1.
Org Lett
; 10(6): 1175-8, 2008 Mar 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-18293992
RESUMO
The scope of CCC-NHC pincer complex synthetic methodology by metalation/transmetalation has been extended to Ir. Structural characterization revealed that it is isomorphous with the Rh complex. Both Rh and Ir complexes are efficient catalysts for the hydroamination/cyclization of secondary amines in the presence of air and/or water.