White spill: Life cycle assessment approach to managing marine EPS litter from flood-released pontoons.

Expanded polystyrene (EPS) pollution in the marine environment is a pressing issue in Queensland, Australia due to a recent flood that scattered hundreds of EPS-containing pontoons along the coastline, causing severe ecological damage. To assist in the clean-up effort and provide crucial data for developing management guidelines, this study investigates the environmental performance of different end-of-life (EoL) disposal/recycling methods, including (i) landfill; (ii) on-site mechanical re-processing using a thermal densifier (MR); and (iii) on-site dissolution/precipitation using d-limonene (DP). Applying the life cycle assessment framework, the results showed that DP was the most environmentally favourable option. Its impacts in climate change (GWP), acidification (TAP), and fossil fuel depletion (FFD) were 612 kg CO2 eq, 4.3 kg SO2 eq, and 184.7 kg oil eq, respectively. For comparison, the impacts of landfilling EPS in these categories were found to be 700 kg CO2 eq, 3.5 kg SO2 eq, and 282 kg oil eq, respectively. Landfill also contributed considerably to eutrophication potential (MEP), at 3.77 kg N eq. Impacts from MR were most significant due to the need to transport the densifier unit to the site. The analysis also revealed that the transportation of personnel and heavy machinery to the site, was the biggest contributor to impacts in the EoL stage. Its impacts in GWP, TAP, MEP, and FFD were 1369.8 kg CO2 eq, 6.5 kg SO2 eq, 0.2189 kg N eq, and 497.7 kg oil eq, respectively. Monte Carlo analysis showed that the conclusions made from these results were stable and reliable. Limitations of this model and recommendations for future investigations were also discussed in this work.

Unlocking the potential of sulphide tailings: A comprehensive characterization study for critical mineral recovery.

Sulphide tailings are a major environmental concern due to acid mine drainage and heavy metal leaching, with costly treatments that lack economic benefits. Reprocessing these wastes for resource recovery can address pollution while creating economic opportunities. This study aimed to evaluate the potential for critical mineral recovery by characterizing sulphide tailings from a Zn-Cu-Pb mining site. Advanced analytical tools, such as electron microprobe analysis (EMPA) and scanning electron microscopy (SEM)-based energy dispersive spectroscopy (EDS), were utilized to determine the physical, geochemical, and mineralogical properties of the tailings. The results showed that the tailings were fine-grained (∼50 wt% below 63 µm) and composed of Si (∼17 wt%), Ba (∼13 wt%), and Al, Fe, and Mn (∼6 wt%). Of these, Mn, a critical mineral, was analyzed for recovery potential, and it was found to be largely contained in rhodochrosite (MnCO3) mineral. The metallurgical balance revealed that ∼93 wt% of Mn was distributed in -150 + 10 µm size fractions containing 75% of the total mass. Additionally, the mineral liberation analysis indicated that Mn-grains were primarily liberated below 106 µm size, suggesting the need for light grinding of above 106 µm size to liberate the locked Mn minerals. This study demonstrates the potential of sulphide tailings as a source for critical minerals, rather than being a burden, and highlights the benefits of reprocessing them for a resource recovery to address both environmental and economic concerns.

Generation and consequence of nano/microplastics from medical waste and household plastic during the COVID-19 pandemic.

Since the end of 2019, the world has faced a major crisis because of the outbreak of COVID-19 disease which has created a severe threat to humanity. To control this pandemic, the World Health Organization gave some guidelines like wearing PPE (personal protective equipment) (e.g., face masks, overshoes, gloves), social distancing, hand hygiene and shutting down all modes of public transport services. During this pandemic, plastic products (e.g., household plastics, PPE and sanitizer bottles) have substantially prevented the spread of this virus. Since the outbreak, approximately 1.6 million tons of plastic waste have been generated daily. However, single-use PPE like face masks (N95), surgical masks and hand gloves contain many non-biodegradable plastics materials. These abandoned products have created a huge number of plastic debris which ended up as microplastics (MPs) followed by nanoplastics (NPs) in nature that are hazardous to the eco-system. These MPs and NPs also act as vectors for the various pathogenic contaminants. The goal of this review is to offer an extensive discussion on the formation of NPs and MPs from all of these abandoned plastics and their long-term impact on the environment as well as human health. This review paper also attempts to assess the present global scenario and the main challenge of waste management to reduce the potential NP/MPs pollution to improve the eco-systems.

Nano/microplastics: Fragmentation, interaction with co-existing pollutants and their removal from wastewater using membrane processes.

NANO: and microplastic (NP/MP) is one of the most challenging types of micropollutants, coming from either direct release or degradation of plastic items into ecosystems. NP/MP can adsorb hazardous pollutants (such as heavy metals and pharmaceutical compounds) and pathogens onto their surface that are consumed by humans, animals, and aquatic living organisms. This paper presents the interaction of NP/MP with other pollutants in the water environment and mechanisms involved to enable the ultimate fate of NP/MP as well as the effectiveness of metal-organic frame (MOF)-based membrane over conventional membrane processes for NP/MP removal. It is found that conventional membranes could remove MPs when their size is usually more than 1000 nm, but they are ineffective in removing NPs. These NPs have potentially greater health impacts due to their greater surface area. MOF-based membrane could effectively remove both NP and MP due to its large porous structure, high adsorption capacity, and low density. This paper also discusses some challenges associated with MOF-based membranes for NP/MP removal. Finally, we conclude a specific MOF-based ultrafiltration membrane (ED-MIL-101 (Cr)) that can potentially remove both negative and positive charged NP/MP from wastewater by electrostatic attraction and repulsion force with efficient water permeability.

Development of a geospatial database of tailing storage facilities in Australia using satellite images.

Tailings storage facilities (TSFs) are the main source of pollution from mining operations. However, TSFs are increasingly being considered as the potential secondary sources of some critical minerals. Recovering the critical minerals from TSFs is important due to both environmental and economic implications. Yet, identification of the potential TSFs is the major challenge in this venture due to the lack of publicly available database of TSFs. The objective of this study was to identify the TSFs and document their status in the form of a database for Australia. Visual inspection and interpretation of satellite images in Google Earth were used to identify the TSFs in 6 states and the publicly available database of TSFs for Western Australia (WA) was validated in this study to incorporate into a national-level database. This study has identified 331 active and 759 inactive TSFs in Australia. Among the sites, 42 active and 56 inactive mine sites with TSFs were found within 2 km of urban centres in the studied states. Coal and gold were the major commodities of 27% of active mine sites with the TSFs and 38% of inactive mine sites with TSFs, respectively. Approximately 16% of active mine sites with TSFs and 28% of inactive mine sites with TSFs were found to process copper as a major commodity. Considering the companionability matrix, many of these TSFs could be explored for the possible recovery of critical minerals (e.g. rare earth elements, cobalt). This study has developed a national-level database of TSFs for Australia for the first time, and it could be used for a number of applications.

Understanding the fate of nano-plastics in wastewater treatment plants and their removal using membrane processes.

Nanoplastics (NPs) have become a major environmental issue due to their adverse effect on the water environment. Wastewater treatment plant (WWTP) is considered as one of the main sources for breaking down of larger-sized plastic debris and microplastics (MPs) into NPs. This study aims to provide a comprehensive understanding of NPs generation in the WWTPs, their physiochemical characteristics and interaction with the WWTPs. It is found that cracking is the major mechanism of plastics fragmentation in the WWTPs. This review also discusses the current membrane process used for NPs removal. It is found that conventional membrane processes are ineffective as they are not designed for NPs removal and fouling is a major obstacle for its application. Therefore, this study concludes by providing an outlook of developing a bio-nanofiltration process that can be used as a tertiary treatment for removing NPs and other components present in water. Such a process can produce NPs-free water for non-potable use or safe discharge into open waterways.

Designing optimal integrated electricity supply configurations for renewable hydrogen generation in Australia.

The high variability and intermittency of wind and solar farms raise questions of how to operate electrolyzers reliably, economically, and sustainably using predominantly or exclusively variable renewables. To address these questions, we develop a comprehensive cost framework that extends to include factors such as performance degradation, efficiency, financing rates, and indirect costs to assess the economics of 10 MW scale alkaline and proton-exchange membrane electrolyzers to generate hydrogen. Our scenario analysis explores a range of operational configurations, considering (i) current and projected wholesale electricity market data from the Australian National Electricity Market, (ii) existing solar/wind farm generation curves, and (iii) electrolyzer capital costs/performance to determine costs of H2 production in the near (2020-2040) and long term (2030-2050). Furthermore, we analyze dedicated off-grid integrated electrolyzer plants as an alternate operating scenario, suggesting oversizing renewable nameplate capacity with respect to the electrolyzer to enhance operational capacity factors and achieving more economical electrolyzer operation.

Application of a life cycle assessment to compare environmental performance in coal mine tailings management.

This study compares coal mine tailings management strategies using life cycle assessment (LCA) and land-use area metrics methods. Hybrid methods (the Australian indicator set and the ReCiPe method) were used to assess the environmental impacts of tailings management strategies. Several strategies were considered: belt filter press (OPT 1), tailings paste (OPT 2), thickened tailings (OPT 3), and variations of OPT 1 using combinations of technology improvement and renewable energy sources (OPT 1A-D). Electrical energy was found to contribute more than 90% of the environmental impacts. The magnitude of land-use impacts associated with OPT 3 (thickened tailings) were 2.3 and 1.55 times higher than OPT 1 (tailings cake) and OPT 2 (tailings paste) respectively, while OPT 1B (tailings belt filter press with technology improvement and solar energy) and 1D (tailings belt press filter with technology improvement and wind energy) had the lowest ratio of environmental impact to land-use. Further analysis of an economic cost model and reuse opportunities is required to aid decision making on sustainable tailings management and industrial symbiosis.