higher intercepts of the local meteoric water line (LMWL) indicated strong recycling of continental moisture. However, in August 2016 and 2018, extremely low slopes and intercepts of the LMWL, and more negative δ18O and δ2H revealed substantial contributions of the Asian summer monsoon to precipitation of the Qilian Mountains, with extremely heavy precipitation in August 2016. The column moisture flux, land-sea thermal contrast, correlations of precipitation δ18O with East Asian Summer Monsoon Index and Westerlies Index, HYSPLIT modeling results and precipitation δ18O along backward trajectories confirmed incursions of the summer monsoon in August 2016 and 2018. Our redefining of the boundary of the summer monsoon region confirmed the summer monsoon incursion zone can extend to the west of longitude 96°E and north of latitude 40°N in strong monsoon years, corresponding to boundaries of monsoon incursions in the mid-Holocene. Temperature correlated with precipitation δ18O at monthly and shorter time scales, but not for whole seasons or at yearly scale, revealing that summer monsoon incursions are therefore more likely than changing temperature to explain the multi-year cycles in the Qilian Mountains ice archives. Continent-scale shifts in atmospheric circulation strongly influence water resources in the Qilian mountains, and may change in frequency as climate warms. This study therefore has important implications for understanding water resources in the Qilian mountains in the past and into the future.

Seasonal variation and sources of atmospheric polycyclic aromatic hydrocarbons in a background site on the Tibetan Plateau.

The study of atmospheric polycyclic aromatic hydrocarbons (PAHs) in northeastern Tibetan Plateau with fragile ecological environment and complex atmospheric circulation system is blank. To understand the characteristics and sources of persistent organic pollutants in the atmosphere of the northeastern Tibetan Plateau, we monitored levels in the central Qilian Mountain. From 2016 to 2017, we collected 45-pair (particle + gas) samples using active air samplers to investigate the sources, transport paths, and their influencing factors. Sources of PAHs were analysed with a source diagnostic model, and atmospheric transport paths were calculated. The concentration range for ∑15PAHs was 439-4666 pg/m3, and the average was 2015 pg/m3. The PAHs in central Qilian Mountain are mainly low molecular weight (LMW) PAHs. Winter concentrations of PAHs were higher than those in summer. The transport of PAHs is mainly affected by westerlies, and there are seasonal differences. Source analysis showed that PAHs mainly came from coal and biomass combustion and vehicle emissions, with seasonal differences. This study clarifies the concentration and seasonal variation of PAHs in the northern Tibetan Plateau, which is conducive to understanding the atmospheric transport process and fate of pollutants. The background site of Qilian Mountains located in the Silk Road economic belt has the value and significance of long-term observation of pollutants.

Control of Mosses on Water Flux in an Alpine Shrub Site on the Qilian Mountains, Northwest China.

Mosses are an important component of the alpine shrub, but little is known about their contribution to ecosystem water and energy exchange, especially potential opportunities for alpine shrub expansion under a warming climate. We studied the role of mosses in alpine shrub evapotranspiration by conducting herb and moss removal experiments with different Potentilla fruticosa L. shrub coverage in the Qilian Mountains, Northwest China. The understory evapotranspiration was measured using lysimeters in different shrub coverage (dense shrub cover, medium shrub cover, and thin shrub cover) during the growing season of 2012. The understory evapotranspiration is about 1.61 mm per day in the control treatment (intact moss and herbs) during the growing season, and the evapotranspiration rates differed significantly between canopy covers. We found a 22% increase in evapotranspiration losses after removing the moss layer compared to the control treatment lysimeter with an intact moss layer in the shrub site. This suggests that most of the understory evaporation originated from the organic layer underlying the moss layer. Given this study's large moss evaporation rates, understory contributions cannot be ignored when interpreting eddy covariance data for the whole alpine ecosystem. Our results show that mosses may exert strong controls on understory water fluxes in alpine shrub meadow ecosystems and suggest that changes in moss cover may have significant consequences for season frozen soil thaw.

Characteristics of dissolved organic carbon and nitrogen in precipitation in the northern Tibetan Plateau.

Dissolved organic carbon (DOC) and nitrogen (N) play essential roles in global C and N cycles. To address the possible role of DOC and N in precipitation and enrich the related global database, the characteristics of DOC and N in precipitation were investigated in a typical remote permafrost region (upper Heihe River Basin) of the northern Tibetan Plateau (TP) from February 2019 to March 2020. The results demonstrated that the average DOC and total dissolved N (TDN) concentrations in the precipitation were 1.41 ± 1.09 µg mL-1 and 0.84 ± 0.48 µg mL-1, respectively, with relatively lower concentrations in the summer. The annual DOC and TDN fluxes were estimated to be 6.42 kg ha-1 yr-1 and 3.39 kg ha-1 yr-1, respectively, indicating that precipitation was a significant factor in C and N deposition. The light-absorbing properties of precipitation DOC from the SUVA254 and spectral slope revealed that precipitation DOC containing more aromatic components and lower molecular weights mostly was present during the summer; the mass cross-section (at the wavelength of 365 nm) ranged 0.26-1.84 m2 g-1, suggesting the potential impact of DOC on climatic forcing in the area. The principal component analysis combined with air mass backward trajectories indicated that the air masses from west Siberia, Central Asia, and northwestern China most significantly influenced the precipitation C and N in the study area. The WRF-Chem simulations and aerosol vertical distributions further illustrated the air mass transport pathways, demonstrating that dust and anthropogenic emissions could be transported over the studied area by westerlies and monsoonal winds. In the study basin, the precipitation deposition of DOC and N contributed largely to the riverine DOC and N exportation during the summer and had potential ecological effects. These results highlight the importance of DOC and N deposition from precipitation in the northern TP.

Riverine dissolved organic carbon and its optical properties in a permafrost region of the Upper Heihe River basin in the Northern Tibetan Plateau.

Riverine dissolved organic carbon (DOC) and its optical properties were investigated in two sub-river basins (Yeniugou and Hulugou river) of the Upper Heihe river basin in the northern Tibetan Plateau. The results showed that DOC concentrations ranged from 0.25 to 12.2 and 0.18-1.04 mg L-1 for Yeniugou and Hulugou river basin with an average of 0.82 and 0.33 mg L-1, respectively. Export of DOC from the studied river (YNG: ~0.86 Gg C yr-1) was lesser compared with other large river in the Tibetan Plateau and Arctic regions because of the small drainage area and lower DOC concentrations. There exhibited significant seasonality for DOC in Yeniugou river basin with higher values observed during late spring and summer; however, no such distinct trend was observed for DOC in the studied rivers of Hulugou river basin. In contrast, total dissolved nitrogen showed a slightly lower value during the summer season. A strong relationship was determined between DOC concentrations and spectral UV absorbance at 254 nm (SUVA254), absorption coefficients and spectral slope for both sub-river basins, attributing that the riverine DOM in the northern Tibetan Plateau has a remarkably high content of aromatic compounds in late spring and summer. Considering the less snow cover percentage, this study highlights the potential impacts of permafrost thaw on the riverine DOC and its characteristics in the permafrost region under climate change.

[Environmental significance of wet deposition composition in the central Qilian Mountains, China].

A total of 90 precipitation samples were collected from individual precipitation events at the Qilian Alpine Ecology & Hydrology Research Station (Hulugou Station, 30 degrees 47'N, 90 degrees 58'E; 3 260 m a. s. l) located in the central Qilian Mountains from August 2012 to November 2013. All samples were analyzed for major cations (Na, K+, Ca2+ and Mg2+), anions (Cl- , NO3- and SO4(2-)) and conductivity. Precipitation EC values ranged from 2.26 to 482 µS x cm(-1) with an average value of 41.9 µS x cm(-1). The precipitation was of SO4(2-) -Mg(2+) -Ca2+ type, which contributed > 70% to the total ionic concentration. The same as the precipitation alkalinity, precipitation events occurred around summer showed lower concentrations, while it had higher concentrations in winter and spring with little precipitation and larger wind speed. Enrichment factor (EF), correlation and factor analysis indicated that regional crustal aerosols and species from central Asian and northwestern China arid regions brought by the westerly circulation were the major sources for these ions, some dust from human pollution were the secondary sources, and the contribution of sea salt was the least due to the long distance transport. These characteristics could be also confirmed by the correlation between ionic concentrations and metrological data in the study region. It is also interesting that the precipitation chemistry was different under the different atmospheric circulation: the monsoon precipitation, the interaction precipitation events ( influenced both by monsoon and westerly) and the westerly precipitation.

[Measurement and estimation of grassland evapotranspiration in a mountainous region at the upper reach of Heihe River basin, China].

Evapotranspiration (ET) is an important component of water cycle, but its measurement in high altitude mountainous region is quite difficult, inducing the insufficient understanding on the actual ET in high altitude mountainous region and the effects of ET on this region' s water cycle. In this paper, two small type weighing mini-lysimeters were applied to measure the daily ET in a piece of grassland in a high altitude mountainous region of the Heihe River basin from July 1st, 2009 to June 30th, 2010. Based on the measured data, the methods of FAO-56 Penman-Monteith (F-P-M), Priestley-Taylor (P-T), and Hargreaves-Samani (H-S) were employed to estimate the ET to analyze the applicability of the three methods for the mountainous region, and the pan coefficient at the measurement spots was discussed. During the measurement period, the total annual ET at the measurement spots was 439.9 mm, accounting for 96.5% of the precipitation in the same period, and the ET showed an obvious seasonal distribution, being 389. 3 mm in May-October, accounting for 88. 5% of the annual value. All the three methods could be well applied to estimate the summer ET but not the winter ET, and their applicability followed the sequence of P-T > F-P-M > H-S. At the measurement spots, the daily pan coefficient in summer was 0.7-0. 8, while that in winter was quite variable.