Polarization-Dependent Lasing Behavior from Low-Symmetry Nanocavity Arrays.

This paper reports how geometric effects in low-symmetry plasmonic nanoparticle arrays can produce polarization-dependent lasing responses. We developed a scalable fabrication procedure to pattern rhombohedral arrays of aluminum anisotropic nanoparticles that support lattice plasmon modes from both first-order and second-order diffraction coupling. We found that nanoparticle shape can be used to engineer the spatial overlap between electromagnetic hot spots of different lattice modes and dye gain to support plasmonic lasing. The lasing behavior revealed that plasmon-exciton energy transfer depends on polarization, with stronger coupling and faster dynamics when the transition dipole moments of the excited gain are aligned with the electric field of the plasmon modes.

Lattice-Resonance Metalenses for Fully Reconfigurable Imaging.

This paper describes a reconfigurable metalens system that can image at visible wavelengths based on arrays of coupled plasmonic nanoparticles. These lenses manipulated the wavefront and focused light by exciting surface lattice resonances that were tuned by patterned polymer blocks on single-particle sites. Predictive design of the dielectric nanoblocks was performed using an evolutionary algorithm to create a range of three-dimensional focusing responses. For scalability, we demonstrated a simple technique for erasing and writing the polymer nanostructures on the metal nanoparticle arrays in a single step using solvent-assisted nanoscale embossing. This reconfigurable materials platform enables tunable focusing with diffraction-limited resolution and offers prospects for highly adaptive, compact imaging.

Stretchable Nanolasing from Hybrid Quadrupole Plasmons.

This paper reports a robust and stretchable nanolaser platform that can preserve its high mode quality by exploiting hybrid quadrupole plasmons as an optical feedback mechanism. Increasing the size of metal nanoparticles in an array can introduce ultrasharp lattice plasmon resonances with out-of-plane charge oscillations that are tolerant to lateral strain. By patterning these nanoparticles onto an elastomeric slab surrounded by liquid gain, we realized reversible, tunable nanolasing with high strain sensitivity and no hysteresis. Our semiquantum modeling demonstrates that lasing build-up occurs at the hybrid quadrupole electromagnetic hot spots, which provides a route toward mechanical modulation of light-matter interactions on the nanoscale.

Structural Engineering in Plasmon Nanolasers.

This review focuses on structural engineering of lasers from the macroscale to the nanoscale, with an emphasis on plasmon nanolasers. Conventional lasers based on Fabry-Pérot cavities are limited in device size. In contrast, plasmon nanolasers can overcome the diffraction limit of light and incorporate unique structural designs to engineer cavity geometries and optical band structure. Since the spaser concept was introduced in 2003, tremendous progress in nanolasing has been made on architectures that exploit metal films and nanoparticles. Theoretical approaches in both frequency and time domains have inspired the development of plasmon nanolasers based on mode analysis and time-dependent lasing buildup. Plasmon nanolasers designed by band-structure engineering open prospects for manipulation of lasing characteristics such as directional emission, real-time tunable wavelengths, and controlled multimode lasing.

Sequential Feature-Density Doubling for Ultraviolet Plasmonics.

Patterning of nanostructures with sub-200 nm periodicities over cm2-scale areas is challenging using standard approaches. This paper demonstrates a scalable technique for feature-density doubling that can generate nanopatterned lines with periodicities down to 100 nm covering >3 cm2. We developed a process based on controlled wet overetching of atomic-layer deposited alumina to tune feature sizes of alumina masks down to several nm. These features transferred into silicon served as masters for template-stripping aluminum nanogratings with three different periodicities. The aluminum nanogratings supported surface plasmon polariton modes at ultraviolet wavelengths that, in agreement with calculations, depended on periodicity and incident excitation angle.

Unidirectional Lasing from Template-Stripped Two-Dimensional Plasmonic Crystals.

Plasmon lasers support cavity structures with sizes below that of the diffraction limit. However, most plasmon-based lasers show bidirectional lasing emission or emission with limited far-field directionality and large radiative losses. Here, we report unidirectional lasing from ultrasmooth, template-stripped two-dimensional (2D) plasmonic crystals. Optically pumped 2D plasmonic crystals (Au or Ag) surrounded by dye molecules exhibited lasing in a single emission direction and their lasing wavelength could be tuned by modulating the dielectric environment. We found that 2D plasmonic crystals were an ideal architecture to screen how nanocavity unit-cell structure, metal material, and gain media affected the lasing response. We discovered that template-stripped strong plasmonic materials with cylindrical posts were an optimal cavity design for a unidirectional laser operating at room temperature.