Jupiter Science Enabled by ESA's Jupiter Icy Moons Explorer.

ESA's Jupiter Icy Moons Explorer (JUICE) will provide a detailed investigation of the Jovian system in the 2030s, combining a suite of state-of-the-art instruments with an orbital tour tailored to maximise observing opportunities. We review the Jupiter science enabled by the JUICE mission, building on the legacy of discoveries from the Galileo, Cassini, and Juno missions, alongside ground- and space-based observatories. We focus on remote sensing of the climate, meteorology, and chemistry of the atmosphere and auroras from the cloud-forming weather layer, through the upper troposphere, into the stratosphere and ionosphere. The Jupiter orbital tour provides a wealth of opportunities for atmospheric and auroral science: global perspectives with its near-equatorial and inclined phases, sampling all phase angles from dayside to nightside, and investigating phenomena evolving on timescales from minutes to months. The remote sensing payload spans far-UV spectroscopy (50-210 nm), visible imaging (340-1080 nm), visible/near-infrared spectroscopy (0.49-5.56 µm), and sub-millimetre sounding (near 530-625 GHz and 1067-1275 GHz). This is coupled to radio, stellar, and solar occultation opportunities to explore the atmosphere at high vertical resolution; and radio and plasma wave measurements of electric discharges in the Jovian atmosphere and auroras. Cross-disciplinary scientific investigations enable JUICE to explore coupling processes in giant planet atmospheres, to show how the atmosphere is connected to (i) the deep circulation and composition of the hydrogen-dominated interior; and (ii) to the currents and charged particle environments of the external magnetosphere. JUICE will provide a comprehensive characterisation of the atmosphere and auroras of this archetypal giant planet.

Ice Giant Circulation Patterns: Implications for Atmospheric Probes.

Atmospheric circulation patterns derived from multi-spectral remote sensing can serve as a guide for choosing a suitable entry location for a future in situ probe mission to the Ice Giants. Since the Voyager-2 flybys in the 1980s, three decades of observations from ground- and space-based observatories have generated a picture of Ice Giant circulation that is complex, perplexing, and altogether unlike that seen on the Gas Giants. This review seeks to reconcile the various competing circulation patterns from an observational perspective, accounting for spatially-resolved measurements of: zonal albedo contrasts and banded appearances; cloud-tracked zonal winds; temperature and para-H2 measurements above the condensate clouds; and equator-to-pole contrasts in condensable volatiles (methane, ammonia, and hydrogen sulphide) in the deeper troposphere. These observations identify three distinct latitude domains: an equatorial domain of deep upwelling and upper-tropospheric subsidence, potentially bounded by peaks in the retrograde zonal jet and analogous to Jovian cyclonic belts; a mid-latitude transitional domain of upper-tropospheric upwelling, vigorous cloud activity, analogous to Jovian anticyclonic zones; and a polar domain of strong subsidence, volatile depletion, and small-scale (and potentially seasonally-variable) convective activity. Taken together, the multi-wavelength observations suggest a tiered structure of stacked circulation cells (at least two in the troposphere and one in the stratosphere), potentially separated in the vertical by (i) strong molecular weight gradients associated with cloud condensation, and by (ii) transitions from a thermally-direct circulation regime at depth to a wave- and radiative-driven circulation regime at high altitude. The inferred circulation can be tested in the coming decade by 3D numerical simulations of the atmosphere, and by observations from future world-class facilities. The carrier spacecraft for any probe entry mission must ultimately carry a suite of remote-sensing instruments capable of fully constraining the atmospheric motions at the probe descent location.

Stormy water on Mars: The distribution and saturation of atmospheric water during the dusty season.

The loss of water from Mars to space is thought to result from the transport of water to the upper atmosphere, where it is dissociated to hydrogen and escapes the planet. Recent observations have suggested large, rapid seasonal intrusions of water into the upper atmosphere, boosting the hydrogen abundance. We use the Atmospheric Chemistry Suite on the ExoMars Trace Gas Orbiter to characterize the water distribution by altitude. Water profiles during the 2018-2019 southern spring and summer stormy seasons show that high-altitude water is preferentially supplied close to perihelion, and supersaturation occurs even when clouds are present. This implies that the potential for water to escape from Mars is higher than previously thought.

Uranus's northern polar cap in 2014.

In October and November 2014, spectra covering the 1.436 - 1.863-µm wavelength range from the SINFONI Integral Field Unit Spectrometer on the Very Large Telescope showed the presence of a vast bright North polar cap on Uranus, extending northward from about 40°N and at all longitudes observed. The feature, first detected in August 2014 from Keck telescope images, has a morphology very similar to the southern polar cap that was seen to fade before the 2007 equinox. At strong methane-absorbing wavelengths (for which only the high troposphere or stratosphere is sampled) the feature is not visible, indicating that it is not a stratospheric phenomenon. We show that the observed northern bright polar cap results mainly from a decrease in the tropospheric methane mixing ratio, rather than from a possible latitudinal variation of the optical properties or abundance of aerosol, implying an increase in polar downwelling near the tropopause level.

The formation and evolution of Titan's winter polar vortex.

Saturn's largest moon Titan has a substantial nitrogen-methane atmosphere, with strong seasonal effects, including formation of winter polar vortices. Following Titan's 2009 northern spring equinox, peak solar heating moved to the northern hemisphere, initiating south-polar subsidence and winter polar vortex formation. Throughout 2010-2011, strengthening subsidence produced a mesospheric hot-spot and caused extreme enrichment of photochemically produced trace gases. However, in 2012 unexpected and rapid mesospheric cooling was observed. Here we show extreme trace gas enrichment within the polar vortex dramatically increases mesospheric long-wave radiative cooling efficiency, causing unusually cold temperatures 2-6 years post-equinox. The long time-frame to reach a stable vortex configuration results from the high infrared opacity of Titan's trace gases and the relatively long atmospheric radiative time constant. Winter polar hot-spots have been observed on other planets, but detection of post-equinox cooling is so far unique to Titan.

ALMA detection and astrobiological potential of vinyl cyanide on Titan.

Recent simulations have indicated that vinyl cyanide is the best candidate molecule for the formation of cell membranes/vesicle structures in Titan's hydrocarbon-rich lakes and seas. Although the existence of vinyl cyanide (C2H3CN) on Titan was previously inferred using Cassini mass spectrometry, a definitive detection has been lacking until now. We report the first spectroscopic detection of vinyl cyanide in Titan's atmosphere, obtained using archival data from the Atacama Large Millimeter/submillimeter Array (ALMA), collected from February to May 2014. We detect the three strongest rotational lines of C2H3CN in the frequency range of 230 to 232 GHz, each with >4σ confidence. Radiative transfer modeling suggests that most of the C2H3CN emission originates at altitudes of ≳200 km, in agreement with recent photochemical models. The vertical column densities implied by our best-fitting models lie in the range of 3.7 × 1013 to 1.4 × 1014 cm-2. The corresponding production rate of vinyl cyanide and its saturation mole fraction imply the availability of sufficient dissolved material to form ~107 cell membranes/cm3 in Titan's sea Ligeia Mare.

Aerosol influence on energy balance of the middle atmosphere of Jupiter.

Aerosols are ubiquitous in planetary atmospheres in the Solar System. However, radiative forcing on Jupiter has traditionally been attributed to solar heating and infrared cooling of gaseous constituents only, while the significance of aerosol radiative effects has been a long-standing controversy. Here we show, based on observations from the NASA spacecraft Voyager and Cassini, that gases alone cannot maintain the global energy balance in the middle atmosphere of Jupiter. Instead, a thick aerosol layer consisting of fluffy, fractal aggregate particles produced by photochemistry and auroral chemistry dominates the stratospheric radiative heating at middle and high latitudes, exceeding the local gas heating rate by a factor of 5-10. On a global average, aerosol heating is comparable to the gas contribution and aerosol cooling is more important than previously thought. We argue that fractal aggregate particles may also have a significant role in controlling the atmospheric radiative energy balance on other planets, as on Jupiter.

Evolution of Stratospheric Chemistry in the Saturn Storm Beacon Region.

The giant northern-hemisphere storm that erupted on Saturn in December 2010 triggered significant changes in stratospheric temperatures and species abundances that persisted for more than a year after the original outburst. The stratospheric regions affected by the storm have been nicknamed "beacons" due to their prominent infrared-emission signatures (Fletcher, L.N. et al. [2011]. Science 332, 1413). The two beacon regions that were present initially merged in April 2011 to form a single, large, anticyclonic vortex (Fletcher, L.N. et al. [2012]. Icarus 221, 560). We model the expected photochemical evolution of the stratospheric constituents in the beacons from the initial storm onset through the merger and on out to March 2012. The results are compared with longitudinally resolved Cassini/CIRS spectra from May 2011. If we ignore potential changes due to vertical winds within the beacon, we find that C2H2, C2H6, and C3H8 remain unaffected by the increased stratospheric temperatures in the beacon, the abundance of the shorter-lived CH3C2H decreases, and the abundance of C2H4 increases significantly due to the elevated temperatures, the latter most notably in a secondary mixing-ratio peak located near mbar pressures. The C4H2 abundance in the model decreases by a factor of a few in the 0.01-10 mbar region but has a significant increase in the 10-30 mbar region due to evaporation of the previously condensed phase. The column abundances of C6H6 and H2O above ~30 mbar also increase due to aerosol evaporation. Model-data comparisons show that models that consider temperature changes alone underpredict the abundance of C2H x species by a factor of 2-7 in the beacon core in May 2011, suggesting that other processes not considered by the models, such as downwelling winds in the vortex, are affecting the species profiles. Additional calculations indicate that downwelling winds of order -10 cm s -1 near ~0.1 mbar need to be included in the photochemical models in order to explain the inferred C2H x abundances in the beacon core, indicating that both strong subsiding winds and chemistry at elevated temperatures are affecting the vertical profiles of atmospheric constituents in the beacon. We (i) discuss the general chemical behavior of stratospheric species in the beacon region, (ii) demonstrate how the evolving beacon environment affects the species vertical profiles and emission characteristics (both with and without the presence of vertical winds), (iii) make predictions with respect to compositional changes that can be tested against Cassini and Herschel data, and higher-spectral-resolution ground-based observations of the beacon region, and (iv) discuss future measurements and modeling that could further our understanding of the dynamical origin, evolution, and chemical processing within these unexpected stratospheric vortices that were generated after the 2010 convective event.

HCN ice in Titan's high-altitude southern polar cloud.

Titan's middle atmosphere is currently experiencing a rapid change of season after northern spring arrived in 2009 (refs 1, 2). A large cloud was observed for the first time above Titan's southern pole in May 2012, at an altitude of 300 kilometres. A temperature maximum was previously observed there, and condensation was not expected for any of Titan's atmospheric gases. Here we report that this cloud is composed of micrometre-sized particles of frozen hydrogen cyanide (HCN ice). The presence of HCN particles at this altitude, together with temperature determinations from mid-infrared observations, indicate a dramatic cooling of Titan's atmosphere inside the winter polar vortex in early 2012. Such cooling is in contrast to previously measured high-altitude warming in the polar vortex, and temperatures are a hundred degrees colder than predicted by circulation models. These results show that post-equinox cooling at the winter pole of Titan is much more efficient than previously thought.

Exploring the diversity of Jupiter-class planets.

Of the 900+ confirmed exoplanets discovered since 1995 for which we have constraints on their mass (i.e. not including Kepler candidates), 75% have masses larger than Saturn (0.3 MJ), 53% are more massive than Jupiter and 67% are within 1 AU of their host stars. When Kepler candidates are included, Neptune-sized giant planets could form the majority of the planetary population. And yet the term 'hot Jupiter' fails to account for the incredible diversity of this class of astrophysical object, which exists on a continuum of giant planets from the cool jovians of our own Solar System to the highly irradiated, tidally locked hot roasters. We review theoretical expectations for the temperatures, molecular composition and cloud properties of hydrogen-dominated Jupiter-class objects under a variety of different conditions. We discuss the classification schemes for these Jupiter-class planets proposed to date, including the implications for our own Solar System giant planets and the pitfalls associated with compositional classification at this early stage of exoplanetary spectroscopy. We discuss the range of planetary types described by previous authors, accounting for (i) thermochemical equilibrium expectations for cloud condensation and favoured chemical stability fields; (ii) the metallicity and formation mechanism for these giant planets; (iii) the importance of optical absorbers for energy partitioning and the generation of a temperature inversion; (iv) the favoured photochemical pathways and expectations for minor species (e.g. saturated hydrocarbons and nitriles); (v) the unexpected presence of molecules owing to vertical mixing of species above their quench levels; and (vi) methods for energy and material redistribution throughout the atmosphere (e.g. away from the highly irradiated daysides of close-in giants). Finally, we discuss the benefits and potential flaws of retrieval techniques for establishing a family of atmospheric solutions that reproduce the available data, and the requirements for future spectroscopic characterization of a set of Jupiter-class objects to test our physical and chemical understanding of these planets.

Active upper-atmosphere chemistry and dynamics from polar circulation reversal on Titan.

Saturn's moon Titan has a nitrogen atmosphere comparable to Earth's, with a surface pressure of 1.4 bar. Numerical models reproduce the tropospheric conditions very well but have trouble explaining the observed middle-atmosphere temperatures, composition and winds. The top of the middle-atmosphere circulation has been thought to lie at an altitude of 450 to 500 kilometres, where there is a layer of haze that appears to be separated from the main haze deck. This 'detached' haze was previously explained as being due to the co-location of peak haze production and the limit of dynamical transport by the circulation's upper branch. Here we report a build-up of trace gases over the south pole approximately two years after observing the 2009 post-equinox circulation reversal, from which we conclude that middle-atmosphere circulation must extend to an altitude of at least 600 kilometres. The primary drivers of this circulation are summer-hemisphere heating of haze by absorption of solar radiation and winter-hemisphere cooling due to infrared emission by haze and trace gases; our results therefore imply that these effects are important well into the thermosphere (altitudes higher than 500 kilometres). This requires both active upper-atmosphere chemistry, consistent with the detection of high-complexity molecules and ions at altitudes greater than 950 kilometres, and an alternative explanation for the detached haze, such as a transition in haze particle growth from monomers to fractal structures.

Thermal structure and dynamics of Saturn's northern springtime disturbance.

Saturn's slow seasonal evolution was disrupted in 2010-2011 by the eruption of a bright storm in its northern spring hemisphere. Thermal infrared spectroscopy showed that within a month, the resulting planetary-scale disturbance had generated intense perturbations of atmospheric temperatures, winds, and composition between 20° and 50°N over an entire hemisphere (140,000 kilometers). The tropospheric storm cell produced effects that penetrated hundreds of kilometers into Saturn's stratosphere (to the 1-millibar region). Stratospheric subsidence at the edges of the disturbance produced "beacons" of infrared emission and longitudinal temperature contrasts of 16 kelvin. The disturbance substantially altered atmospheric circulation, transporting material vertically over great distances, modifying stratospheric zonal jets, exciting wave activity and turbulence, and generating a new cold anticyclonic oval in the center of the disturbance at 41°N.

Upper limits for undetected trace species in the stratosphere of Titan.

In this paper we describe the first quantitative search for several molecules in Titan's stratosphere in Cassini CIRS infrared spectra. These are: ammonia (NH3), methanol (CH3OH), formaldehyde (H2CO), and acetonitrile (CH3CN), all of which are predicted by photochemical models but only the last of which has been observed, and not in the infrared. We find non-detections in all cases, but derive upper limits on the abundances from low-noise observations at 25 degrees S and 75 degrees N. Comparing these constraints to model predictions, we conclude that CIRS is highly unlikely to see NH3 or CH3OH emissions. However, CH3CN and H2CO are closer to CIRS detectability, and we suggest ways in which the sensitivity threshold may be lowered towards this goal.

Dynamical implications of seasonal and spatial variations in Titan's stratospheric composition.

Titan's diverse inventory of photochemically produced gases can be used as tracers to probe atmospheric circulation. Since the arrival of the Cassini-Huygens mission in July 2004 it has been possible to map the seasonal and spatial variations of these compounds in great detail. Here, we use 3.5 years of data measured by the Cassini Composite InfraRed Spectrometer instrument to determine spatial and seasonal composition trends, thus providing clues to underlying atmospheric motions. Titan's North Pole (currently in winter) displays enrichment of trace species, implying subsidence is occurring there. This is consistent with the descending branch of a single south-to-north stratospheric circulation cell and a polar vortex. Lack of enrichment in the south over most of the observed time period argues against the presence of any secondary circulation cell in the Southern Polar stratosphere. However, a residual cap of enriched gas was observed over the South Pole early in the mission, which has since completely dissipated. This cap was most probably due to residual build-up from southern winter. These observations provide new and important constraints for models of atmospheric photochemistry and circulation.