Self-Formulated Na-Based Dual-Ion Battery Using Nonflammable SO2 -Based Inorganic Liquid Electrolyte.

Sodium secondary batteries have gained much attention as alternative power sources to replace lithium secondary batteries. However, some technical issues must be solved to ensure their success. Here, a highly safe and cost-effective Na-based dual-ion battery system employing self-formulated CuCl cathode material starting from a mixture of Cu and NaCl in conjunction with a nonflammable NaAlCl4 ·2SO2 inorganic liquid electrolyte is demonstrated. It is found that CuCl is spontaneously formed by redox coupling of Cu/Cu(I) and SO2 /SO2 - anion radical. In the proposed battery, Na+ and Cl- are employed as energy carriers for the anode and cathode, respectively, and it is further demonstrated that the Na-metal-free battery configuration is possible using a hard carbon anode. Owing to the use of cheap electrode materials and a highly conductive and safe electrolyte, the proposed batteries deserve to be regarded as a promising approach for next-generation Na rechargeable batteries.

Lithium-Ion Intercalation into Graphite in SO2-Based Inorganic Electrolyte toward High-Rate-Capable and Safe Lithium-Ion Batteries.

Herein, we have identified that lithium ions in an SO2-based inorganic electrolyte reversibly intercalate and deintercalate into/out of graphite electrode using ex situ X-ray diffraction and various electrochemical methods. X-ray photoelectron spectroscopy shows that the solid electrolyte interphase on the graphite electrode is mainly composed of inorganic compounds, such as LiCl and lithium sulfur-oxy compounds. Graphite electrode in SO2-based inorganic electrolyte has stable capacity retention up to 100 cycles and outstanding rate capability performance. This can be attributed to low interfacial impedance and high ionic conductivity of SO2-based inorganic electrolyte, which are superior to those of conventional organic electrolytes. Considering the remarkable rate capability and intrinsically nonflammable properties of the electrolyte, use of graphite and an SO2 electrolyte will likely facilitate the development of advanced lithium-ion batteries.

Dendrite-Free Li Metal Anode for Rechargeable Li-SO2 Batteries Employing Surface Modification with a NaAlCl4-2SO2 Electrolyte.

Dendritic growth of a Li metal anode during cycling is one of major issues to be addressed for practical application of Li metal rechargeable batteries. Herein, we demonstrate that surface modification of Li metal with a Na-containing SO2 electrolyte can be an effective way to prevent dendritic Li growth during cell operation. The surface-modified Li metal anode exhibited no dendritic deposits even under a high areal capacity (5 mA h cm-2) and a high current density (3 mA cm-2), whereas the unmodified anode showed typical filamentary Li deposition. The surface-modified Li metal anode also demonstrated significantly enhanced electrochemical performance, which could be attributed to the newly formed Na-containing inorganic surface layer that exhibits uniform and dense properties. Consequently, surface modification with a Na-containing SO2 inorganic electrolyte is suggested as one of the most effective ways to realize a highly stable Li metal anode with dendrite-free Li deposition for Li metal-based rechargeable batteries.