Flavonoids: A Reservoir of Drugs from Nature.

Flavonoids are associated with many plants and dietary foods; their chemical study has always attracted the interest of chemists working in the area of natural products and synthetic chemistry. Research in phytochemistry has produced many useful drugs. The analogs of flavonoids exhibit anticancer, anti-tuberculosis, anti-diabetic, antiviral, antibacterial, antioxidant, anti-inflammatory, antiproliferative, anti-spermatogenic, and antipsychotic activities. This review article highlights flavonoids' significance and medicinal application and displays a comparative overview of the biological activities of flavonoids and flavonoid derivatives. It covers almost all necessary reports for future directions in drug discovery.

Lignin-Based Gel Polymer Electrolyte for Cationic Conductivity.

The article presents the results of the preparation and study of a gel-polymer electrolyte based on lignin obtained from Pinus sylvestris. Sulfonation and subsequent chlorination of lignin make possible implementation of the principle of mono-ionic conductivity in a natural biopolymer matrix, which provides predominantly cationic conductivity of the electrolyte. Based on the results of the qualitative and quantitative analysis of the synthesized samples, the mechanisms of the chemical conversion of the biopolymer, the structure models of the converted fragments of macromolecules, as well as the quantum-chemical calculation of their electronic and geometric parameters are presented. The key electronic characteristics of the gel polymer electrolytes (GPE) based on a composite of lignins with 20 wt.% polyvinyl alcohol are determined by impedance spectroscopy. The maximum value of the specific volume conductivity is 2.48 × 10-4 S cm-1, which is comparable with most commercial electrolytes of this type, but at the same time, record values are reached in the number of lithium cation transfer tLi+ of 0.89. The studies allow to identify the basic laws of the effect of chemical modification on the structure of GPE and describe the mechanism of ionic conductivity.

Water-Soluble Copper Ink for the Inkjet Fabrication of Flexible Electronic Components.

The aim of this work is preparation and investigation of copper conductive paths by printing with a different type of functional ink. The solutions based on copper-containing complex compounds were used as inks instead of dispersions of metal nanoparticles. Thermal characteristics of synthesized precursors were studied by thermogravimetry in an argon atmosphere. Based on the comparison of decomposition temperature, the dimethylamine complex of copper formate was found to be more suitable precursor for the formation of copper layers. Structure and performance of this compound was studied in detail by X-ray diffraction, test of wettability, printing on flexible substrate, and electrical measurements.

Up-Scalable Synthesis of Size-Controlled White-Green Emitting Behavior of Core/Shell (CdSe/ZnS) Quantum Dots for LED Applications.

Research on CdSe/ZnS core-shell quantum dots (QDs) was synthesized by a chemical route using bio-conjugated organic amino acid (L-Cysteine). The structural, morphological, and optical properties of the nanocrystal powder samples were analyzed using various characterization techniques. The diameter of the resulting QDs was about 3 nm with uniform size distribution. The optical properties QDs exhibited an absorption and emission peak at 515 and 525 nm respectively, at room temperature. The QDs through emission in the spectral range at 516-535 nm is special for their application in green LEDs and white-light generation. The high optical properties performance of the QDs nanocomposites gained indicates that the materials are promising for (LED) applications.

Photocatalytic decomposition effect of erbium doped cerium oxide nanostructures driven by visible light irradiation: Investigation of cytotoxicity, antibacterial growth inhibition using catalyst.

Cerium (IV) oxide (CeO2) is the most accessible noble rare earth metal oxide for the excitation of the excitons by light-harvesting performance. The present work is focused on Erbium doped ceria nanoparticles that were beneficially obtained by hydrothermal method from cerium nitrate and Erbium nitrate as precursors for decomposition of Rhodamine-B (RhB) dye in the polluted waste water removed from the industries. Dye removal efficiency of the catalyst was found to be nearly ~94%. The structural phases, functional groups and the transitions are identified with the help of various techniques. XRD pattern determines the development of cubic phase with the particle size is 20 nm. Highly crystalline nature of as-synthesized nanomaterials with an average diameter of 35 nm was investigated by HRSEM. The crystalline size, shape and textural morphology, of the Erbium doped ceria nanostructures were analysed by HRTEM. Our results suggest, that the concentration of OH- ion determines the lattice constants and oxygen vacancy in the nanostructures which stimulate the probability of photocatalytic decomposition effect of organic pollutants, due to synergistic approach. In this context, both unhydrolyzed things and their swiftly drip from deceased or scratched cells with conceded membranes, even when the cells embrace some are outstanding attention. Although, the loss of viable cells also depends on epithelial cell dynamically conceal of numerous molar matrix.