Elaborating the mechanism of lead adsorption by biochar: Considering the impacts of water-washing and freeze-drying in preparing biochar.

This paper examined the impacts of different pretreatments on the characteristics of biochar and its adsorption behavior for Pb2+. Biochar with combined pretreatment of water-washing and freeze-drying (W-FD-PB) performed a maximum adsorption capacity for Pb2+ of 406.99 mg/g, higher than that of 266.02 mg/g on water-washing pretreated biochar (W-PB) and 188.21 mg/g on directly pyrolyzed biochar (PB). This is because the water-washing process partially removed the K and Na, resulting in the relatively enriched Ca and Mg on W-FD-PB. And the freeze-drying pretreatment broke the fiber structure of pomelo peel, favoring the development of a fluffy surface and large specific surface area during pyrolysis. Quantitative mechanism analysis implied that cation ion exchange and precipitation were the driving forces in Pb2+ adsorption on biochar, and both mechanisms were enhanced during Pb2+ adsorption on W-FD-PB. Furthermore, adding W-FD-PB to Pb-contaminated soil increased the soil pH and significantly reduced the availability of Pb.

Regulation of tourmaline-mediated Fenton-like system by biochar: Free radical pathway to non-free radical pathway.

The heterogeneous Fenton-like systems induced by Fe-containing minerals have been largely applied for the degradation of organic pollutants. However, few studies have been conducted on biochar (BC) as an additive to Fenton-like systems mediated by iron-containing minerals. In this study, the addition of BC prepared at different temperatures was found to significantly enhance the degradation of contaminants in the tourmaline-mediated Fenton-like system (TM/H2O2) using Rhodamine B (RhB) as the target contaminant. Furthermore, the hydrochloric acid-modified BC prepared at 700 °C (BC700(HCl)) could achieve complete degradation of high concentrations of RhB in the BC700(HCl)/TM/H2O2 system. Free radical quenching experiments showed that TM/H2O2 system removed contaminants mainly mediated by the free radical pathway. After adding BC, the removal of contaminants is mainly mediated by the non-free radical pathway in BC700(HCl)/TM/H2O2 system which was confirmed by the Electron paramagnetic resonance (EPR) experiments and electrochemical impedance spectroscopy (EIS). In addition, BC700(HCl) had broad feasibility in the degradation of other organic pollutants (Methylene Blue (MB) 100%, Methyl Orange (MO) 100%, and tetracycline (TC) 91.47%) in the tourmaline-mediated Fenton-like system. Possible pathways for the degradation of RhB by the BC700(HCl)/TM/H2O2 system were also proposed.

Fabrication, application, and mechanism of metal and heteroatom co-doped biochar composites (MHBCs) for the removal of contaminants in water: A review.

The potential risk of various contaminants in water has recently attracted public attention. Biochars and modified biochars have been widely developed for environmental remediation. Metal and heteroatom co-doped biochar composites (MHBCs) quickly caught the interest of researchers with more active sites and higher affinity for contaminants compared to single-doped biochar by metal or heteroatoms. This study provides a comprehensive review of MHBCs in wastewater decontamination. Firstly, the main fabrication methods of MHBCs were external doping and internal doping, with external doping being the most common. Secondly, the applications of MHBCs as adsorbents and catalysts in water treatment were introduced emphatically, which mainly included the removal of metals, antibiotics, dyes, pesticides, phenols, and other organic contaminants. Thirdly, the removal mechanisms of contaminants by MHBCs were deeply discussed in adsorption, oxidation and reduction, and degradation. Furthermore, the influencing factors for the removal of contaminants by MHBCs were also summarized, including the physicochemical properties of MHBCs, and environmental variables of pH and co-existing substance. Finally, futural challenges of MHBCs are proposed in the leaching toxicity of metal from MHBCs, the choice of heteroatoms on the fabrication for MHBCs, and the application in the composite system and soil remediation.