Solvent assisted evolution and growth mechanism of zero to three dimensional ZnO nanostructures for dye sensitized solar cell applications.

We report the structural engineering of ZnO nanostructures by a consistent solution method using distinct solvents such as ethylene glycol, 1-butanol, acetic acid and water. The growth kinetics are found to depend strongly on the physicochemical properties of the solvent and zeta potential of the colloidal solution. Furthermore, the resulting nanostructures as a photoanode material, displayed a prominent structure dependent property in determining the efficiency of dye-sensitized solar cells (DSSCs). The fabricated solar cell with ZnO nanostructures based photoanode exhibited improved conversion efficiency. Moreover, the nanoflower based DSSCs showed a higher conversion efficiency of 4.1% compared to the other structures. The excellent performance of ZnO nanoflower is attributed to its better light-harvesting ability and increased resistance to charge-recombination. Therefore ZnO nanostructures can be a promising alternative for TiO2 in DSSCs. These findings provide new insight into the simple, low cost and consistent synthetic strategies for ZnO nanostructures and its outstanding performance as a photoanode material in DSSCs.

Optical characterization and tunable antibacterial properties of gold nanoparticles with common proteins.

The interaction of three proteins, viz. Bovine Serum Albumin (BSA), Human Serum Albumin (HSA) and Hen Egg White Lysozyme (HEWL) with gold nanoparticles (GNPs) is investigated using surface plasmon resonance (SPR) spectroscopy, fluorescence spectroscopy and circular dichroism (CD). Size and morphology of the samples was established using Transmission Electron Microscopy (TEM) and stability studies was established using zeta potential analysis. The stability of protein-GNP complex was found to be greater than that of individual protein as well as individual GNPs. Also HEWL-GNP complex was more stable compared to the other protein complexes. Absorbance of proteins increases with increase in gold nanoparticle concentration due to the extension of peptide strands of protein and decrease in hydrophobicity of gold nanoparticles. A ground state complex is also formed which is evident from the moderate shift observed in the absorbance peaks. Apparent association constant was also determined from the absorption spectra and was found to be maximum for HEWL and minimum for HSA. Gold nanoparticles were found to act as quenchers and reduced the protein fluorescence intensity. Binding constant and number of binding sites were found to be maximum for HEWL and minimum for HSA. The temperature dependent fluorescence studies were also performed to calculate the thermodynamic parameters and to determine the nature of interaction between the proteins and gold nanoparticles. The circular dichroism studies elucidate the reason behind the maximum binding for HEWL and minimum binding for HSA. TGA analysis determined the thermal stability of the samples. Fluorescence lifetime studies indicate static quenching of proteins. Antibacterial activity of protein-gold nanoparticles was studied against four pathogens, viz. Bacillus pumilus, Escherichia coli, Pseudomonas aeruginosa, and Staphylococcus aureus. HEWL exhibits a tunable antimicrobial activity against Pseudomonas aeruginosa due to the maximum binding of HEWL with gold nanoparticles. The study proposes a novel method for adjusting the antibacterial activity of HEWL against Pseudomonas aeruginosa when the resistance of this pathogen is a major issue in the chemotherapy of many infectious diseases. Thus the combination therapy of protein-gold nanoparticles could prove to be a new approach in medical field in the near future.

Fluorescence resonance energy-transfer-based fluoride ion sensor.

The present work describes an energy-transfer-based fluoride sensor using the highly photo-stable Coumarin 540a (C540a)-Rhodamine 6g (Rh6g) dye pair. Rh6g exhibits a decrease in fluorescence emission, whereas C540a shows no change in response to fluoride. The increase in fluoride concentration decreases the energy transfer efficiency between the C540a donor and Rh6g acceptor in acetonitrile, leading to a subsequent recovery of fluorescence emission from C540a molecules. The sensing mechanism using fluorescence resonance energy transfer is found to be highly specific towards fluoride detection when compared to the response towards other anions. The fluorescence emission of both dyes is monitored to enable fluoride detection within a broad range.

Ag nanowire-assisted low threshold WGM lasing from polymer optical fiber.

Whispering Gallery Mode (WGM) emission has been observed from Ag nanowire doped polymer optical fiber laser. Low threshold lasing and high photostability of the active medium has been noticed with a given concentration of Ag nanowires in the microcavity of the fiber. Quantum yield and lifetime measurements of the dye (active medium) with and without nanowires confirm that presence of nanowires enhance the rate of radiative decay of the fluorophore, thereby providing low pump pulse energy for the excitation of lasing modes in the cavity, as compared with a bare dye-doped polymer fiber laser.

Thermo-optic tuning of whispering gallery mode lasing from a dye-doped hollow polymer optical fiber.

We report temperature-induced tuning of whispering gallery mode (WGM) laser emission from a Rhodamine-B-doped polymethylmethacrylate hollow optical fiber. Lasing studies on dye-doped hollow fibers with different radii were carried out with optical pumping using a Q-switched Nd:YAG laser. The observed lasing modes were confirmed as WGM emission with a high quality factor of 7.58×103. The diameter-dependent variation in lasing spectra of these hollow fibers was investigated. A tuning range of 0.44 nm with a sensitivity of 0.011 nm/°C was obtained for the lasing modes by varying the temperature from 25°C to 60°C from a dye-doped polymethylmethacrylate hollow fiber of diameter 305 µm.

Photochemical Degradation of Curcumin: a Mechanism for Aqueous Based Sensing of Fluoride.

The present work describes the enhanced photochemical degradation of natural dye Curcumin in acetonitrile-water mixture in the presence of fluoride upon irradiation with light. The strong basicity of fluoride modifies the solvent environment around Curcumin molecule leading to alkaline mediated degradation of Curcumin which is further accelerated by irradiation with light. The photochemical degradation of Curcumin is studied using absorption and fluorescence spectroscopy and verified using infrared spectroscopy and fluorescence lifetime studies. The results of the work indicate that the method of Curcumin irradiation can be used as a sensing technique for fluoride detection in a wide range.

Tuning whispering gallery lasing modes from polymer fibers under tensile strain.

Wavelength tuning of whispering gallery lasing modes has been observed from Rhodamine-B-doped polymer fibers under tensile strain. Good quality whispering gallery lasing modes are produced from both solid and hollow fibers by transverse optical pumping. The lasing modes are shifted linearly toward the shorter wavelength side when the fiber is elongated in the axial direction. Compared with solid fiber, the lasing modes of hollow fiber can be tuned over the entire gain spectrum with a tuning range of ∼5 nm. It is found that the tuning of the lasing modes of hollow fiber is reversible.

Laser emission from the whispering gallery modes of a graded index fiber.

Whispering gallery mode (WGM) laser emission has been observed from rhodamine B doped polymer optical graded index (GI) fiber by transverse pumping with a frequency doubled Q-switched Nd:YAG laser. The propagation and confinement of these modes were also observed. A variation in the free spectral range from 0.29 to 1.24 nm is obtained along the length due to the confinement of WGMs in the GI fiber.