Extreme mechanical resilience of self-assembled nanolabyrinthine materials.

Low-density materials with tailorable properties have attracted attention for decades, yet stiff materials that can resiliently tolerate extreme forces and deformation while being manufactured at large scales have remained a rare find. Designs inspired by nature, such as hierarchical composites and atomic lattice-mimicking architectures, have achieved optimal combinations of mechanical properties but suffer from limited mechanical tunability, limited long-term stability, and low-throughput volumes that stem from limitations in additive manufacturing techniques. Based on natural self-assembly of polymeric emulsions via spinodal decomposition, here we demonstrate a concept for the scalable fabrication of nonperiodic, shell-based ceramic materials with ultralow densities, possessing features on the order of tens of nanometers and sample volumes on the order of cubic centimeters. Guided by simulations of separation processes, we numerically show that the curvature of self-assembled shells can produce close to optimal stiffness scaling with density, and we experimentally demonstrate that a carefully chosen combination of topology, geometry, and base material results in superior mechanical resilience in the architected product. Our approach provides a pathway to harnessing self-assembly methods in the design and scalable fabrication of beyond-periodic and nonbeam-based nano-architected materials with simultaneous directional tunability, high stiffness, and unsurpassed recoverability with marginal deterioration.

Acoustic properties of porous microlattices from effective medium to scattering dominated regimes.

Microlattices are architected materials that allow for an unprecedented control of mechanical properties (e.g., stiffness, density, and Poisson's coefficient). In contrast to their quasi-static mechanical properties, the acoustic properties of microlattices remain largely unexplored. This paper analyzes the acoustic response of periodic millimeter-sized microlattices immersed in water using experiments and numerical simulations. Microlattices are fabricated using high-precision stereolithographic three-dimensional printing in a large variety of porosities and lattice topologies. This paper shows that the acoustic propagation undergoes a frequency dependent transition from a classic poroelastic behaviour that can be described by Biot's theory to a regime that is dominated by scattering effects. Biot's acoustic parameters are derived from direct simulations of the microstructure using coupled fluid and solid finite elements. The wave speeds predicted with Biot's theory agree well with the experimental measures. Within the scattering regime, the signals show a strong attenuation and dispersion, which is characterized by a cut-off frequency. The strong dispersion results in a frequency dependent group velocity. A simplified model of an elastic cylindrical scatterer allows predicting the signal attenuation and dispersion observed experimentally. The results in this paper pave the way for the creation of microlattice materials for the control of ultrasonic waves across a wide range of frequencies.

Harnessing Photochemical Shrinkage in Direct Laser Writing for Shape Morphing of Polymer Sheets.

Structures that change their shape in response to external stimuli unfold possibilities for more efficient and versatile production of 3D objects. Direct laser writing (DLW) is a technique based on two-photon polymerization that allows the fabrication of microstructures with complex 3D geometries. Here, it is shown that polymerization shrinkage in DLW can be utilized to create structures with locally controllable residual stresses that enable programmable, self-bending behavior. To demonstrate this concept, planar and 3D-structured sheets are preprogrammed to evolve into bio-inspired shapes (lotus flowers and shark skins). The fundamental mechanisms that control the self-bending behavior are identified and tested with microscale experiments. Based on the findings, an analytical model is introduced to quantitatively predict bending curvatures of the fabricated sheets. The proposed method enables simple fabrication of objects with complex geometries and precisely controllable shape morphing potential, while drastically reducing the required fabrication times for producing 3D, hierarchical microstructures over large areas in the order of square centimeters.

Deployable micro-traps to sequester motile bacteria.

The development of strategies to reduce the load of unwanted bacteria is a fundamental challenge in industrial processing, environmental sciences and medical applications. Here, we report a new method to sequester motile bacteria from a liquid, based on passive, deployable micro-traps that confine bacteria using micro-funnels that open into trapping chambers. Even in low concentrations, micro-traps afford a 70% reduction in the amount of bacteria in a liquid sample, with a potential to reach >90% as shown by modelling improved geometries. This work introduces a new approach to contain the growth of bacteria without chemical means, an advantage of particular importance given the alarming growth of pan-drug-resistant bacteria.

Engineered metabarrier as shield from seismic surface waves.

Resonant metamaterials have been proposed to reflect or redirect elastic waves at different length scales, ranging from thermal vibrations to seismic excitation. However, for seismic excitation, where energy is mostly carried by surface waves, energy reflection and redirection might lead to harming surrounding regions. Here, we propose a seismic metabarrier able to convert seismic Rayleigh waves into shear bulk waves that propagate away from the soil surface. The metabarrier is realized by burying sub-wavelength resonant structures under the soil surface. Each resonant structure consists of a cylindrical mass suspended by elastomeric springs within a concrete case and can be tuned to the resonance frequency of interest. The design allows controlling seismic waves with wavelengths from 10-to-100 m with meter-sized resonant structures. We develop an analytical model based on effective medium theory able to capture the mode conversion mechanism. The model is used to guide the design of metabarriers for varying soil conditions and validated using finite-element simulations. We investigate the shielding performance of a metabarrier in a scaled experimental model and demonstrate that surface ground motion can be reduced up to 50% in frequency regions below 10 Hz, relevant for the protection of buildings and civil infrastructures.

Composite 3D-printed metastructures for low-frequency and broadband vibration absorption.

Architected materials that control elastic wave propagation are essential in vibration mitigation and sound attenuation. Phononic crystals and acoustic metamaterials use band-gap engineering to forbid certain frequencies from propagating through a material. However, existing solutions are limited in the low-frequency regimes and in their bandwidth of operation because they require impractical sizes and masses. Here, we present a class of materials (labeled elastic metastructures) that supports the formation of wide and low-frequency band gaps, while simultaneously reducing their global mass. To achieve these properties, the metastructures combine local resonances with structural modes of a periodic architected lattice. Whereas the band gaps in these metastructures are induced by Bragg scattering mechanisms, their key feature is that the band-gap size and frequency range can be controlled and broadened through local resonances, which are linked to changes in the lattice geometry. We demonstrate these principles experimentally, using advanced additive manufacturing methods, and inform our designs using finite-element simulations. This design strategy has a broad range of applications, including control of structural vibrations, noise, and shock mitigation.