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Analyst ; 134(10): 2118-22, 2009 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-19768223

RESUMO

This report presents the development of new selective gas sensors utilizing a b-oriented silicalite-1 layer-magneto-elastic ribbon assembly. The key principle for the operation of these sensors is monitoring the changes in the resonance frequency of the Metglas strip in relation to the concentration of a component in the gas phase. This technique provides a simple way for monitoring the effects of the amount of adsorbed gases in the silicalite-1 coating. The thickness of the zeolite layer is that of a single crystal. The silicalite-1 crystals are oriented in the b-direction, meaning that the straight channels are perpendicular to the sensor surface, which is confirmed by X-ray diffraction (XRD) analysis. The sensor was able to repeatedly sense carbon dioxide in air and could discriminate between linear and branched hydrocarbons. The sensor was able to detect n-butane, while it did not respond to the presence of iso-butane, indicating sensing selectivity.


Assuntos
Técnicas de Química Analítica/instrumentação , Magnetismo , Zeolitas/química , Elasticidade , Radicais Livres/química , Gases/análise , Gases/química , Membranas Artificiais , Microscopia Eletrônica de Varredura , Oxidantes/química , Oxigênio/química , Ozônio/química , Temperatura , Termogravimetria , Difração de Raios X
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