Binding-Free Taste Visualization with Plasmonic Metasurfaces.

Taste sensors using photonics, termed artificial photonic tongues, have emerged as a promising platform for intuitive taste discrimination. However, the need for complex binding protocols for each taste profile limits their applicability to a narrow range of taste molecules. Here, we introduce an intriguing "binding-free" approach to molecular taste sensing using plasmonics, eliminating the requirement for physical or chemical binding protocols. We develop a wafer-scale plasmonic metasurface constructed by coating metallic nanoparticles in a scalable manner onto a metallic mirror. This metasurface functions to detect molecular refractive indices and surface tensions via 2D projection optical images of an array of liquid droplets containing the taste molecules on top, which can immediately visualize and distinguish between the five basic tastes of molecules (including their mixtures) as well as other additional spicy and alcoholic tastes. We anticipate that this intuitive and rapid taste-sensing approach has the potential to establish a user-friendly and portable taste-sensing platform.

Programmable directional color dynamics using plasmonics.

Adaptive multicolor filters have emerged as key components for ensuring color accuracy and resolution in outdoor visual devices. However, the current state of this technology is still in its infancy and largely reliant on liquid crystal devices that require high voltage and bulky structural designs. Here, we present a multicolor nanofilter consisting of multilayered 'active' plasmonic nanocomposites, wherein metallic nanoparticles are embedded within a conductive polymer nanofilm. These nanocomposites are fabricated with a total thickness below 100 nm using a 'lithography-free' method at the wafer level, and they inherently exhibit three prominent optical modes, accompanying scattering phenomena that produce distinct dichroic reflection and transmission colors. Here, a pivotal achievement is that all these colors are electrically manipulated with an applied external voltage of less than 1 V with 3.5 s of switching speed, encompassing the entire visible spectrum. Furthermore, this electrically programmable multicolor function enables the effective and dynamic modulation of the color temperature of white light across the warm-to-cool spectrum (3250 K-6250 K). This transformative capability is exceptionally valuable for enhancing the performance of outdoor optical devices that are independent of factors such as the sun's elevation and prevailing weather conditions.

Proton-Assisted Assembly of Colloidal Nanoparticles into Wafer-Scale Monolayers in Seconds.

Underwater adhesion processes in nature promise controllable assembly of functional nanoparticles for industrial mass production; However, their artificial strategies have faced challenges to uniformly transfer nanoparticles into a monolayer, particularly those below 100 nm in size, over large areas. Here a scalable "one-shot" self-limiting nanoparticle transfer technique is presented, enabling the efficient transport of nanoparticles from water in microscopic volumes to an entire 2-inch wafer in a remarkably short time of 10 seconds to reach near-maximal surface coverage (≈40%) in a 2D mono-layered fashion. Employing proton engineering in electrostatic assembly accelerates the diffusion of nanoparticles (over 50 µm2/s), resulting in a hundredfold faster coating speed than the previously reported results in the literature. This charge-sensitive process further enables "pick-and-place" nanoparticle patterning at the wafer scale, with large flexibility in surface materials, including flexible metal oxides and 3D-printed polymers. As a result, the fabrication of wafer-scale disordered plasmonic metasurfaces in seconds is successfully demonstrated. These metasurfaces exhibit consistent resonating colors across diverse material and geometrical platforms, showcasing their potential for applications in full-color painting and optical encryption devices.

Plasmonic Nanostructure Engineering with Shadow Growth.

Physical shadow growth is a vacuum deposition technique that permits a wide variety of 3D-shaped nanoparticles and structures to be fabricated from a large library of materials. Recent advances in the control of the shadow effect at the nanoscale expand the scope of nanomaterials from spherical nanoparticles to complex 3D shaped hybrid nanoparticles and structures. In particular, plasmonically active nanomaterials can be engineered in their shape and material composition so that they exhibit unique physical and chemical properties. Here, the recent progress in the development of shadow growth techniques to realize hybrid plasmonic nanomaterials is discussed. The review describes how fabrication permits the material response to be engineered and highlights novel functions. Potential fields of application with a focus on photonic devices, biomedical, and chiral spectroscopic applications are discussed.

Magnetically enhanced luminescence of CdSe/ZnS quantum dot light-emitting diodes using circular ferromagnetic Co/Pt multilayer disks.

We investigate the effect of a magnetic field on red, green, and blue CdSe/ZnS quantum dot light-emitting diodes (QDLEDs). Circular multilayer ferromagnetic cobalt/platinum (Co/Pt) disks are deposited on a MgF2 layer covering an Al electrode, and a perpendicular magnetic field is applied to the QDs in the active layer. Carriers injected into the active layer are then trapped and efficiently recombined inside the QDs because of strong carrier localization caused by the perpendicular magnetic field. The luminescence of the QDLEDs in the multilayer increases by 33.31% at 7.5 V, 22.34% at 7.5 V, and 16.73% at 7.0 V compared with that of QDLEDs without the multilayer. The time-resolved photoluminescence of all the QDLEDs also indicates that their increased luminescence results from improved radiative recombination through the stronger carrier localization in the QDs.

Improved efficiency of InGaN/GaN light-emitting diodes with perpendicular magnetic field gradients.

The effect of magnetic fields on the optical output power of flip-chip light-emitting diodes (LEDs) with InGaN/GaN multiple quantum wells (MQWs) was investigated. Films and circular disks comprising ferromagnetic cobalt/platinum (Co/Pt) multilayers were deposited on a p-ohmic reflector to apply magnetic fields in the direction perpendicular to the MQWs of the LEDs. At an injection current of 20 mA, the ferromagnetic Co/Pt multilayer film increased the optical output power of the LED by 20% compared to an LED without a ferromagnetic Co/Pt multilayer. Furthermore, the optical output power of the LED with circular disks was 40% higher at 20 mA than the output of the LED with a film. The increase of the optical output power of the LEDs featuring ferromagnetic Co/Pt multilayers is attributed to the magnetic field gradient in the MQWs, which increases the carrier path in the MQWs. The time-resolved photoluminescence measurement indicates that the improvement of optical output power is owing to an enhanced radiative recombination rate of the carriers in the MQWs as a result of the magnetic field gradient from the ferromagnetic Co/Pt multilayer.