1.
Chemistry
; 20(49): 16093-6, 2014 Dec 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25339137
RESUMO
Without extra addition of sulfinate salt, allylic sulfones were synthesized by palladium-catalyzed cross-coupling of aryl iodide with N-tosylhydrazone. In this transformation, not only the diazo compound but also the sulfinate salt, which were both generated in situ from base-mediated decomposition of the N-tosylhydrazone, was used as nucleophilic partner.