1.
Org Biomol Chem
; 12(15): 2394-403, 2014 Apr 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-24595409
RESUMO
A palladium-catalyzed cyclization of ß-enaminocarbonyl compounds with allylic bisacetates is described. 2-Vinyl-2,3-dihydropyrroles and 3-methylene-1,2,3,4-tetrahydropyridines were produced from the reaction of ß-enaminocarbonyl compounds with 1,4-diacetoxy-2-butene and 2-methylene-1,3-propanediol diacetate, respectively.
Assuntos
Acetatos/química , Alcenos/química , Paládio/química , Piridinas/química , Piridinas/síntese química , Pirróis/química , Pirróis/síntese química , Catálise , Técnicas de Química Sintética , Ciclização
2.
J Org Chem
; 78(4): 1687-92, 2013 Feb 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23363421
RESUMO
The reaction of propargylic carbonates with 4-hydroxy-2-pyrones in the presence of a palladium catalyst is described. By the choice of the reaction temperature, two types of the substituted furo[3,2-c]pyran-4-one derivatives were regioselectively synthesized, respectively.