Magnetic graphene oxide based nano-composites for removal of radionuclides and metals from contaminated solutions.

Magnetic graphene oxide based composites of the nano-particle size of <10 nm were synthesized, characterized and used in sorption experiments. The adsorption of Cs(I), Co(II), Ni(II), Cu(II) and Pb(II) to nano-composites was studied in a wide range of initial concentrations and analyzed by Langmuir and Freundlich models. In addition, the effects of pH and coexisting ions on the adsorption of Cs to Prussian blue based composites were investigated. The maximum adsorption capacities of studied elements varied from 29 to 641 mg g-1. The obtained Langmuir and Freundlich constants indicated the dominating physisorption mechanism and favorable adsorption conditions.

Transport of (137)Cs, (241)Am and Pu isotopes in the Curonian Lagoon and the Baltic Sea.

Activities of (137)Cs, (241)Am and (239,240)Pu were analyzed with special emphasis on better understanding of radionuclide transport from land via the Neman River estuaries to the Baltic Sea and behavior in the marine environment. Although activity concentrations of (137)Cs in water samples collected the Baltic Sea were almost 100 times higher as compared to the Curonian Lagoon, its activities in the bottom sediments were found to be comparable. Activity (238)Pu/(239,240)Pu and atom (240)Pu/(239)Pu ratios indicated a different contribution of the Chernobyl-originated Pu to the suspended particulate matter (SPM) and bottom sediments. The largest amount of the Chernobyl-derived Pu was found in the smallest suspended matter particles of 0.2-1 µm in size collected in the Klaipeda Strait in 2011-2012. The decrease of characteristic activity (238)Pu/(239,240)Pu and atom (240)Pu/(239)Pu ratios towards the global fallout ones in surface soil and the corresponding increase of plutonium (Pu) ratios in the suspended particulate matter and bottom sediments have indicated that the Chernobyl-derived Pu, primarily deposited on the soil surface, was washed out and transported to the Baltic Sea. Behavior of (241)Am was found to be similar to that of Pu isotopes.