Indoor Air Quality Levels in Schools: Role of Student Activities and No Activities.

This work describes a methodology for the definition of indoor air quality monitoring plans in schools and above all to improve the knowledge and evaluation of the indoor concentration levels of some chemical pollutants. The aim is to guide interventions to improve the health of students and exposed staff connected with the activities carried out there. The proposed methodology is based on the simultaneous study of chemical (indoor/outdoor PM2.5, NO2, CO2) and physical (temperature, humidity) parameters by means of automatic analyzers coupled with gaseous compounds (benzene, toluene, ethylbenzene, xylenes, formaldehyde and NO2) sampled by denuders. The important novelty is that all the data were collected daily in two different situations, i.e., during school activities and no-school activities, allowing us to evaluate the exposure of each student or person. The different behaviors of all the measured pollutants during the two different situations are reported and commented on. Finally, a statistical approach will show how the investigated compounds are distributed around the two components of combustion processes and photochemical reactions.

Toxicity of the readily leachable fraction of urban PM2.5 to human lung epithelial cells: Role of soluble metals.

Fine airborne particulate matter (PM2.5) has been repeatedly associated with adverse health effects in humans. The PM2.5 soluble fraction, and soluble metals in particular, are thought to cause lung damage. Literature data, however, are not consistent and the role of leachable metals is still under debate. In this study, Winter and Summer urban PM2.5 aqueous extracts, obtained by using a bio-compatible solution and different contact times at 37 °C, were used to investigate cytotoxic effects of PM2.5 in cultured lung epithelial cells (A549) and the role played by the leachable metals Cu, Fe, Zn, Ni, Pb and Cd. Cell viability and migration, as well as intracellular glutathione, extracellular cysteine, cysteinylglycine and homocysteine concentrations, were evaluated in cells challenged with both PM2.5 extracts before and after ultrafiltration and artificial metal ion solutions mimicking the metal composition of the genuine extracts. The thiol oxidative potential was also evaluated by an abiotic test. Results demonstrate that PM2.5 bioactive components were released within minutes of PM2.5 interaction with the leaching solution. Among these are i) low MW (<3 kDa) solutes inducing oxidative stress and ii) high MW and/or water-insoluble compounds largely contributing to thiol oxidation and to increased homocysteine levels in the cell medium. Cu and/or Ni ions likely contributed to the effects of Summer PM2.5 extracts. Nonetheless, the strong bio-reactivity of Winter PM2.5 extracts could not be explained by the presence of the studied metals. A possible role for PM2.5 water-extractable organic components is discussed.

Analysis of major pollutants and physico-chemical characteristics of PM2.5 at an urban site in Rome.

Air quality data from a one year study at an urban roadside location in Rome are reported for major pollutants. Continuous concentration data of carbon monoxide, ozone, nitrogen dioxide, aromatic hydrocarbons and natural radioactivity were measured in the urban air of Rome from January 2016 to January 2017. Moreover, PM2.5 mass concentration and physico-chemical characteristics of single constituent particles are herein reported. Gaseous pollutants, except ozone, and PM2.5 showed maximum concentrations in December due to high atmospheric stability. O3 and NO2 trend analysis showed photochemical smog episodes in June and September. In September, during a photochemical smog episode the aromatic hydrocarbons contribution to ozone formation was experimentally proven. Pearson's coefficient among aromatic hydrocarbons and the ratio Toluene/Benzene (T/B) showed that pollutants were under the influence of vehicular traffic. Physico-chemical characterization of PM2.5 single particles, carried out by field emission scanning electron microscope combined with energy dispersive X-ray spectroscopy, displayed the presence of particle diversity from natural and anthropogenic origin. Four principal components in the PM2.5 were identified: carbonaceous particles, Ca-sulphates, soil dust and building structure particles, metal particles. The principal source of carbonaceous particles in this urban area consists of the motor vehicle exhausts and the heating systems in winter. Traces of S and sometimes S, Na, K were detected on varying percentages of carbonaceous particles. These data suggested that the carbonaceous particles act as vehicles for strong acids, prevalently H2SO4 and alkaline metal sulphates. A Saharan dust contribution to PM2.5 was found in different periods. Metal particles included iron oxide particles, metals oxide particles and Fe-rich metal compounds. The identification of chemical composition of individual particles provide useful information to determine their origin and formation processes.

[Air pollution in an urban area nearby the Rome-Ciampino city airport]. / Inquinamento atmosferico in un'area urbana limitrofa all'aeroporto di Roma-Ciampino.

OBJECTIVES: to assess air pollution spatial and temporal variability in the urban area nearby the Ciampino International Airport (Rome) and to investigate the airport-related emissions contribute. DESIGN AND SETTING: the study domain was a 64 km2 area around the airport. Two fifteen-day monitoring campaigns (late spring, winter) were carried out. Results were evaluated using several runs outputs of an airport-related sources Lagrangian particle model and a photochemical model (the Flexible Air quality Regional Model, FARM). MAIN OUTCOME MEASURES: both standard and high time resolution air pollutant concentrations measurements: CO, NO, NO2, C6H6, mass and number concentration of several PM fractions. 46 fixed points (spread over the study area) of NO2 and volatile organic compounds concentrations (fifteen days averages); deterministic models outputs. RESULTS: standard time resolution measurements, as well as model outputs, showed the airport contribution to air pollution levels being little compared to the main source in the area (i.e. vehicular traffic). However, using high time resolution measurements, peaks of particles associated with aircraft takeoff (total number concentration and soot mass concentration), and landing (coarse mass concentration) were observed, when the site measurement was downwind to the runway. CONCLUSIONS: the frequently observed transient spikes associated with aircraft movements could lead to a not negligible contribute to ultrafine, soot and coarse particles exposure of people living around the airport. Such contribute and its spatial and temporal variability should be investigated when assessing the airports air quality impact.

Environmental concentrations of fibers with fluoro-edenitic composition and population exposure in Biancavilla (Sicily, Italy).

INTRODUCTION: The town of Biancavilla (Sicily) was included in the National Priorities List of Contaminated Sites due to environmental dispersion of amphibole fibers owing to the extraction of materials from a local quarry. The present report summarizes results from several, hitherto unpublished, environmental surveys carried out in the area, as well as from published analyses of the chemistry and composition of fibers. METHODS: Data included here comprises environmental fiber concentrations by scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis in soil, indoor and outdoor air, personal monitoring, as well as a chemical characterization of the fibers. The full chemical structure and spectroscopic characterization of fibers were obtained through a multi-analytical approach: SEM-EDS, X-ray powder diffraction (XRPD), as well as Mössbauer (MS) and Fourier transform infrared (FT-IR) spectroscopies. RESULTS: Data analyzed provided a spatial and temporal picture of fiber concentrations in Biancavilla, and a qualitative assessment of population exposure. Results suggest that until 2000, the population had been exposed to high levels of amphibole fibers. Mitigation measures adopted since 2001, gradually reduced exposure levels to about 0.1-0.4 ff/l. Previous studies on fibrous amphiboles from Biancavilla reported considerable chemical variability. Differences in composition, especially concerning the presence of Si, Ca, Fe, and Na, were found both within and between samples. Compared to the previously investigated prismatic fluoro-edenite, these fibrous fluorine amphiboles consistently showed higher average values of Si and Fe content, whereas Ca was significantly lower, which we consider a distinctive characteristic of the fluorine fibrous variety. CONCLUSIONS: The population of Biancavilla had been highly exposed to a suite of fibrous amphiboles for over 50 years. Dust mitigation measures have gradually reduced exposure, but continuous environmental follow-up is necessary in order to monitor exposure levels and prevent adverse health effects for future generations.

Evaluation of the temporal variation of air quality in Rome, Italy, from 1999 to 2008.

The main objective of this study was to asses the temporal variation (1999 trough 2008) of air quality in Rome, focusing on airborne concentration of selected pollutants (PM10 and PM2.5 mass concentration and particle number concentration, PNC, carbon monoxide, CO, nitrogen oxides, NO and NO2) used for health effects assessment in epidemiological analyses. Time series analysis using Seasonal Kendall test has been applied. A statistically significant decreasing trend was found for primary gaseous pollutants and total particle number concentrations. Moreover a decreasing trend was assessed for PM10, PM2.5 and NO2 measured at traffic oriented sites even if the estimated reduction was lower compared with NO, CO and PNC. The urban background PM10 and NO2 concentrations seem to be practically unchanged since 1999 as no statistically significant trends were found. All the pollutants show higher slope of the estimated trend line at traffic oriented sites compared with those observed at the urban background. Thus a reduction of the intra-city concentration variability throughout the years occurred.

Two-years of fine and ultrafine particles measurements in Rome, Italy.

Long-term aerosol measurements have been conducted at two sites in Rome, Italy, April 2001 through March 2003, in a traffic-oriented site, and at an urban background site, close to the city center. The main objective was to establish validated and consistent data sets of particle number concentrations (PNC) in Rome to be used for epidemiological analyses of cardiovascular health effects. Particle number concentrations were measured by a condensation particle counter (CPC 3022A, TSI). Other pollutants (PM10, PM2.5, CO, NO2, NO, NOx, O3) were simultaneously measured at the traffic-oriented site. During the study period, the mean (standard deviation) 24-h PNC values were 4.69 x 10(4) (1.99 x 10(4)) cm(-3) and 2.46 x 10(4) (1.10 x 10(4)) cm(-3), respectively, at the traffic-oriented site and at the urban background site. Mean (standard deviation) 24-h mass concentration of PM2.5 was 23.1 (11.9) microg m(-3), while for PM10 it was 41.3 (17.9) microg m(-3). Higher values for all the pollutants, except ozone, were recorded during the winter period in comparison with the summer period, and a higher variability of the results was also observed during cold months. The comparison between the daily PNC measured at the two sites showed a good correlation (r = .74). CO (r = .77), NO (r = .82), and NOx (r = .83) were all highly correlated with PNC (simultaneous obs. number 576). The diurnal and seasonal pattern of PNC can be attributed to the combined effect of motor vehicle emissions and meteorological conditions.

[Particulate matter measurements PM2.5 and PM10 in Rome: comparison indoor/outdoor]. / Misure di materiale particellare PM10 e PM2.5 a Roma: confronti indoor/outdoor.

The concentration of airborne particulate matter (PM2.5 and PM10) was assessed over 12 months (1999-2000) both outdoor and indoor (workplaces and homes without major PM sources) through a manual gravimetric method. Mean concentration values outdoors were moderately lower than indoor concentrations in summer, but higher in winter. The correlations between outdoor and indoor values are statistically significant, especially for PM2.5 in winter. The position of indoor sites with respect to street level was immaterial as far as mean values is concerned, whilst maximum values presented some differences accordingly. Day-to-day variability was higher outside than inside, especially in winter. The PM2.5/PM10 ratio was higher indoors, probably owing to the higher sedimentation speed of the coarse fraction.