1.
Nat Prod Commun
; 8(7): 873-5, 2013 Jul.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23980414
RESUMO
The second generation total synthesis of the neo-clerodane diterpenoid, methyl barbascoate, was accomplished in seven or nine linear steps via double enol triflation and subsequent palladium catalyzed double carbonylation, followed by regioselective samarium diiodide mediated conjugate reduction.
Assuntos
Furanos/síntese química , Compostos Heterocíclicos com 3 Anéis/síntese química
2.
Nat Prod Commun
; 6(3): 311-3, 2011 Mar.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21485265
RESUMO
The total synthesis of the recently isolated bicyclic sesquiterpenoid drechslerine B (2), isolated from the algicolous fungus Drechslera dematioidearare in the marine red alga Liagora viscida, has been achieved, starting from (S)-carvone (8), via an intramolecular aldol reaction and palladium-catalyzed carbon monoxide insertion as key reactions.