RESUMO
Stipulation of fresh water for domestic use without any microbial, organic and inorganic contaminants is of high need. Sustainable, efficient, cost-effective and robust water purification technologies is of high need and it can be achieved using nanomaterials and their composite. Nanostructured graphene has unique properties like high surface to volume ratio, higher absorbability, reusability with minimal chemical alterations, and low cytotoxicity. From the validation of these properties, we have developed PLLA-Ag@graphene sandwich structures as an effective adsorbate for water purification application. As the real water bodies have lot of bacterial contaminants, the material is also designed as efficient adsorbate with antibacterial efficacy. In view of achieving these objectives, we have synthesized PLLA fibre mats by electrospinning method, followed by PLLA-Graphene and Ag decorated PLLA-graphene mats. The crystallite size for graphite and Ag@graphene was calculated as 30.82 nm and 43.79 nm, respectively. Furthermore, the UV analysis of Ag@graphene shows two peaks corresponding to graphene and Ag NP at 285 nm and 407 nm respectively. The layers were assembled in the order of polymeric fibre, as-fired biomass graphite, Ag@graphene for methodical filtration process. The filtration efficacy of the filtrate was tested using sewage water and the results shows higher contamination removal percentage of 87 % with TDS values in the drinking water standards after filtration. The antibacterial efficacy results also evidence of the potentialities of the hybrid system towards water purification application.
