Monitoring Air Pollution in Greek Urban Areas During the Lockdowns, as a Response Measure of SARS-CoV-2 (COVID-19).

On March 11, 2020, the World Health Organization declared COVID-19 (SARS-CoV-2) a pandemic. Countries all over the world imposed restriction measures, in an attempt to limit the expansion of the pandemic. Provided that human activities in large urban areas affect air quality, we studied the concentrations of gaseous pollutants ΝΟ, ΝΟ2, O3, C6H6, and particulate matter PM10 in the air, through gas pollution measuring stations in the center of Athens (Greek capital), the center of Piraeus (Greece's largest port), Athens International Airport (most international and domestic flights within Greece). We monitored and compared the concentrations of ΝΟ, ΝΟ2, O3, C6H6, and ΡΜ10, of 2020 to those of the previous years and found that the primary air pollutants, ΝΟ, ΝΟ2, and C6H6, recorded decreased compared to those of the past years. The O3, which is produced secondarily at the ground of the earth being inversely dependent on NO/NO2, had in most cases increased. The particulate matter PM10, although reduced by the cessation of human activities, was inextricably linked to natural conditions, such as wind velocity and direction transporting African desert dust masses through storms, during which at certain periods was showing increased in concentrations. Supplementary Information: The online version contains supplementary material available at 10.1007/s11270-022-06024-7.

Cosmetic wastewater treatment technologies: a review.

Over the past three decades, environmental concerns about the water pollution have been raised on societal and industrial levels. The presence of pollutants stemming from cosmetic products has been documented in wastewater streams outflowing from industrial as well as wastewater treatment plants. To this end, a series of consistent measures should be taken to prevent emerging contaminants of water resources. This need has driven the development of technologies, in an attempt to mitigate their impact on the environment. This work offers a thorough review of existing knowledge on cosmetic wastewater treatment approaches, including, coagulation, dissolved air flotation, adsorption, activated sludge, biodegradation, constructed wetlands, and advanced oxidation processes. Various studies have already documented the appearance of cosmetics in samples retrieved from wastewater treatment plants (WWTPs), which have definitely promoted our comprehension of the path of cosmetics within the treatment cycle; however, there are still multiple blanks to our knowledge. All treatments have, without exception, their own limitations, not only cost-wise, but also in terms of being feasible, effective, practical, reliable, and environmentally friendly.

Arsenic exposure promotes the emergence of cardiovascular diseases.

A large number of studies conducted in the past decade 2010-2020 refer to the impact of arsenic (As) exposure on cardiovascular risk factors. The arsenic effect on humans is complex and mainly depends on the varying individual susceptibilities, its numerous toxic expressions and the variation in arsenic metabolism between individuals. In this review we present relevant data from studies which document the association of arsenic exposure with various biomarkers, the effect of several genome polymorphisms on arsenic methylation and the underling molecular mechanisms influencing the cardiovascular pathology. The corresponding results provide strong evidence that high and moderate-high As intake induce oxidative stress, inflammation and vessel endothelial dysfunction that are associated with increased risk for cardiovascular diseases (CVDs) and in particular hypertension, myocardial infarction, carotid intima-media thickness and stroke, ventricular arrhythmias and peripheral arterial disease. In addition, As exposure during pregnancy implies risks for blood pressure abnormalities among infants and increased mortality rates from acute myocardial infarction during early adulthood. Low water As concentrations are associated with increased systolic, diastolic and pulse pressure, coronary heart disease and incident stroke. For very low As concentrations the relevant studies are few. They predict a risk for myocardial infarction, stroke and ischemic stroke and incident CVD, but they are not in agreement regarding the risk magnitude.

Cadmium accumulation, translocation factor, and health risk potential in a wastewater-irrigated soil-wheat (Triticum aestivum L.) system.

The accumulation of trace elements in wastewater-irrigated soils may introduce them to the food chain and therefore can threaten human health. The present study investigated the accumulation, translocation factor, and health risk potential of cadmium (Cd) in a soil-wheat system irrigated with treated wastewater compared with a reference soil (irrigated with fresh water). All treated wastewater-irrigated soils showed significantly higher levels of electrical conductivity (EC) than that of reference soil by 75-143%. Irrigation with treated wastewater increased both available and total Cd content in soil by 2-4 times. In all irrigated sites, Cd content was about twice as great as the maximum acceptable rate. Bioconcentration factor (BCF) and translocation factor (TF) indicated that Cd was mainly accumulated in the roots (BCF = 2.2-3.1), while little mobilization from roots to stems and grains was noted (TFshoot/root = 0.07-0.21; TFgrain/root = 0.18-0.24). The average hazard quotient (HQ) for different age groups of the population varied in the range of 0.1-1.0, implying low non-carcinogenic health risk of Cd to local wheat-consuming residents. The risk of Cd to cause carcinogenic health risk (CR) was in the range of 1 × 10-5 to 1 × 10-4, indicating low to moderate potential risk. CR for different age groups was in the order: individuals above 18 years old > individuals 7-18 years old > individuals 0-6 years old. For reducing potential health risks to local people, it is imperative to continuously monitor heavy metal levels in the wheat-soil system and urgently adopt more efficient managerial strategies to reduce Cd contamination.

Impact of the uncontrolled leakage of leachate from a municipal solid waste landfill on soil in a cultivated-calcareous environment.

The heavy metal pollution generated by landfill leachate becomes increasingly concerning due to its potential to impact human health through the food chain. In the present study, the accumulation and potential health risk of heavy metals (Zn, Cu, Cd, Pb, and Ni) were investigated in a calcareous soil -wheat system affected by an uncontrolled landfill leachate. The results showed soils were significantly enriched by both the available and total fractions of the metals in the sequences of Zn > Pb > Ni > Cd > Cu and Cd > Zn > Ni > Pb > Cu, respectively. Nevertheless, only the Cd content exceeded the standard levels. For the various population groups, the mean hazard quotient (HQ) was lower than the unity, implying a lack of non-carcinogenic health risk for the local residents, while the average hazard index (HI) was 2.3 and 1.1 for people aged 0-5 and 6-18 years, respectively, illustrating a moderate non-carcinogenic health risk for the two groups. Cd and Pb contributed the most to HI, followed by Cu, Zn, and Ni. In addition, the carcinogenic health risk of Cd, ranging from 1 × 10-5 to 1 × 10-6, showed a low potential risk in the different population groups exposed to wheat grains and decreased in the sequence of adult > population 6-18 years > population 0-5 years. The findings of the study, which can be used in regions under similar environmental conditions, provide a valuable benchmark for the design of appropriate strategies to manage these agroecosystems by both local and national managers of such macrosystems.

Arsenic and antimony removal from drinking water by adsorption on granular ferric oxide.

Arsenic and antimony occur in drinking water due to natural weathering or anthropogenic activities. There has been growing concern about their impact on health. The aim of this study was to assess the efficiency of a granular ferric oxide adsorbent medium to remove arsenic and antimony from drinking water via rapid small-scale column tests (RSSCTs). Three different water matrices - deionized, raw water treated with a reverse osmosis domestic device and raw water - were spiked with arsenic and/or antimony to a concentration of 100 µg L⁻¹. Both elements were successfully adsorbed onto the medium. The loadings until the guideline value was exceeded in the effluent were found to be 0.35-1.63 mg g⁻¹ for arsenic and 0.12-2.11 mg g⁻¹ for antimony, depending on the water matrix. Adsorption of one element was not substantially affected by the presence of the other. Aeration did not affect significantly the adsorption capacity. Granular ferric oxide could be employed for the simultaneous removal of arsenic and antimony from drinking water, whereas full-scale systems should be assessed via laboratory tests before their implementation.

Interrelationships of pollution load index, transfer factor, and concentration factor under the effect of sludge.

A greenhouse experiment was conducted during 2010-2011. A complete randomized blocks design was used including seven treatment levels of sludge(tons per hectare), i.e., 0, 6, 12, 18, 24, 30, and "30+ treated wastewater", in four replications. Lettuce (Lactuca sativa L var longifolia) was chosen as a test plant. The purpose of the experiment was to study the relationships between soil Pollution Load Index, heavy metal transfer factor, and concentration factor and to determine optimum concentration factor values. The following were found: several mathematical relationships were established between the above parameters that could be used for the study of heavy metal accumulation in soils and plants under the effect of the applied sludge. They can be also used for the calculation of one of the above parameters as a function of the others. Based on the experimental data, the optimum concentration factor for several heavy metals were determined by multiple linear regression analysis, expressing the concentration factor as a function of the maximum dry lettuce matter yield, and of optimum/minimum heavy metal content of plant dry matter. The mean value of the calculated concentration factor obtained for each separate metal was: Zn, 2.93; Cd, 0.39; Co, 1.47; and Ni, 0.52.

Soil pollution under the effect of treated municipal wastewater.

Soil heavy metal pollution due to wastewater reuse was assessed by means of the concentration factor (CF) and/or pollution load index (PLI).In this respect, a greenhouse pot experiment was conducted, using a completely randomized block design, including five treatments of treated municipal wastewater (0%, 25%, 50%, 75%, and 100%), in four replications. Brassica oleracea var. Capitata was used as a test crop. The optimum CFs were expressed as a function of maximum dry matter of cabbage plant parts yield, and the values obtained per plant part were as follows: stems-Zn-CF 2.96, Co-CF 0.85, Ni-CF 0.92; whole plant-Cu-CF 3.90, Ni-CF 0.87, and Pb-CF 11.52; and leaves-Pb-CF 11.78. The PLI was calculated as the geometric mean of the CF of each metal, and was related to the maximum dry mater yield of cabbage stems and heads. The optimum values found were: stems PLI 1.99-2.55 and heads 2.25.