Electrospun Nanofibre Filtration Media to Protect against Biological or Nonbiological Airborne Particles.

Electrospun nanofibres can outperform their melt-blown counterparts in many applications, especially air filtration. The different filtration mechanisms of nanofibres are particularly important when it comes to the air filtration of viruses (such as COVID-19) and bacteria. In this work, we present an electrospun nanofibre filter media, FilterLayrTM by NanoLayr Ltd., containing poly(methyl methacrylate)/ethylene vinyl alcohol nanofibres. The outstanding uniformity of the nanofibres was indicated by the good correlation between pressure drop (ΔP) and areal weight with R2 values in the range of 0.82 to 0.98 across various test air velocities. By adjusting the nanofibre areal weight (basis weight), the nanofibre filter media was shown to meet the particle filtration efficiency and breathability requirements of the following internationally accepted facemask and respirator standards: N95 respirator facemask performance in accordance with NIOSH 42CFR84 (filtration efficiency of up to 98.10% at a pressure drop of 226 Pa and 290 Pa at 85 L·min-1 and 120 L·min-1, respectively), Level 2 surgical facemask performance in accordance with ASTM F2299 (filtration efficiency of up to 99.97% at 100 nm particle size and a pressure drop of 44 Pa at 8 L·min-1), and Level 2 filtration efficiency and Level 1 breathability for barrier face coverings in accordance with ASTM F3502 (filtration efficiency of up to 99.68% and a pressure drop of 133 Pa at 60 L·min-1), with Level 2 breathability being achievable at lower nanofibre areal weights.

Correction: Substituents drive ligand rearrangements, giving dinuclear rather than mononuclear complexes, and tune CoII/III redox potential.

Correction for 'Substituents drive ligand rearrangements, giving dinuclear rather than mononuclear complexes, and tune CoII/III redox potential' by Fabrice N. H. Karabulut et al., Dalton Trans., 2018, 47, 11749-11759, DOI: .

Substituents drive ligand rearrangements, giving dinuclear rather than mononuclear complexes, and tune CoII/III redox potential.

Three new tetradentate imine ligands, HLHBr, HLClH and HLBrH (HLR1R2) were synthesised by 2 : 1 condensation of the appropriately n-halo substituted pyridine-2-carboxaldehyde (5-bromo-4a, 6-bromo-4b or 6-chloro-4c) with 1,3-diaminopropan-2-ol (5). Reactions of each of these three ligands with one equivalent of cobalt(ii) tetrafluoroborate resulted in the formation of three N4O2 coordinated cobalt(ii) complexes: the anticipated mononuclear complex [CoII(HLHBr)(MeOH)2](BF4)2 (1), and two unexpected dinuclear complexes, [CoII2(LBrH-BF2OMe)]2(BF4)2 (2) and [CoII2(LClH-BF2OMe)]2(BF4)2 (3). Dinuclear 2 and 3 result from complexation of cobalt(ii) to the ligands derived from the sterically demanding 6-halo substituted pyridine-2-carboxaldehydes (4b and 4c) undergoing rearrangement, reacting with MeOH and a BF4 anion, resulting in a pair of borate ester bridges between the two cobalt(ii) centres. A similar type of rearrangement is proposed for the PF6 analogues. Cyclic voltammetry in acetonitrile reveals that cobalt(ii) complexes 1-3 undergo a quasi-reversible oxidation: Em = 0.57, 0.38 and 0.29 V vs. 0.01 AgNO3/Ag, respectively. The observed Em value is tuned by the ligand, with the 6-chloro-substituent leading to the lowest Em value being observed for the corresponding cobalt complex, 3, rather than for either of the complexes of the n-bromo-substituted ligands (n = 6 or 5), 2 and 1.