Assessing the uptake and accumulation of heavy metals and particulate matter from ambient air by some tree species in Isfahan Metropolis, Iran.

The main scope of this study is to evaluate the uptake and accumulation potential of heavy metals in unwashed and washed leaves and particulate matter (PM) in leaf surfaces plus waxes of different tree species in Isfahan city. The highest mean concentrations of Cd, Cr, and Ni in unwashed and washed leaves were detected in M. nigra, Zn and Cu in P. fraxinifolia, and Pb was related to P. orientalis. The highest and lowest mean total depositions of total particulate matter (sum of PM10, PM2.5, and PM0.2) were found in the leaf of M. nigra (190.23 ± 23.5) and S. alba (11.9 ± 4.42 µg/cm2), respectively. The maximum bio-concentration factor (BCF) of Cd, Pb, and Ni was observed in Morus nigra; Cu and Zn in Pterocarya fraxinifolia, with the BCF of Cr found in Acer negundo. Comprehensive bio-concentration index (CBCI) and metal accumulation index (MAI) were applied for comparing different tree species in HMs accumulation from soil and ambient air. The highest CBCI was measured for M. nigra (0.86), so this tree has the potential to remediate metals from the polluted soil. Higher MAI values in washed and unwashed leaves were found in S. alba (6.77 and 6.98) and M. nigra (5.93 and 5.62), demonstrating the high capability of these trees for controlling air born-metal pollution. Based on the AOM factor, M. nigra, P. fraxinifolia, U. umbraculifera, P. fraxinifolia, A. altissima, and M. alba trees had the highest ability to capture Cd, Zn, Cu, Ni, Pb, and Cr from air. So, planting these trees would be beneficial in sensitive and critical zones such as industrial and urban areas with such atmospheric pollutants.

Seasonal variations of polycyclic aromatic hydrocarbons in coastal sediments of a marine resource hot spot: the case of pars special economic energy zone, Iran.

Polycyclic aromatic hydrocarbons (PAHs) are an important group of compounds of major environmental concern, which are in the class of persistent organic pollutants. Therefore, the key purpose of this research was to analyze seasonal fluctuations and to determine the probability of polycyclic aromatic hydrocarbons in coastal sediments of the Iranian Marine Resource Center based on the evaluation of 16 US-EPA important PAH compounds. These compounds have been collected from intertidal sediments located in the marine resources of southern Iran in different seasons. These samples of the surficial sediment were collected at the PSEEZ area using a stainless steel grab sampler in four seasons, from depths between 0.5 and 30 m. Surface sediment samples were removed by spoons and carefully placed in an aluminum foil; they were taken to the laboratory on ice and held at 20° C until their study. After extraction, by using a rotary evaporator apparatus, samples were condensed. The assay was added to roughly 2 g of activated copper flasks in the refrigerator for 36 h for desulfurization. Among different seasons, the highest concentration was observed in winter, with a mean of 281.3 ng g-1. According to ecological risk assessment (concentrations of possible effects, low effect range, degree of threshold effects, and median effect range), PAH risks in surface sediments of PSEEZ were lower than the threshold results levels (TEL), possible effects levels (PEL), low range of effects (ERL), and median range of effects (ERM), indicating that a biological effect would rarely occur. The dry weight scale of the concentration of ∑PAHs ranges from 145.7 to 348.42 ng g-1 with a mean quantity of 260.52 ng g-1. Therefore, according to the amount of ∑PAH concentration, the sediments in the PSEEZ area indicated moderate to heavy pollutions. In this way, the sedimentary surface ecosystems of the Persian Gulf were considered as moderately polluted compared with other ecosystems worldwide. Our study highlighted some of the research gaps in PAH contamination studies and the level of PAH contamination. Therefore, this study will provide a scientific background, planning, and policies for PAH pollution control and environmental protection in Iran and similar regions around the world.