Magnetic field effect on the free induction decay of hydroxyl radicals (OH) in the terahertz region.

The effect of an external longitudinal magnetic field on the optical free induction decay from a free radical is observed for the first time. The experiments were performed on a rotational transition of the hydroxyl radical, OH (2Π3/2(J = 1) ← 2Π3/2(J = 0) at 83.8 cm-1), using a terahertz free electron laser. In contrast to the results of the experiments with a stable paramagnetic molecule, NO, the observed effect of an external magnetic field on the free induction decay from hydroxyl radicals is more complicated. A longitudinal magnetic field leads to the rotation of the polarization plane of the FID radiation and to an additional modulation of the signal intensity. The angle of the rotation of the plane of polarization is large, in agreement with the theoretical predictions. The observed FID kinetics in the time domain are in semi-quantitative agreement with the modeling. This observation opens an opportunity for the selective detection of weak signals of short-lived reactive paramagnetic free radicals from overwhelming signals that originate from stable non-paramagnetic species by polarization discrimination.

3D micro/nanoshaping of metal strip arrays by direct imprinting for chiral metasurfaces.

An original hybrid method for three-dimensional (3D) shaping of micro- and nanostructures by direct imprinting of lithographically patterned metal 2D-elements on a polymer substrate is proposed. The technological features of the method are demonstrated by transforming Au micro/nanostrip arrays into 3D half-turn helices. The metasurface formed by an array of 3D half-turn Au microhelices in the surface layer of a polymer substrate rotates the polarization plane of transmitted 3 THz radiation through an angle in excess of 50°. Both experimentally and numerically, it is established that the metasurface permits to control the state of polarization and the intensity of transmitted linearly polarized THz radiation using half-wavelength and guided-mode resonances as well as diffraction effects. The proposed approach enables the fabrication of double-layer arrays of half-helices, designed for infrared metasurfaces, from 80 nm wide Au nanostrips. These studies not only pave the way towards the fabrication of large-area chiral metamaterials but, also, open a new avenue in the development of 3D micro/nanostructures for other applications.

Regular and anomalous extraordinary optical transmission at the THz-gap.

In this paper Anomalous Extraordinary Transmission (ET) is reported for s-polarization of low loss doubly periodic subwavelength hole arrays patterned on polypropylene (PP) substrates by conventional contact photolithography at the so-called THz-gap (1-10 THz). The unexpected enhanced transmittance for s-polarization (i.e. without spoof plasmons) was previously numerically demonstrated in subwavelength slits arrays. However, subsequently no experimental work has been devoted to this unexpected Extraordinary Transmission neither in subwavelength slits nor in subwavelength holes. Here, numerical study and experimental results of the Anomalous ET and the symmetric and antisymmetric transmittance modes associated with the already well-known p-polarization ET are shown alongside a systematically analysis of the frequency peaks as a function of hole size for both incident polarizations.

Commissioning of the accelerator-recuperator for the FEL at the Siberian Center for Photochemical Research.

A 100 MeV eight-turn accelerator-recuperator intended to drive a high-power infrared free-electron laser (FEL) is currently under construction in Novosibirsk. The first stage of the machine includes a one-turn accelerator-recuperator that contains a full-scale RF system. It was commissioned successfully in June 2002.