Indicators for resource recovery monitoring within the circular economy model implementation in the wastewater sector.

The European Union is currently in the process of transformation toward a circular economy model in which different areas of activity should be integrated for more efficient management of raw materials and waste. The wastewater sector has a great potential in this regard and therefore is an important element of the transformation process to the circular economy model. The targets of the circular economy policy framework such as resource recovery are tightly connected with the wastewater treatment processes and sewage sludge management. With this in view, the present study aims to review existing indicators on resource recovery that can enable efficient monitoring of the sustainable and circular solutions implemented in the wastewater sector. Within the reviewed indicators, most of them were focused on technological aspects of resource recovery processes such as nutrient removal efficiency, sewage sludge processing methods and environmental aspects as the pollutant share in the sewage sludge or its ashes. Moreover, other wide-scope indicators such as the wastewater service coverage or the production of bio-based fertilizers and hydrochar within the wastewater sector were analyzed. The results were used for the development of recommendations for improving the resources recovery monitoring framework in the wastewater sector and a proposal of a circularity indicator for a wastewater treatment plant highlighting new challenges for further researches and wastewater professionals.

Microbial community dynamics linked to enhanced substrate availability and biogas production of electrokinetically pre-treated waste activated sludge.

The restricted hydrolytic degradation rate of complex organic matter presents a considerable challenge in anaerobic digestion of waste activated sludge (WAS). Within this context, application of pre-treatment of digester substrate has potential for improved waste management and enhanced biogas production. Anaerobic degradation of untreated or electrokinetically pre-treated WAS was performed in two pilot-scale digesters for 132days. WAS electrokinetically pre-treated with energy input 0.066kJ/kg sludge was used in a first phase of operation and WAS pre-treated with energy input 0.091kJ/kg sludge was used in a second phase (each phase lasted at least three hydraulic retention times). Substrate characteristics before and after pre-treatment and effects on biogas digester performance were comprehensively analysed. To gain insights into influences of altered substrate characteristics on microbial communities, the dynamics within the bacterial and archaeal communities in the two digesters were investigated using 16S rRNA gene sequencing (pyrosequencing) and quantitative PCR (qPCR). Specific primers targeting dominant operation taxonomic units (OTUs) and members of the candidate phylum Cloacimonetes were designed to further evaluate their abundance and dynamics in the digesters. Electrokinetic pre-treatment significantly improved chemical oxygen demand (COD) and carbohydrate solubility and increased biogas production by 10-11% compared with untreated sludge. Compositional similarity of the bacterial community during initial operation and diversification during later operation indicated gradual adaptation of the community to the higher solubility of organic material in the pre-treated substrate. Further analyses revealed positive correlations between gene abundance of dominant OTUs related to Clostridia and Cloacimonetes and increased substrate availability and biogas production. Among the methanogens, the genus Methanosaeta dominated in both digesters. Overall, the results showed that electrokinetic pre-treatment of WAS increases substrate solubility and biogas production. Changes in bacterial community composition and abundances of dominant bacterial OTUs were observed during anaerobic degradation of pre-treated WAS, whereas the relative abundance of methanogenic community members remained stable.

Comparing the influence of low power ultrasonic and microwave pre-treatments on the solubilisation and semi-continuous anaerobic digestion of waste activated sludge.

Anaerobic digestion is a well-known technique for the recovery of energy from waste sludge. Pre-treatment methods are useful tools to improve the biodegradability of the sludge and to enhance the digestion efficiency. In this study, an ultrasound (US) and a microwave (MW) pre-treatment were compared in a long-term digestion experiment, using 3 small pilot scale semi-continuous digesters (SRT=20 days). A specific energy of 96 kJ/kg sludge was applied, hence enabling to compare the effectiveness of both pre-treatment methods towards sludge solubilisation and biogas production enhancement. Total and volatile solids (TS and VS), COD, carbohydrates and proteins were monitored throughout the digestion experiment. It was seen that US was most effective in COD solubilisation. The average biogas increment was 20% for the microwave pre-treatment and 27% for the ultrasonic pre-treatment. However, this additional biogas production did not outweigh the energy consumed by the pre-treatment, leading to a negative energy balance.

Influence of microwave pre-treatment on sludge solubilization and pilot scale semi-continuous anaerobic digestion.

Anaerobic digestion is widely applied for the recovery of energy from waste activated sludge. Pre-treatment methods are of high interest to increase the biodegradability of the sludge and to enhance the digestion efficiency. This paper studies the application of a microwave pre-treatment. An experimental set-up of two pilot scale semi-continuous digesters was used. During a long term experiment, one of the reactors was fed with untreated sludge, while microwave pre-treated sludge (336 kJ/kg sludge) was introduced in the second one. A solid retention time of 20 days was kept during the experiments. (Organic) dry solids, carbohydrates, proteins and volatile fatty acids were monitored during digestion. It was seen that the microwave pre-treatment resulted in an effective solubilization of the organic matter in the sludge. The changes to the sludge composition resulted in an increase in biogas production by 50%, while the methane concentration in both reactors remained stable.

Effects of ultrasonic pre-treatment on sludge characteristics and anaerobic digestion.

In this work, the influence of an ultrasonic pre-treatment on anaerobic digestion of waste activated sludge is studied. Attention is paid to the solubilisation of the main organic (proteins, carbohydrates) and inorganic (heavy metals) sludge components during ultrasonic treatment and the influence of the dry solids content (DS) on the degree of solubilisation. The second part of the paper focuses on the relationship between the applied specific energy of the ultrasonic treatment and methane production. In general, a higher specific energy and a higher DS content are beneficial for the release of organic matter, resulting in an increased methane production. The efficiency of the subsequent anaerobic digestion is similar for both sludge types (2.1 and 3.2% DS). However, at lower DS contents (2.1%), the methane production increase was more significant.