1.
Chem Commun (Camb)
; 60(39): 5149-5152, 2024 May 09.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38591265
RESUMO
A novel chiral photoswitch composed of a binaphthyl unit and a hexafluorocyclopentene ring has been synthesized. This chiral photoswitch exhibited thermally reversible photochromism between the binaphthyl and helicenoid forms based on 6π-electrocyclization. The helicity of the binaphthyl moiety was reversed upon stereospecific photocyclization and reverted back during the thermal ring opening.