RESUMO
Radar-absorbing materials (RAMs) covering the exterior surfaces of installed parts and assembled devices are crucial in absorbing most incident electromagnetic (EM) waves. This absorption minimizes reflected energy, thereby enhancing pilot safety and the stability of operating electronic devices without interference. Particularly, active stealth aircraft require effective protection from near- and far-field EM radiation across a wide spectrum of frequencies from both highly integrated electronic components and advanced enemy radars. Studies of RAMs often prioritize absorption over crucial tunability in frequency selectivity, revealing a research gap. In this study, we propose smart RAMs with frequency-selective absorption capabilities. Our approach involves incorporating two types of core-shell spheres in a polymer matrix, which feature shells of either wave-diffuse reflecting metal or wave-absorbing graphene. The key innovation lies in the ability to tailor absorption frequencies in the X-band range (8.2-12.4 GHz) by adjusting the interstitial spaces between the metallic spheres while the scattered waves are efficiently attenuated by graphene networks in the composites. On a metal substrate, a 2 mm-thick composite with an optimized structural composition and ratio of the two types of spheres exhibits a maximum absorption efficiency of 99.3%, effectively trapping and extinguishing incident waves. Combined with the structural tunability and frequency-selective properties of spherical fillers, our approach provides a scalable and effective method for creating functional isotropic coverings on various metallic surfaces.
RESUMO
Antireflection coatings (ARCs) enhance optical clarity and improve light transmission by reducing glare and reflections. The application of conventional ARCs in flexible devices, however, is impeded by their lack of durability, particularly under bending deformation. We develop ARCs that withstand delamination and fracture, remaining intact even after 1000 bending cycles with a 5 cm bending radius. We fabricate integrated ARCs (iARCs) on a poly(methyl methacrylate) (PMMA) substrate by inducing free polymers to infiltrate the interstices of a disordered assembly of hollow silica nanochains and nanospheres. The polydispersity of PMMA creates a refractive index gradient, yielding a broadband antireflection capability. The nanochain-based iARCs are superior to the nanosphere-based coatings in both antireflection properties and mechanical durability, owing to the lower packing density and mechanical interlocking of the nanochains, respectively. Additionally, these nanochain iARCs display antifogging properties stemming from their superhydrophilicity. While our demonstrations are based on PMMA as a model substrate, this methodology is potentially extendable to other polymers, enhancing the iARC's applicability across various practical applications, including flexible and wearable devices.
RESUMO
The incorporation of porous structures into films and coatings can transform their properties for applications in optics, separation, electronics, and energy generation and storage. Packing nanoparticles (NPs) is a versatile approach for fabricating nanoporous films with a tunable structure and properties. The mechanical fragility of NP packing-based films and coatings, however, significantly impedes their widespread utilization. Although infiltrating a polymer into the interstices of these NP packings has been shown to enhance their mechanical durability, this method completely eliminates the porosity of the structures, compromising their properties and functionality. This study presents a new approach to fabricate highly loaded porous nanocomposite films with a gradient in the refractive index by infiltrating subsaturating amounts of poly(methyl methacrylate) (PMMA) into disordered packings of hollow silica NPs. We demonstrate that dual porosity is a critical feature that enhances their antireflection (AR) and mechanical properties. The hollow cores of NPs prevent a substantial increase in the refractive index of the resulting films. Moreover, the interparticle voids allow for mechanical reinforcement to occur when the NP packings are infiltrated with PMMA, making them even more suitable for AR coatings. The refractive index and gradient across the nanocomposites can be tailored by adjusting the amount of PMMA infiltrated into the NP packing, the shape of hollow NPs, and the annealing time. The nanocomposite coatings with a continuous gradient in refractive index exhibit excellent AR properties and enhanced mechanical durability. Combined with the unique structural tunability afforded by the dual porosity, this approach provides a scalable and effective way to create robust and graded nanoporous structures for various applications.
RESUMO
As electromagnetic (EM) pollution continues to increase, electromagnetic interference (EMI) shielding materials have been intensively evaluated in terms of two main shielding mechanisms of reflection and absorption. Since the shielding effectiveness (SE) is represented in the logarithmic scale and in a coupled way of transmission (SET), absorption (SEA), and reflection (SER), often there is a misinterpretation that the EM wave reflectors are regarded as EM wave-absorbing materials. Surprisingly, we found that many materials reported as an EM wave absorber in the literature provide, in fact, less than 50% of EM wave-absorbing capability, i.e., over 50% of EM wave-reflecting feature. According to the theory and definition of EMI SE, the absorption-dominant EMI shielding materials should have the ratio of absorption to incident energy (A) as A > 0.5, which corresponds to a necessary condition that SER < 3.01 dB. The SER subsequently gives SEA in relation to SET. Using this criterion, we classified the EMI shielding materials with their shielding mechanism. The proposed methodology provides significant insight into the evaluation and development of EMI shielding materials.
