Sustainability in Membrane Technology: Membrane Recycling and Fabrication Using Recycled Waste.

Membrane technology has shown a promising role in combating water scarcity, a globally faced challenge. However, the disposal of end-of-life membrane modules is problematic as the current practices include incineration and landfills as their final fate. In addition, the increase in population and lifestyle advancement have significantly enhanced waste generation, thus overwhelming landfills and exacerbating environmental repercussions and resource scarcity. These practices are neither economically nor environmentally sustainable. Recycling membranes and utilizing recycled material for their manufacturing is seen as a potential approach to address the aforementioned challenges. Depending on physiochemical conditions, the end-of-life membrane could be reutilized for similar, upgraded, and downgraded operations, thus extending the membrane lifespan while mitigating the environmental impact that occurred due to their disposal and new membrane preparation for similar purposes. Likewise, using recycled waste such as polystyrene, polyethylene terephthalate, polyvinyl chloride, tire rubber, keratin, and cellulose and their derivates for fabricating the membranes can significantly enhance environmental sustainability. This study advocates for and supports the integration of sustainability concepts into membrane technology by presenting the research carried out in this area and rigorously assessing the achieved progress. The membranes' recycling and their fabrication utilizing recycled waste materials are of special interest in this work. Furthermore, this study offers guidance for future research endeavors aimed at promoting environmental sustainability.

Reverse osmosis membrane functionalized with aminated graphene oxide and polydopamine nanospheres plugging for enhanced NDMA rejection and anti-fouling performance.

The use of reverse osmosis (RO) for water reclamation has become an essential part of the water supply owing to the ever-increasing water demand and the utmost performance of the RO membranes. Despite the global RO implementation, its inferior rejection against low molecular weight contaminants of emerging concerns (CECs) (i.e., N-nitrosodimethylamine (NDMA)) and propensity to fouling remain bottle-neck thus affecting process robustness for water reuse. This study aims to enhance both the rejection and antifouling properties of the RO membrane. Herein for the first time, we report RO membrane modification using polydopamine nanospheres (PDAns) followed by aminated-graphene oxide (AGO) deposition as an effective approach to overcome these challenges. The modification of the RO membrane using PDAns-AGO resulted in 89.3 ± 2.7% rejection compared to the pristine RO membrane which demonstrated 69.2 ± 2.1% NDMA rejection. This significant improvement can be ascribed to the plugging and shielding of defective areas (formed during interfacial polymerization) of the polyamide layer through active PDAns and AGO layers and to the added sieving mechanism that arose through narrow channels of the AGO owing to its reduction. Moreover, the in-situ and non-destructive fouling monitoring using optical coherence tomography (OCT) revealed that the PDAns-AGO coating enhanced both the anti-scaling and anti-biofouling characteristics. The improved hydrophilicity and bactericidal effect together with roughness and surface charge suppression synergistically enhanced anti-fouling properties. This study provides a new direction for safe and cost-effective water reuse practices. The membrane with high selectivity against CECs such as NDMA has the potential to eliminate permeate staging using second pass RO and other advanced oxidation processes which are utilized as a tertiary treatment to make reclaimed water suitable for potable/non-potable application.

Modified Electrospun Membranes Using Different Nanomaterials for Membrane Distillation.

Obtaining fresh drinking water is a challenge directly related to the change in agricultural, industrial, and societal demands and pressure. Therefore, the sustainable treatment of saline water to get clean water is a major requirement for human survival. In this review, we have detailed the use of electrospun nanofiber-based membranes (ENMs) for water reclamation improvements with respect to physical and chemical modifications. Although membrane distillation (MD) has been considered a low-cost water reclamation process, especially with the availability of low-grade waste heat sources, significant improvements are still required in terms of preparing efficient membranes with enhanced water flux, anti-fouling, and anti-scaling characteristics. In particular, different types of nanomaterials have been explored as guest molecules for electrospinning with different polymers. Nanomaterials such as metallic organic frameworks (MOFs), zeolites, dioxides, carbon nanotubes (CNTs), etc., have opened unprecedented perspectives for the implementation of the MD process. The integration of nanofillers gives appropriate characteristics to the MD membranes by changing their chemical and physical properties, which significantly enhances energy efficiency without impacting the economic costs. Here, we provide a comprehensive overview of the state-of-the-art status, the opportunities, open challenges, and pitfalls of the emerging field of modified ENMs using different nanomaterials for desalination applications.

Modification of Liquid Separation Membranes Using Multidimensional Nanomaterials: Revealing the Roles of Dimension Based on Classical Titanium Dioxide.

Membrane technology has become increasingly popular and important for separation processes in industries, as well as for desalination and wastewater treatment. Over the last decade, the merger of nanotechnology and membrane technology in the development of nanocomposite membranes has emerged as a rapidly expanding research area. The key motivation driving the development of nanocomposite membranes is the pursuit of high-performance liquid separation membranes that can address the bottlenecks of conventionally used polymeric membranes. Nanostructured materials in the form of zero to three-dimensions exhibit unique dimension-dependent morphology and topology that have triggered considerable attention in various fields. While the surface hydrophilicity, antibacterial, and photocatalytic properties of TiO2 are particularly attractive for liquid separation membranes, the geometry-dependent properties of the nanocomposite membrane can be further fine-tuned by selecting the nanostructures with the right dimension. This review aims to provide an overview and comments on the state-of-the-art modifications of liquid separation membrane using TiO2 as a classical example of multidimensional nanomaterials. The performances of TiO2-incorporated nanocomposite membranes are discussed with attention placed on the special features rendered by their structures and dimensions. The innovations and breakthroughs made in the synthesis and modifications of structure-controlled TiO2 and its composites have enabled fascinating and advantageous properties for the development of high-performance nanocomposite membranes for liquid separation.

Electrosprayed CNTs on Electrospun PVDF-Co-HFP Membrane for Robust Membrane Distillation.

In this investigation, the electrospraying of CNTs on an electrospun PVDF-Co-HFP membrane was carried out to fabricate robust membranes for the membrane distillation (MD) process. A CNT-modified PVDF-Co-HFP membrane was heat pressed and characterized for water contact angle, liquid entry pressure (LEP), pore size distribution, tensile strength, and surface morphology. A higher water contact angle, higher liquid entry pressure (LEP), and higher tensile strength were observed in the electrosprayed CNT-coated PVDF-Co-HFP membrane than in the pristine membrane. The MD process test was conducted at varying feed temperatures using a 3.5 wt. % simulated seawater feed solution. The CNT-modified membrane showed an enhancement in the temperature polarization coefficient (TPC) and water permeation flux up to 16% and 24.6%, respectively. Field-effect scanning electron microscopy (FESEM) images of the PVDF-Co-HFP and CNT-modified membranes were observed before and after the MD process. Energy dispersive spectroscopy (EDS) confirmed the presence of inorganic salt ions deposited on the membrane surface after the DCMD process. Permeate water quality and rejection of inorganic salt ions were quantitatively analyzed using ion chromatography (IC) and inductively coupled plasma-mass spectrometry (ICP-MS). The water permeation flux during the 24-h continuous DCMD operation remained constant with a >99.8% inorganic salt rejection.

Natural and recycled materials for sustainable membrane modification: Recent trends and prospects.

Despite water being critical for human survival, its uneven distribution, and exposure to countless sources of pollution make water shortages increasingly urgent. Membrane technology offers an efficient solution for alleviating the water shortage impact. The selectivity and permeability of membranes can be improved by incorporating additives of different nature and size scales. However, with the vast debate about the environmental and economic feasibility of the common nanoscale materials in water treatment applications, we can infer that there is a long way before the first industrial nanocomposite membrane is commercialized. This stumbling block has motivated the scientific community to search for alternative modification routes and/or materials with sustainable features. Herein, we present a pragmatic review merging the concept of sustainability, nanotechnology, and membrane technology through the application of natural additives (e.g., Clays, Arabic Gum, zeolite, lignin, Aquaporin), recycled additives (e.g., Biochar, fly ash), and recycled waste (e.g., Polyethylene Terephthalate, recycled polystyrene) for polymeric membrane synthesis and modification. Imparted features on polymeric membranes, induced by the presence of sustainable natural and waste-based materials, are scrutinized. In addition, the strategies harnessed to eliminate the hurdles associated with the application of these nano and micro size additives for composite membranes modification are elaborated. The expanding research efforts devoted recently to membrane sustainability and the prospects for these materials are discussed. The findings of the investigations reported in this work indicate that the application of natural and waste-based additives for composite membrane fabrication/modification is a nascent research area that deserves the attention of both research and industry.

Biomolecule-Enabled Liquid Separation Membranes: Potential and Recent Progress.

The implementation of membrane surface modification to enhance the performance of membrane-based separation has become a favored strategy due to its promise to address the trade-off between water permeability and salt rejection as well as to improve the durability of the membranes. Tremendous work has been committed to modifying polymeric membranes through physical approaches such as surface coating and ontology doping, as well as chemical approaches such as surface grafting to introduce various functional groups to the membrane. In the context of liquid separation membranes applied for desalination and water and wastewater treatment, biomolecules have gained increasing attention as membrane-modifying agents due to their intriguing structural properties and chemical functionalities. Biomolecules, especially carbohydrates and proteins, exhibit attractive features, including high surface hydrophilicity and zwitterionic and antimicrobial properties that are desired for liquid separation membranes. In this review, we provide an overview of the recent developments in biomolecule-enabled liquid separation membranes. The roles and potentials of some commonly explored biomolecules in heightening the performance of polymeric membranes are discussed. With the advancements in material synthesis and the need to answer the call for more sustainable materials, biomolecules could serve as attractive alternatives for the development of high-performance composite membranes.

Advances in Membrane Distillation Module Configurations.

Membrane Distillation (MD) is a membrane-based, temperature-driven water reclamation process. While research emphasis has been largely on membrane design, upscaling of MD has prompted advancements in energy-efficient module design and configurations. Apart from the four conventional configurations, researchers have come up with novel MD membrane module designs and configurations to improve thermal efficiency. While membrane design has been the focus of many studies, development of appropriate system configurations for optimal energy efficiency for each application has received considerable attention, and is a critical aspect in advancing MD configurations. This review assesses advancements in modified and novel MD configurations design with emphasis on the effects of upscaling and pilot scale studies. Improved MD configurations discussed in this review are the material gap MD, conductive gap MD, permeate gap MD, vacuum-enhanced AGMD/DCMD, submerged MD, flashed-feed MD, dead-end MD, and vacuum-enhanced multi-effect MD. All of these modified MD configurations are designed either to reduce the heat loss by mitigating the temperature polarization or to improve the mass transfer and permeate flux. Vacuum-enhanced MD processes and MD process with non-contact feed solution show promise at the lab-scale and must be further investigated. Hollow fiber membrane-based pilot scale modules have not yet been sufficiently explored. In addition, comparison of various configurations is prevented by a lack of standardized testing conditions. We also reflect on recent pilot scale studies, ongoing hurdles in commercialization, and niche applications of the MD process.

Membrane Technologies for Nitrogen Recovery from Waste Streams: Scientometrics and Technical Analysis.

The concerns regarding the reactive nitrogen levels exceeding the planetary limits are well documented in the literature. A large portion of anthropogenic nitrogen ends in wastewater. Nitrogen removal in typical wastewater treatment processes consumes a considerable amount of energy. Nitrogen recovery can help in saving energy and meeting the regulatory discharge limits. This has motivated researchers and industry professionals alike to devise effective nitrogen recovery systems. Membrane technologies form a fundamental part of these systems. This work presents a thorough overview of the subject using scientometric analysis and presents an evaluation of membrane technologies guided by literature findings. The focus of nitrogen recovery research has shifted over time from nutrient concentration to the production of marketable products using improved membrane materials and designs. A practical approach for selecting hybrid systems based on the recovery goals has been proposed. A comparison between membrane technologies in terms of energy requirements, recovery efficiency, and process scale showed that gas permeable membrane (GPM) and its combination with other technologies are the most promising recovery techniques and they merit further industry attention and investment. Recommendations for potential future search trends based on industry and end users' needs have also been proposed.

Surface Design of Liquid Separation Membrane through Graft Polymerization: A State of the Art Review.

Surface modification of membranes is an effective approach for imparting unique characteristics and additional functionalities to the membranes. Chemical grafting is a commonly used membrane modification technique due to its versatility in tailoring and optimizing the membrane surface with desired functionalities. Various types of polymers can be precisely grafted onto the membrane surface and the operating conditions of grafting can be tailored to further fine-tune the membrane surface properties. This review focuses on the recent strategies in improving the surface design of liquid separation membranes through grafting-from technique, also known as graft polymerization, to improve membrane performance in wastewater treatment and desalination applications. An overview on membrane technology processes such as pressure-driven and osmotically driven membrane processes are first briefly presented. Grafting-from surface chemical modification approaches including chemical initiated, plasma initiated and UV initiated approaches are discussed in terms of their features, advantages and limitations. The innovations in membrane surface modification techniques based on grafting-from techniques are comprehensively reviewed followed by some highlights on the current challenges in this field. It is concluded that grafting-from is a versatile and effective technique to introduce various functional groups to enhance the surface properties and separation performances of liquid separation membranes.

Evaluating Fertilizer-Drawn Forward Osmosis Performance in Treating Anaerobic Palm Oil Mill Effluent.

Fertilizer-drawn forward osmosis (FDFO) is a potential alternative to recover and reuse water and nutrients from agricultural wastewater, such as palm oil mill effluent that consists of 95% water and is rich in nutrients. This study investigated the potential of commercial fertilizers as draw solution (DS) in FDFO to treat anaerobic palm oil mill effluent (An-POME). The process parameters affecting FO were studied and optimized, which were then applied to fertilizer selection based on FO performance and fouling propensity. Six commonly used fertilizers were screened and assessed in terms of pure water flux (Jw) and reverse salt flux (JS). Ammonium sulfate ((NH4)2SO4), mono-ammonium phosphate (MAP), and potassium chloride (KCl) were further evaluated with An-POME. MAP showed the best performance against An-POME, with a high average water flux, low flux decline, the highest performance ratio (PR), and highest water recovery of 5.9% for a 4-h operation. In a 24-h fouling run, the average flux decline and water recovered were 84% and 15%, respectively. Both hydraulic flushing and osmotic backwashing cleaning were able to effectively restore the water flux. The results demonstrated that FDFO using commercial fertilizers has the potential for the treatment of An-POME for water recovery. Nevertheless, further investigation is needed to address challenges such as JS and the dilution factor of DS for direct use of fertigation.

The emerging role of 3D printing in water desalination.

Unmatched flexibility in terms of material selection, design and scalability, along with gradually decreasing cost, has led 3D printing to gain significant attention in various water treatment and desalination applications. In desalination, 3D printing has been applied to improve the energy efficiency of existing technologies. For thermal desalination, this involves the use of 3D printed components that enhance water evaporation and energy harvesting with new materials and designs. For membrane-based desalination, 3D printing offers membranes and other module components with customized materials and geometries for better fouling resistance and productivity. This review highlights the current status, advances and challenges associated with 3D printing in both thermal and membrane-based desalination technologies. Other unique benefits offered by 3D printing for water desalination along with the associated challenges are also discussed in this review. Finally, the future prospects and research directions are highlighted related to the application of 3D printing in the water desalination industry.

Green Approaches for Sustainable Development of Liquid Separation Membrane.

Water constitutes one of the basic necessities of life. Around 71% of the Earth is covered by water, however, not all of it is readily available as fresh water for daily consumption. Fresh water scarcity is a chronic issue which poses a threat to all living things on Earth. Seawater, as a natural resource abundantly available all around the world, is a potential water source to fulfil the increasing water demand. Climate-independent seawater desalination has been touted as a crucial alternative to provide fresh water. While the membrane-based desalination process continues to dominate the global desalination market, the currently employed membrane fabrication materials and processes inevitably bring adverse impacts to the environment. This review aims to elucidate and provide a comprehensive outlook of the recent efforts based on greener approaches used for desalination membrane fabrication, which paves the way towards achieving sustainable and eco-friendly processes. Membrane fabrication using green chemistry effectively minimizes the generation of hazardous compounds during membrane preparation. The future trends and recommendations which could potentially be beneficial for researchers in this field are also highlighted.

Strategies in Forward Osmosis Membrane Substrate Fabrication and Modification: A Review.

Forward osmosis (FO) has been recognized as the preferred alternative membrane-based separation technology for conventional water treatment technologies due to its high energy efficiency and promising separation performances. FO has been widely explored in the fields of wastewater treatment, desalination, food industry and bio-products, and energy generation. The substrate of the typically used FO thin film composite membranes serves as a support for selective layer formation and can significantly affect the structural and physicochemical properties of the resultant selective layer. This signifies the importance of substrate exploration to fine-tune proper fabrication and modification in obtaining optimized substrate structure with regards to thickness, tortuosity, and porosity on the two sides. The ultimate goal of substrate modification is to obtain a thin and highly selective membrane with enhanced hydrophilicity, antifouling propensity, as well as long duration stability. This review focuses on the various strategies used for FO membrane substrate fabrication and modification. An overview of FO membranes is first presented. The extant strategies applied in FO membrane substrate fabrications and modifications in addition to efforts made to mitigate membrane fouling are extensively reviewed. Lastly, the future perspective regarding the strategies on different FO substrate layers in water treatment are highlighted.

Ceramic Microfiltration Membranes in Wastewater Treatment: Filtration Behavior, Fouling and Prevention.

Nowadays, integrated microfiltration (MF) membrane systems treatment is becoming widely popular due to its feasibility, process reliability, commercial availability, modularity, relative insensitivity in case of wastewater of various industrial sources as well as raw water treatment and lower operating costs. The well thought out, designed and implemented use of membranes can decrease capital cost, reduce chemical usage, and require little maintenance. Due to their resistance to extreme operating conditions and cleaning protocols, ceramic MF membranes are gradually becoming more employed in the drinking water and wastewater treatment industries when compared with organic and polymeric membranes. Regardless of their many advantages, during continuous operation these membranes are susceptible to a fouling process that can be detrimental for successful and continuous plant operations. Chemical and microbial agents including suspended particles, organic matter particulates, microorganisms and heavy metals mainly contribute to fouling, a complex multifactorial phenomenon. Several strategies, such as chemical cleaning protocols, turbulence promoters and backwashing with air or liquids are currently used in the industry, mainly focusing around early prevention and treatment, so that the separation efficiency of MF membranes will not decrease over time. Other strategies include combining coagulation with either inorganic or organic coagulants, with membrane treatment which can potentially enhance pollutants retention and reduce membrane fouling.

Unlocking the application potential of forward osmosis through integrated/hybrid process.

Study of forward osmosis (FO) has been increasing steadily over recent years with applications mainly focusing on desalination and wastewater treatment processes. The working mechanism of FO lies in the natural movement of water between two streams with different osmotic pressure, which makes it useful in concentrating or diluting solutions. FO has rarely been operated as a stand-alone process. Instead, FO processes often appear in a hybrid or integrated form where FO is combined with other treatment technologies to achieve better overall process performance and cost savings. This article aims to provide a comprehensive review on the need for hybridization/integration for FO membrane processes, with emphasis given to process enhancement, draw solution regeneration, and pretreatment for FO fouling mitigation. In general, integrated/hybrid FO processes can reduce the membrane fouling propensity; prepare the solution suitable for subsequent value-added uses and production of renewable energy; lower the costs associated with energy consumption; enhance the quality of treated water; and enable the continuous operation of FO through the regeneration of draw solution. The future potential of FO lies in the success of how it can be hybridized or integrated with other technologies to minimize its own shortcomings, while enhancing the overall performance.

The role of wastewater treatment plants as tools for SARS-CoV-2 early detection and removal.

The world is facing the third coronavirus caused pandemic in less than twenty years. The SARS-CoV-2 virus not only affects the human respiratory system, but also the gastrointestinal tract. The virus has been found in human feces, in sewage and in wastewater treatment plants. It has the potential to become a panzootic disease, as it is now proven that several mammalian species become infected. Since it has been shown that the virus can be detected in sewage even before the onset of symptoms in the local population, Wastewater Based Epidemiology should be developed not only to localize infection clusters of the primary wave but also to detect a potential second, or subsequent, wave. To prevent a panzootic, virus removal techniques from wastewater need to be implemented to prevent the virus dissemination into the environment. In that context, this review presents recent improvements in all the fields of wastewater treatment from treatment ponds to the use of algae or nanomaterials with a particular emphasis on membrane-based techniques.

Novel low-fouling membranes from lab to pilot application in textile wastewater treatment.

A novel antifouling coating based on the polymerization of a polymerisable bicontinuous microemulsion (PBM) was developed and applied for commercially available membranes for textile wastewater treatment. PBM coating was produced by polymerizing, on a polyethersulfone (PES) membrane, a bicontinuous microemulsion, realized by finely tuning its properties in terms of chemical composition and polymerization temperature. In particular, the PBM was prepared by using, as the surfactant component, inexpensive and commercially available dodecyltrimethylammonium bromide (DTAB). The coating exhibited a more hydrophilic and a smoother surface in comparison to uncoated PES surface, making the produced PBM membranes more resistant and less prone to be affected by fouling. The anti-fouling potential of PBM membranes was assessed by using humic acid (HA) as a model foulant, evaluating the water permeability decrease as an indicator of the fouling propensity of the membranes. PBM membrane performances in terms of dye rejection, when applied for model textile wastewater treatment, were also evaluated and compared to PES commercial ones. The PBM membranes were finally successfully scaled-up (total membrane area 0.33 m2) and applied in a pilot membrane bioreactor (MBR) unit for the treatment of real textile wastewater.

Atomic force microscopy studies of bioprocess engineering surfaces - imaging, interactions and mechanical properties mediating bacterial adhesion.

The detrimental effect of bacterial biofilms on process engineering surfaces is well documented. Thus, interest in the early stages of bacterial biofilm formation; in particular bacterial adhesion and the production of anti-fouling coatings has grown exponentially as a field. During this time, Atomic force microscopy (AFM) has emerged as a critical tool for the evaluation of bacterial adhesion. Due to its versatility AFM offers not only insight into the topographical landscape and mechanical properties of the engineering surfaces, but elucidates, through direct quantification the topographical and biomechnical properties of the foulants The aim of this review is to collate the current research on bacterial adhesion, both theoretical and practical, and outline how AFM as a technique is uniquely equipped to provide further insight into the nanoscale world at the bioprocess engineering surface.

Treatment of textile wastewater by submerged membrane bioreactor: In vitro bioassays for the assessment of stress response elicited by raw and reclaimed wastewater.

The performance of a pilot-scale membrane bioreactor (MBR) system for the treatment of textile wastewater was investigated. The MBR was continuously operated for 7 months. Very high treatment efficiencies were achieved (color, 100%; chemical oxygen demand (COD), 98%; biochemical oxygen demand (BOD5), 96%; suspended solids (SS), 100%). Furthermore, the MBR treatment efficiency was analyzed from a toxicological-risk assessment point of view, via different In vitro bioassays using Caco-2 cells, a widely used cell model in toxicological studies. Results showed that MBR treatment significantly reduced the raw textile wastewater (RTWW) cytotoxicity on Caco-2 cells by 53% for a hydraulic retention time (HRT) of 2 days. Additionally, the RTWW-induced disruption in the barrier function (BF) of the Caco-2 cell monolayer was also significantly reduced after MBR treatment under a HRT of 2 days (no disruption of BF was observed). Moreover, the effect of RTWW and treated wastewater on stress response was investigated using different stress genes: AHSA1, HSPD1, HSPA1A, HSPA5 and HSPA8. The cell exposure to RTWW significantly increased the expression of all used stress genes; interestingly, the treated wastewater (HRT 2 days) did not show any significant modulation of the stress genes.