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1.
Science ; 382(6672): 792-796, 2023 Nov 17.
Artigo em Inglês | MEDLINE | ID: mdl-37972183

RESUMO

Upon cooling, condensed-matter systems typically transition into states of lower symmetry. The converse-i.e., the emergence of higher symmetry at lower temperatures-is extremely rare. In this work, we show how an unusually isotropic magnetoresistance in the highly anisotropic, one-dimensional conductor Li0.9Mo6O17 and its temperature dependence can be interpreted as a renormalization group (RG) flow toward a so-called separatrix. This approach is equivalent to an emergent symmetry in the system. The existence of two distinct ground states, Mott insulator and superconductor, can then be traced back to two opposing RG trajectories. By establishing a direct link between quantum field theory and an experimentally measurable quantity, we uncover a path through which emergent symmetry might be identified in other candidate materials.

2.
Nat Commun ; 14(1): 4150, 2023 Jul 12.
Artigo em Inglês | MEDLINE | ID: mdl-37438333

RESUMO

The quantum vortex liquid (QVL) is an intriguing state of type-II superconductors in which intense quantum fluctuations of the superconducting (SC) order parameter destroy the Abrikosov lattice even at very low temperatures. Such a state has only rarely been observed, however, and remains poorly understood. One of the key questions is the precise origin of such intense quantum fluctuations and the role of nearby non-SC phases or quantum critical points in amplifying these effects. Here we report a high-field magnetotransport study of FeSe1-xSx and FeSe1-xTex which show a broad QVL regime both within and beyond their respective electron nematic phases. A clear correlation is found between the extent of the QVL and the strength of the superconductivity. This comparative study enables us to identify the essential elements that promote the QVL regime in unconventional superconductors and to demonstrate that the QVL regime itself is most extended wherever superconductivity is weakest.

3.
Nature ; 595(7869): 661-666, 2021 07.
Artigo em Inglês | MEDLINE | ID: mdl-34321672

RESUMO

Strange metals possess highly unconventional electrical properties, such as a linear-in-temperature resistivity1-6, an inverse Hall angle that varies as temperature squared7-9 and a linear-in-field magnetoresistance10-13. Identifying the origin of these collective anomalies has proved fundamentally challenging, even in materials such as the hole-doped cuprates that possess a simple bandstructure. The prevailing consensus is that strange metallicity in the cuprates is tied to a quantum critical point at a doping p* inside the superconducting dome14,15. Here we study the high-field in-plane magnetoresistance of two superconducting cuprate families at doping levels beyond p*. At all dopings, the magnetoresistance exhibits quadrature scaling and becomes linear at high values of the ratio of the field and the temperature, indicating that the strange-metal regime extends well beyond p*. Moreover, the magnitude of the magnetoresistance is found to be much larger than predicted by conventional theory and is insensitive to both impurity scattering and magnetic field orientation. These observations, coupled with analysis of the zero-field and Hall resistivities, suggest that despite having a single band, the cuprate strange-metal region hosts two charge sectors, one containing coherent quasiparticles, the other scale-invariant 'Planckian' dissipators.

4.
Chemosphere ; 265: 129132, 2021 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-33307506

RESUMO

Here, we evaluated the levels of As, Hg, Pb, and Cd in shark meat sold along the Amazon Coast of Brazil and used nitrogen stable isotope values to determine trophic position and to assess element biomagnification. From market samples, a total of 13 species were identified via molecular analysis, including those listed as endangered and vulnerable by the IUCN Red List. Arsenic was present in significantly higher concentrations than all other elements, followed by Hg, with the highest mean concentrations recorded in M. higmani (As: 19.46 ± 8.79 µg/g ww) and C. acronotus (Hg: 1.12 ± 0.68 µg/g ww). Lead and Cd were recorded at much lower levels in all species. The EWI of individual elements were above PTWI for all species when considering Hg, seven species for inorganic arsenic (iAs), and one species for Pb. The weekly consumption of 10 species should be reduced to less than 416.39 g, which is equivalent to the daily estimated fish consumption rate in the region. The mean (±SD) δ15N values of species ranged from 10.7 ± 0.51‰ in M. higmani to 14.2 ± 0.59‰ in C. porosus, indicating feeding over >1 trophic level. Arsenic was negatively correlated with δ15N values, while Hg was positively correlated indicating biodilution and biomagnification, respectively. Our results indicate that the sale and consumption of shark meat will expose consumers to potentially harmful levels of iAs and Hg, as well as contributing to the population decline of species including those that are currently categorized as threatened.


Assuntos
Mercúrio , Tubarões , Poluentes Químicos da Água , Animais , Brasil , Ecossistema , Monitoramento Ambiental , Peixes , Cadeia Alimentar , Humanos , Carne , Mercúrio/análise , Poluentes Químicos da Água/análise
5.
Phys Rev Lett ; 124(10): 107001, 2020 Mar 13.
Artigo em Inglês | MEDLINE | ID: mdl-32216412

RESUMO

We present resistivity and thermal-conductivity measurements of superconducting FeSe in intense magnetic fields up to 35 T applied parallel to the ab plane. At low temperatures, the upper critical field µ_{0}H_{c2}^{ab} shows an anomalous upturn, while thermal conductivity exhibits a discontinuous jump at µ_{0}H^{*}≈24 T well below µ_{0}H_{c2}^{ab}, indicating a first-order phase transition in the superconducting state. This demonstrates the emergence of a distinct field-induced superconducting phase. Moreover, the broad resistive transition at high temperatures abruptly becomes sharp upon entering the high-field phase, indicating a dramatic change of the magnetic-flux properties. We attribute the high-field phase to the Fulde-Ferrel-Larkin-Ovchinnikov (FFLO) state, where the formation of planar nodes gives rise to a segmentation of the flux-line lattice. We point out that strongly orbital-dependent pairing as well as spin-orbit interactions, the multiband nature, and the extremely small Fermi energy are important for the formation of the FFLO state in FeSe.

6.
Sci Adv ; 5(7): eaar8027, 2019 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-31281877

RESUMO

We report on an emerging symmetry axis in the magnetoresistance of bulk single crystals of quasi-one-dimensional Li0.9Mo6O17 below T min = 25 K, the temperature at which the electrical resistivity experiences a minimum. Detailed angle-dependent magnetoresistance sweeps reveal that this symmetry axis is induced by the development of a negative magnetoresistance, which is suppressed only for magnetic fields oriented along the poles of the MoO6 octahedra that form the conducting chains. We show that this unusual negative magnetoresistance is consistent with the melting of dark excitons, composed of previously omitted orbitals within the t 2g manifold that order below T min. The unveiled symmetry axis in directional magnetic fields not only provides evidence for the crystallization of these dark excitons but also sheds new light on the long-standing mystery of the metal-insulator transition in Li0.9Mo6O17.

7.
Nature ; 567(7747): 213-217, 2019 03.
Artigo em Inglês | MEDLINE | ID: mdl-30760921

RESUMO

Correlated electron systems are highly susceptible to various forms of electronic order. By tuning the transition temperature towards absolute zero, striking deviations from conventional metallic (Fermi-liquid) behaviour can be realized. Evidence for electronic nematicity, a correlated electronic state with broken rotational symmetry, has been reported in a host of metallic systems1-5 that exhibit this so-called quantum critical behaviour. In all cases, however, the nematicity is found to be intertwined with other forms of order, such as antiferromagnetism5-7 or charge-density-wave order8, that might themselves be responsible for the observed behaviour. The iron chalcogenide FeSe1-xSx is unique in this respect because its nematic order appears to exist in isolation9-11, although until now, the impact of nematicity on the electronic ground state has been obscured by superconductivity. Here we use high magnetic fields to destroy the superconducting state in FeSe1-xSx and follow the evolution of the electrical resistivity across the nematic quantum critical point. Classic signatures of quantum criticality are revealed: an enhancement in the coefficient of the T2 resistivity (due to electron-electron scattering) on approaching the critical point and, at the critical point itself, a strictly T-linear resistivity that extends over a decade in temperature T. In addition to revealing the phenomenon of nematic quantum criticality, the observation of T-linear resistivity at a nematic critical point also raises the question of whether strong nematic fluctuations play a part in the transport properties of other 'strange metals', in which T-linear resistivity is observed over an extended regime in their respective phase diagrams.

8.
Rep Prog Phys ; 81(5): 052501, 2018 05.
Artigo em Inglês | MEDLINE | ID: mdl-29353812

RESUMO

The iron-based high temperature superconductors share a number of similarities with their copper-based counterparts, such as reduced dimensionality, proximity to states of competing order, and a critical role for 3d electron orbitals. Their respective temperature-doping phase diagrams also contain certain commonalities that have led to claims that the metallic and superconducting (SC) properties of both families are governed by their proximity to a quantum critical point (QCP) located inside the SC dome. In this review, we critically examine these claims and highlight significant differences in the bulk physical properties of both systems. While there is now a large body of evidence supporting the presence of a (magnetic) QCP in the iron pnictides, the situation in the cuprates is much less apparent, at least for the end point of the pseudogap phase. We argue that the opening of the normal state pseudogap in cuprates, so often tied to a putative QCP, arises from a momentum-dependent breakdown of quasiparticle coherence that sets in at much higher doping levels but which is driven by the proximity to the Mott insulating state at half filling. Finally, we present a new scenario for the cuprates in which this loss of quasiparticle integrity and its evolution with momentum, temperature and doping plays a key role in shaping the resultant phase diagram.

9.
Phys Rev Lett ; 121(25): 256602, 2018 Dec 21.
Artigo em Inglês | MEDLINE | ID: mdl-30608835

RESUMO

We report a study of quantum oscillations in the high-field magnetoresistance of the nodal-line semimetal HfSiS. In the presence of a magnetic field up to 31 T parallel to the c axis, we observe quantum oscillations originating both from orbits of individual electron and hole pockets, and from magnetic breakdown between these pockets. In particular, we reveal a breakdown orbit enclosing one electron and one hole pocket in the form of a "figure of eight," which is a manifestation of Klein tunneling in momentum space, although in a regime of partial transmission due to the finite separation between the pockets. The observed very strong dependence of the oscillation amplitude on the field angle and the cyclotron masses of the orbits are in agreement with the theoretical predictions for this novel tunneling phenomenon.

10.
Nat Commun ; 8: 15001, 2017 04 13.
Artigo em Inglês | MEDLINE | ID: mdl-28406142

RESUMO

In many layered metals, coherent propagation of electronic excitations is often confined to the highly conducting planes. While strong electron correlations and/or proximity to an ordered phase are believed to be the drivers of this electron confinement, it is still not known what triggers the loss of interlayer coherence in a number of layered systems with strong magnetic fluctuations, such as cuprates. Here, we show that a definitive signature of interlayer coherence in the metallic-layered triangular antiferromagnet PdCrO2 vanishes at the Néel transition temperature. Comparison with the relevant energy scales and with the isostructural non-magnetic PdCoO2 reveals that the interlayer incoherence is driven by the growth of short-range magnetic fluctuations. This establishes a connection between long-range order and interlayer coherence in PdCrO2 and suggests that in many other low-dimensional conductors, incoherent interlayer transport also arises from the strong interaction between the (tunnelling) electrons and fluctuations of some underlying order.

11.
Phys Rev Lett ; 117(25): 256601, 2016 Dec 16.
Artigo em Inglês | MEDLINE | ID: mdl-28036219

RESUMO

We report a high-field magnetotransport study of an ultrahigh mobility (µ[over ¯]≈25×10^{6} cm^{2} V^{-1} s^{-1}) n-type GaAs quantum well. We observe a strikingly large linear magnetoresistance (LMR) up to 33 T with a magnitude of order 10^{5}% onto which quantum oscillations become superimposed in the quantum Hall regime at low temperature. LMR is very often invoked as evidence for exotic quasiparticles in new materials such as the topological semimetals, though its origin remains controversial. The observation of such a LMR in the "simplest system"-with a free electronlike band structure and a nearly defect-free environment-excludes most of the possible exotic explanations for the appearance of a LMR and rather points to density fluctuations as the primary origin of the phenomenon. Both, the featureless LMR at high T and the quantum oscillations at low T follow the empirical resistance rule which states that the longitudinal conductance is directly related to the derivative of the transversal (Hall) conductance multiplied by the magnetic field and a constant factor α that remains unchanged over the entire temperature range. Only at low temperatures, small deviations from this resistance rule are observed beyond ν=1 that likely originate from a different transport mechanism for the composite fermions.

12.
J Fish Biol ; 88(6): 2144-56, 2016 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-27245624

RESUMO

In Bimini, Bahamas, the consistent employment of longlines, beginning in 1982, provided a rare opportunity to explore population trends for large resident sharks. This study assessed three shallow water longline survey periods at this location; 1982-1989, 1992-2002 and 2003-2014, with the aim of determining trends in annual catch per unit effort (CPUE) for an IUCN listed near-threatened species, the lemon shark Negaprion brevirostris. A general additive model (GAM) was used to analyse the non-linear annual CPUE values over the entire 32-year research period. The GAM displayed high variability of annual CPUE, with a peak value of 0·026 N. brevirostris per hook day (hooks day(-1) ) in 2000. The temporal pattern of CPUE indicated an abundance trend with a complete cycle, from trough to trough, occurring over a period of approximately 18 years. The 1982-1989 survey period saw the highest proportion of mature individuals (19·8%) and the smallest average pre-caudal length (LPC ; 124·8 cm). The 1992-2002 survey period had the highest average annual CPUE (0·018 hooks day(-1) ), while the 2003-2014 research period saw largest average LPC size (134·8 cm) and the lowest average CPUE values (0·009 hooks day(-1) ) of the entire research period. The long-term trend identified in this study provides a baseline for future assessment.


Assuntos
Tubarões/fisiologia , Migração Animal , Animais , Oceano Atlântico , Bahamas , Ecossistema , Espécies em Perigo de Extinção , Densidade Demográfica , Comportamento Sexual Animal
13.
Nat Commun ; 7: 10903, 2016 Mar 29.
Artigo em Inglês | MEDLINE | ID: mdl-27020134

RESUMO

The magnetic field-induced changes in the conductivity of metals are the subject of intense interest, both for revealing new phenomena and as a valuable tool for determining their Fermi surface. Here we report a hitherto unobserved magnetoresistive effect in ultra-clean layered metals, namely a negative longitudinal magnetoresistance that is capable of overcoming their very pronounced orbital one. This effect is correlated with the interlayer coupling disappearing for fields applied along the so-called Yamaji angles where the interlayer coupling vanishes. Therefore, it is intrinsically associated with the Fermi points in the field-induced quasi-one-dimensional electronic dispersion, implying that it results from the axial anomaly among these Fermi points. In its original formulation, the anomaly is predicted to violate separate number conservation laws for left- and right-handed chiral (for example, Weyl) fermions. Its observation in PdCoO2, PtCoO2 and Sr2RuO4 suggests that the anomaly affects the transport of clean conductors, in particular near the quantum limit.

14.
Nat Commun ; 5: 3280, 2014.
Artigo em Inglês | MEDLINE | ID: mdl-24518054

RESUMO

In the quest to increase the critical temperature Tc of cuprate superconductors, it is essential to identify the factors that limit the strength of superconductivity. The upper critical field Hc2 is a fundamental measure of that strength, yet there is no agreement on its magnitude and doping dependence in cuprate superconductors. Here we show that the thermal conductivity can be used to directly detect Hc2 in the cuprates YBa2Cu3Oy, YBa2Cu4O8 and Tl2Ba2CuO6+δ, allowing us to map out Hc2 across the doping phase diagram. It exhibits two peaks, each located at a critical point where the Fermi surface of YBa2Cu3Oy is known to undergo a transformation. Below the higher critical point, the condensation energy, obtained directly from Hc2, suffers a sudden 20-fold collapse. This reveals that phase competition-associated with Fermi-surface reconstruction and charge-density-wave order-is a key limiting factor in the superconductivity of cuprates.

15.
Sci Rep ; 3: 3261, 2013 Nov 20.
Artigo em Inglês | MEDLINE | ID: mdl-24253025

RESUMO

The nature of the electronic state of a metal depends strongly on its dimensionality. In a system of isolated conducting chains, the Fermi-liquid (quasiparticle) description appropriate for higher dimensions is replaced by the so-called Tomonaga-Luttinger liquid picture characterized by collective excitations of spin and charge. Temperature is often regarded as a viable tuning parameter between states of different dimensionality, but what happens once thermal broadening becomes comparable to the interchain hopping energy remains an unresolved issue, one that is central to many organic and inorganic conductors. Here we use the ratio of the thermal to electrical conductivities to probe the nature of the electronic state in PrBa2Cu4O8 as a function of temperature. We find that despite the interchain transport becoming non-metallic, the charge carriers within the CuO chains appear to retain their quasiparticle nature. This implies that temperature alone cannot induce a crossover from Fermi-liquid to Tomonaga-Luttinger-liquid behaviour in quasi-one-dimensional metals.

16.
Phys Rev Lett ; 108(18): 187003, 2012 May 04.
Artigo em Inglês | MEDLINE | ID: mdl-22681108

RESUMO

The upper critical field H(c2) of purple bronze Li0:9Mo6O17 is found to exhibit a large anisotropy, in quantitative agreement with that expected from the observed electrical resistivity anisotropy. With the field aligned along the most conducting axis, H(c2) increases monotonically with decreasing temperature to a value 5 times larger than the estimated paramagnetic pair-breaking field. Theories for the enhancement of H(c2) invoking spin-orbit scattering or strong-coupling superconductivity are shown to be inadequate in explaining the observed behavior, suggesting that the pairing state in Li0:9Mo6O17 is unconventional and possibly spin triplet.

17.
J Fish Biol ; 80(5): 991-1018, 2012 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-22497371

RESUMO

Greenland shark Somniosus microcephalus is a potentially important yet poorly studied cold-water species inhabiting the North Atlantic and Arctic Oceans. Broad-scale changes in the Arctic ecosystem as a consequence of climate change have led to increased attention on trophic dynamics and the role of potential apex predators such as S. microcephalus in the structure of Arctic marine food webs. Although Nordic and Inuit populations have caught S. microcephalus for centuries, the species is of limited commercial interest among modern industrial fisheries. Here, the limited historical information available on S. microcephalus occurrence and ecology is reviewed and new catch, biological and life-history information from the Arctic and North Atlantic Ocean region is provided. Given the considerable by-catch rates in high North Atlantic Ocean latitudes it is suggested that S. microcephalus is an abundant predator that plays an important, yet unrecognized, role in Arctic marine ecosystems. Slow growth and large pup sizes, however, may make S. microcephalus vulnerable to increased fishing pressure in a warming Arctic environment.


Assuntos
Tubarões/crescimento & desenvolvimento , Tubarões/fisiologia , Animais , Regiões Árticas , Oceano Atlântico , Conservação dos Recursos Naturais , Pesqueiros , Cadeia Alimentar , Groenlândia
18.
J Fish Biol ; 80(5): 1449-84, 2012 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-22497393

RESUMO

Stable-isotope analysis (SIA) can act as a powerful ecological tracer with which to examine diet, trophic position and movement, as well as more complex questions pertaining to community dynamics and feeding strategies or behaviour among aquatic organisms. With major advances in the understanding of the methodological approaches and assumptions of SIA through dedicated experimental work in the broader literature coupled with the inherent difficulty of studying typically large, highly mobile marine predators, SIA is increasingly being used to investigate the ecology of elasmobranchs (sharks, skates and rays). Here, the current state of SIA in elasmobranchs is reviewed, focusing on available tissues for analysis, methodological issues relating to the effects of lipid extraction and urea, the experimental dynamics of isotopic incorporation, diet-tissue discrimination factors, estimating trophic position, diet and mixing models and individual specialization and niche-width analyses. These areas are discussed in terms of assumptions made when applying SIA to the study of elasmobranch ecology and the requirement that investigators standardize analytical approaches. Recommendations are made for future SIA experimental work that would improve understanding of stable-isotope dynamics and advance their application in the study of sharks, skates and rays.


Assuntos
Ecologia/métodos , Elasmobrânquios/fisiologia , Isótopos/análise , Migração Animal , Animais , Dieta , Ecossistema , Manejo de Espécimes
19.
Philos Trans A Math Phys Eng Sci ; 369(1941): 1626-39, 2011 Apr 28.
Artigo em Inglês | MEDLINE | ID: mdl-21422018

RESUMO

From analysis of the in-plane resistivity ρ(ab)(T) of La(2-x)Sr(x)CuO(4), we show that normal state transport in overdoped cuprates can be delineated into two regimes in which the electrical resistivity varies approximately linearly with temperature. In the low-temperature limit, the T-linear resistivity extends over a very wide doping range, in marked contrast to expectations from conventional quantum critical scenarios. The coefficient of this T-linear resistivity scales with the superconducting transition temperature T(c), implying that the interaction causing this anomalous scattering is also associated with the superconducting pairing mechanism. At high temperatures, the coefficient of the T-linear resistivity is essentially doping independent beyond a critical doping p(crit)=0.19 at which the ratio of the two coefficients is maximal. Taking our cue from earlier thermodynamic and photoemission measurements, we conclude that the opening of the normal-state pseudogap at p(crit) is driven by the loss of coherence of anti-nodal quasi-particles at low temperatures.

20.
Proc Natl Acad Sci U S A ; 107(40): 17131-4, 2010 Oct 05.
Artigo em Inglês | MEDLINE | ID: mdl-20855579

RESUMO

The doping of charge carriers into the CuO(2) planes of copper oxide Mott insulators causes a gradual destruction of antiferromagnetism and the emergence of high-temperature superconductivity. Optimal superconductivity is achieved at a doping concentration p beyond which further increases in doping cause a weakening and eventual disappearance of superconductivity. A potential explanation for this demise is that ferromagnetic fluctuations compete with superconductivity in the overdoped regime. In this case, a ferromagnetic phase at very low temperatures is predicted to exist beyond the doping concentration at which superconductivity disappears. Here we report on a direct examination of this scenario in overdoped La(2-x)Sr(x)CuO(4) using the technique of muon spin relaxation. We detect the onset of static magnetic moments of electronic origin at low temperature in the heavily overdoped nonsuperconducting region. However, the magnetism does not exist in a commensurate long-range ordered state. Instead it appears as a dilute concentration of static magnetic moments. This finding places severe restrictions on the form of ferromagnetism that may exist in the overdoped regime. Although an extrinsic impurity cannot be absolutely ruled out as the source of the magnetism that does occur, the results presented here lend support to electronic band calculations that predict the occurrence of weak localized ferromagnetism at high doping.


Assuntos
Cobre/química , Condutividade Elétrica , Magnetismo , Cristalização , Análise Espectral/métodos
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