Mapping electric field components of superchiral field with photo-induced force.

Circular dichroism (CD) of materials, difference in absorbance of left- and right-circularly polarized light, is a standard measure of chirality. Detection of the chirality for individual molecules is a frontier in analytical chemistry and optical science. The usage of a superchiral electromagnetic field near metallic structure is one promising way because it boosts the molecular far-field CD signal. However, it is still elusive as to how such a field actually interacts with the molecules. The cause is that the distribution of the electric field vector is unclear in the vicinity of the metal surface. In particular, it is difficult to directly measure the localized field, e.g., using aperture-type scanning near-field optical microscope. Here, we calculate the three-dimensional (3D) electric field vector, including the longitudinal field, and reveal the whole figure of the near-field CD on a two-dimensional (2D) plane just above the metal surface. Moreover, we propose a method to measure the near-field CD of the whole superchiral field by photo-induced force microscopy (PiFM), where the optical force distribution is mapped in a scanning 2D plane. We numerically demonstrate that, although the presence of the metallic probe tip affects the 3D electric field distribution, the PiFM is sufficiently capable to evaluate the superchiral field. Unveiling the whole figure of near-field is significantly beneficial in obtaining rich information of single molecules with multiple orientations and in analyzing the boosted far-field CD signals.

Nanoscale rotational optical manipulation.

Light has momentum, and hence, it can move small particles. The optical tweezer, invented by Ashkin et al. [Opt. Lett. 11, 288 (1986)] is a representative application. It traps and manipulates microparticles and has led to great successes in the biosciences. Currently, optical manipulation of "nano-objects" is attracting growing attention, and new techniques have been proposed and realized. For flexible manipulation, push-pull switching [Phys. Rev. Lett. 109, 087402 (2012)] and super-resolution trapping by using the electronic resonance of nano-objects have been proposed [ACS Photonics 5, 318 (2017)]. However, regarding the "rotational operation" of nano-objects, the full potential of optical manipulation remains unknown. This study proposes mechanisms to realize rotation and direction switching of nano-objects in macroscopic and nanoscopic areas. By controlling the balance between the dissipative force and the gradient force by using optical nonlinearity, the direction of the macroscopic rotational motion of nano-objects is switched. Further, conversion between the spin angular momentum and orbital angular momentum by light scattering through localized surface plasmon resonance in metallic nano-complexes induces optical force for rotational motion in the nanoscale area. This study pieces out fundamental operations of the nanoscale optical manipulation of nanoparticles.