1.
Acta Crystallogr C
; 63(Pt 4): m144-6, 2007 Apr.
Artigo
em Inglês
| MEDLINE
| ID: mdl-17413215
RESUMO
In the title compound, [Ge(C(8)H(14)NO)(2)Cl]CF(3)SO(3), which is the first complex containing an eight-membered lactam (enantholactam) as ligand, the coordination polyhedron of the Ge(IV) atom is intermediate between trigonal-bipyramidal and square-pyramidal. Quantum chemical calculations of the crystal structure indicate the absence of additional coordination bonding between the Ge(IV) atom and the trifluoromethanesulfonate anion.