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Macromol Rapid Commun ; 32(23): 1925-9, 2011 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-22002727

RESUMO

Cryo-electron microscopy, atomic force microscopy, and light microscopy investigations provide experimental evidence that amphiphilic emulsion copolymerization particles change their morphology in dependence on concentration. The shape of the particles is spherical at solids content above 1%, but it changes to rod-like, ring-like, and web-like structures at lower concentrations. In addition, the shape and morphology of these particles at low concentrations are not fixed but very flexible and vary with time between spheres, flexible pearl-necklace structures, and stretched rods.


Assuntos
Emulsões/química , Polímeros/química , Polímeros/síntese química , Microscopia Crioeletrônica , Microscopia de Força Atômica , Tamanho da Partícula
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