RESUMO
Carbonic acid (H2CO3) is a fundamental species in biological, ecological, and astronomical systems. However, its spectroscopic characterization is incomplete because of its reactive nature. The photoionization (PI) and the photoion mass-selected threshold photoelectron (ms-TPE) spectra of H2CO3 were obtained by utilizing vacuum ultraviolet (VUV) synchrotron radiation and double imaging photoelectron photoion coincidence spectroscopy. Two carbonic acid conformers, namely, cis-cis and cis-trans, were identified. Experimental adiabatic ionization energies (AIEs) of cis-cis and cis-trans H2CO3 were determined to be 11.27 ± 0.02 and 11.18 ± 0.03 eV, and the cation enthalpies of formation could be derived as ΔfH°0K = 485 ± 2 and 482 ± 3 kJ mol-1, respectively. The cis-cis conformer shows intense peaks in the ms-TPES that are assigned to the C=O/C-OH stretching mode, while the cis-trans conformer exhibits a long progression to which two C=O/C-OH stretching modes contribute. The TPE spectra allow for the sensitive and conformer-selective detection of carbonic acid in terrestrial experiments to better understand astrochemical reactions.
RESUMO
Photoion mass-selected threshold photoelectron spectroscopy (ms-TPES) is a synchrotron-based, universal, sensitive, and multiplexed detection tool applied in the areas of catalysis, combustion, and gas-phase reactions. Isomer-selective vibrational fingerprints in the ms-TPES of stable and reactive intermediates allow for unequivocal assignment of spectral carriers. Case studies are presented on heterogeneous catalysis, revealing the role of ketenes in the methanol-to-olefins process, the catalytic pyrolysis mechanism of lignin model compounds, and the radical chemistry upon C-H activation in oxyhalogenation. These studies demonstrate the potential of ms-TPES as an analytical technique for elucidating complex reaction mechanisms. We examine the robustness of ms-TPES assignments and address sampling effects, especially the temperature dependence of ms-TPES due to rovibrational broadening. Data acquisition approaches and the Stark shift from the extraction field are also considered to arrive at general recommendations. Finally, the PhotoElectron PhotoIon Spectral Compendium (https://pepisco.psi.ch), a spectral database hosted at Paul Scherrer Institute to support assignment, is introduced.
RESUMO
Understanding how isomerism influences photoelectron spectra helps in the assignment and analysis of reactive mixtures, especially for heterocycles with numerous isomers. Threshold photoelectron spectra of lutidyl radical isomers, i. e., benzyl derivatives with a nitrogen heteroatom and a methyl substituent, are recorded using vacuum ultraviolet synchrotron radiation. The radicals are produced by flash pyrolysis from aminomethyl methylpyridine precursors. Experimental ionization energies are determined to be 7.54, 7.50, and 7.45â eV for 2,4-, 2,6- and 3,5-lutidyl, respectively, in excellent agreement with composite method calculations. Franck-Condon simulations aid the TPES assignment but are also shown to exhibit artifacts if large-amplitude motions, notably the methyl internal rotation are assumed to be active in the double harmonic approximation. Based on calculated adiabatic ionization energies (AIE) of benzyl, picolyl, and xylyl radicals, the N and CH3 substituent effects are found to be additive, position-dependent and decrease in the para>orthoâ³meta order in magnitude with the nitrogen heteroatom increasing and the methyl substituent decreasing the AIE. These effects are discussed in light of the charge distribution upon ionization. The additivity of the substituent effects also helps predict the influence of substituents on the binding energy of the unpaired electron in analogous radicals.
