1.
Chem Commun (Camb)
; 48(89): 10993-5, 2012 Nov 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23038212
RESUMO
4-exo-trig Cyclization reaction of a 4-pentenyl carbon radical containing the gem-difluoromethylene moiety adjacent to a radical accepting α,ß-unsaturated ester was found to proceed efficiently to furnish a novel gem-difluorocyclobutane derivative. The cyclized product could be transformed into a gem-difluoromethylene analogue of oxetanocin T.