[Occupational Diseases in General Practice]. / Berufserkrankungen in der Hausarztpraxis.

This article shows an overview of occupational diseases. You can find a lot of these diseases in family practice. For treatment of occupational diseases specialists can be consulted. It is a big challenge to detect diseases caused by work influence. This is what you should do: inquire specifically about newly diagnosed illness after work. Ask about the current occupation and previous occupational activities. Already report the suspicion of an occupational disease to the competent authority. For every occupational disease, there is a leaflet with scientific basics, explanation of occupational stress and its impact on the body. Remedies and aids may not be prescribed by family doctors at the expense of the statutory health insurance.

(Eta3-phenylallyl)(phosphanyloxazoline)palladium complexes: X-ray crystallographic studies, NMR investigations, and Ab initio/DFT calculations.

All possible (eta(3)-allyl)palladium complexes (1-4) of the ligand (4S)-[2-(2'-diphenylphosphanyl)phenyl]-4,5-dihydro-4-(2-propyl)-oxazole (L 1) and eta(3)-allyl ligands with one to three phenyl substituents at the terminal allylic centers were synthesized and characterized by X-ray crystal structure analysis and, with respect to allylic isomers, by NMR investigations. Equilibrium geometries, electronic structures, and relative energies of isomeric complexes were computed by restricted Hartree-Fock (RHF) and density functional theory (DFT) calculations; experimentally determined isomer ratios could be reproduced. The results allowed important conclusions to be drawn regarding the mechanism of Pd-catalyzed asymmetric allylic substitutions.