RESUMO
The title compound, C24H18BrF3N4O4, is a 1,2,3-triazole derivative featuring, among others, a quinoline-derived substituent. In the crystal, C-Hâ¯O, C-Hâ¯N and C-Hâ¯F contacts connect the mol-ecules into a three-dimensional network. The shortest centroid-centroid distance between two aromatic systems is 3.896â (2)â Å and is found between the two different six-membered rings of the quinoline scaffold in neighbouring mol-ecules.
RESUMO
In the title compound, C19H16F3NO6, a quinoline derivative featuring an annealated furan substituent, the mean planes of the carb-oxy substituents are at an angle of 74.3â (2)°. In the crystal, C-Hâ¯O contacts result in undulating chains along [110]. C-Hâ¯F contacts also occur. The shortest centroid-centroid distance between rings is 3.3376â (7)â Å, involving two furan rings of neighbouring mol-ecules.
RESUMO
In the title compound, C14H19N3O2, the heterocycle adopts a (1)C4 conformation with the N atom being one of the flap atoms. In the crystal, classical N-Hâ¯O hydrogen bonds and C-Hâ¯O contacts connect the mol-ecules into a three-dimensional network.
RESUMO
In the crystal structur of the achiral title compound, C(9)H(8)N(2), N-Hâ¯N hydrogen bonds connect the mol-ecules into zigzag chains in [100]. Weak inter-molecular N-Hâ¯π inter-actions further consolidate the crystal packing.
RESUMO
In the title compound, C(20)H(21)N(3)O(2)·H(2)O, the aza-substitued six-membered ring adopts a (L4)B conformation. In the crystal, classical N-Hâ¯O, N-Hâ¯N and O-Hâ¯O hydrogen bonds connect the entities into a three-dimensional network. Intra-molecular C-Hâ¯O contacts are also observed.
RESUMO
In the title compound, C(15)H(12)ClNO, the isoxazoline ring adopts an envelope conformation with the C atom bearing an unsubstituted phenyl ring as the flap atom. The chlorinated phenyl group is nearly in-plane with the four coplanar atoms of the heterocycle and the corresponding mean planes enclosing an angle of 1.16â (7)°. The unsubstituted phenyl group attached to the envelope flap atom approaches a nearly perpendicular orientation relative to the isoxazoline ring with a dihedral angle of 74.93â (7)°. In the crystal, weak C-Hâ¯O, C-Hâ¯N and C-Hâ¯π inter-actions connect the mol-ecules into layers perpendicular to the a axis.
RESUMO
The title compound, C(20)H(22)N(2)O(3), is a secondary amine featuring an amide and an ester functionality in connection with a Michael system. The conformation about the C=C bond is E. Intra-molecular N-Hâ¯O hydrogen bonds occur. In the crystal, C-Hâ¯O contacts connect the mol-ecules into chains along the b-axis direction.
RESUMO
In the title compound, C23H27N3O4, the dihydro-pyridine ring adopts a (1,4)B conformation. Intra-molecular C-Hâ¯O contacts occur. In the crystal, N-Hâ¯O and N-Hâ¯N hydrogen bonds and C-Hâ¯N contacts connect the mol-ecules into strands along the a-axis direction.
RESUMO
In the title compound, C21H23N3O4S·H2O, the methyl-sulfanyl group is disordered over two sets of sites with site-occupancy factors of 0.631â (11) and 0.369â (11). The dihydro-pyridine ring adopts an E4 conformation. In the crystal, classical O-Hâ¯N, O-Hâ¯O and N-Hâ¯O hydrogen bonds, as well as C-Hâ¯O and C-Hâ¯S contacts, connect the mol-ecules into a three-dimensional network.
RESUMO
The asymmetric unit of the title compound, C13H10F3NO3, contains two independent mol-ecules with similar conformations. In the crystal, N-Hâ¯O hydrogen bonds link alternating independent mol-ecules into chains in [-110]. In the chain, the quinoline planes of the independent mol-ecules are almost perpendicular to each other, forming a dihedral angle of 89.8â (1)°. π-π inter-actions between the aromatic rings of quinoline bicycles related by inversion centres [for two independent centrosymmetric dimers, the shortest centroid-centroid distances are 3.495â (1) and 3.603â (1)â Å] link the hydrogen-bonded chains into layers parallel to (110). Weak C-Hâ¯F and C-Hâ¯O inter-actions further consolidate the crystal packing.