Structure of χ3-Borophene Studied by Total-Reflection High-Energy Positron Diffraction (TRHEPD).

We have investigated the structure of χ3-borophene on Ag(111), a monolayer material of boron atoms, via total-reflection high-energy positron diffraction (TRHEPD). By comparing the experimental rocking-curves with ones for several structures calculated by using dynamical diffraction theory, we confirmed that the χ3-borophene layer has a flat structure. The distance from the topmost layer of the metal crystal is 2.4 Å, which is consistent with results reported by X-ray standing wave-excited X-ray photoelectron spectroscopy. We also demonstrated that the in-plane structure of χ3-borophene is compatible with the theoretical predictions. These structural properties indicate that χ3-borophene belongs to a group of epitaxial monolayer sheets, such as graphene, which have weak interactions with the substrates.

Observation of a shape resonance of the positronium negative ion.

When an electron binds to its anti-matter counterpart, the positron, it forms the exotic atom positronium (Ps). Ps can further bind to another electron to form the positronium negative ion, Ps(-) (e(-)e(+)e(-)). Since its constituents are solely point-like particles with the same mass, this system provides an excellent testing ground for the three-body problem in quantum mechanics. While theoretical works on its energy level and dynamics have been performed extensively, experimental investigations of its characteristics have been hampered by the weak ion yield and short annihilation lifetime. Here we report on the laser spectroscopy study of Ps(-), using a source of efficiently produced ions, generated from the bombardment of slow positrons onto a Na-coated W surface. A strong shape resonance of (1)P(o) symmetry has been observed near the Ps (n=2) formation threshold. The resonance energy and width measured are in good agreement with the result of three-body calculations.

Electrochemical transfer of (18)F from (18)O water to aprotic polar solvent.

Electrochemical transfer of (18)F(-) from enriched [(18)O]-water to pure acetonitrile was investigated to develop a simple and effective synthesis of (18)F-radiopharmaceuticals. The transfer of (18)F is composed of two steps: first step is electro-deposition on a graphite anode and the next step is electro-emission into pure acetonitrile by inversing the polarity of the electric tension. A sufficiently high fraction of the electro-emission, 73%, was achieved. The electrochemical transfer of (18)F to aprotic polar solvents without any additives, such as phase transfer catalysis, will make the synthesis of diverse (18)F-radiopharamceuticals simple and easy.

Experimental evidence for spin-orbit interactions in positronium-Xe collisions.

Spin-orbit interaction of positronium (Ps) with the surrounding atoms, predicted by Mitroy and Novikov [Phys. Rev. Lett. 90, 183202 (2003)], has been detected experimentally. We have found that the lifetime of the magnetically unperturbed ortho-Ps in Xe gas of 1 atm decreases significantly when a magnetic field of 1.0 T is applied. This decrease is attributed to the Ps spin conversion caused by spin-orbit interaction during Ps-Xe collision. The annihilation cross section of ortho-Ps due to this interaction has been determined to be 3 times as large as that expected by Mitroy and Novikov.

Measurement of Cu K-shell and Ag L-shell ionization cross sections by low-energy positron impact.

Inner shell ionization cross sections by low-energy positron impact have been measured. Development of an x-ray detector with thin Si(Li) crystals has enabled the first measurements of the absolute cross sections for the positron impacts in the energy range below 30 keV. Threshold behavior of the measured cross sections for the Cu K shell and Ag L shell are compared with the theoretical results of Gryzinski and Kowalski [Phys. Lett. A 183, 196 (1993)]] and Khare and Wadehra [Can. J. Phys. 74, 376 (1996)]]. Good agreement has been found for the Cu K shell, while the experimental values for the Ag L shell were found to be smaller than the corresponding theoretical results.

Direct measurement of the parapositronium lifetime in alpha-SiO2.

The mean lifetime of delocalized parapositronium in alpha-SiO2 has been determined directly for the first time using a newly developed positron lifetime spectrometer based on BaF2 scintillators and a fast digital oscilloscope. The lifetime is found to be 156+/-4 ps, which is much longer than its intrinsic lifetime of 125 ps. This indicates clearly that the primary many-body effect on positronium in alpha-SiO2 is the screening of the Coulomb interaction between the constituent particles by electrons of the medium and that the average distance between the electron and positron in positronium becomes larger than its vacuum value.