1.
RSC Adv
; 12(22): 14018-14021, 2022 May 05.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35548388
RESUMO
In the current work, the reactions of [60]fullerene with alkynes promoted by OH- (base) are addressed. The treatment of C60 with alkynes in the presence of TBAOH produces alkynylation products (R-C60-H) with high selectivity in o-DCB at 100 °C. Plausible reaction mechanisms were proposed. This work provides a convenient and environmental friendly method for the functionalization of fullerenes.