RESUMO
The distinctive and tuneable physical, chemical and configurational properties of carbon nanotubes (CNTs), has prompted their combination with metal oxides to contrive carbon composites showing entrancing adsorption property with incredible potential in water treatment. MWCNT/Alumina (RMAC) nodules with effective adsorption capacity were synthesized following aqueous sol-gel route. Batch sorption experiments examined the efficiency of removal of dyes and heavy metal ions from an aqueous solution on RMAC nodules. The factors affecting adsorption were studied for adsorption of methylene blue dye (MB) and hexavalent chromium by altering the MWCNT concentration from 1 wt.% to 5 wt.%. The adsorption experiment demonstrated an adsorption capacity of 187.5 and 597 mg g-1 at 25 °C for MB and Cr (VI) respectively. Various characterization techniques such as XRD, BET, TEM, Raman, FTIR, TPD and CHN were employed to study the initial development of the material. Multiple adsorption interaction mechanisms (electrostatic interactions, hydrogen bonding, π-π electron-donor-acceptor interactions) may be credited for the remarkable adsorption capacity of these nodules. Results of this work are of great significance for environmental applications of Alumina/MWCNT composite as a promising adsorbent nanomaterial for organic pollutants from aqueous solutions. Apart from high sorption ability, these nodules offer ease of separation with splendid regeneration ability.
RESUMO
E896 has measured Lambda production in 11.6A GeV/c Au-Au collisions over virtually the whole rapidity phase space. The midrapidity p(t) distributions have been measured for the first time at this energy and appear to indicate that the Lambda hyperons have different freeze-out conditions than protons. A comparison with the relativistic quantum molecular dynamics model shows that while there is good shape agreement at high rapidity the model predicts significantly different slopes of the m(t) spectra at midrapidity. The data, where overlap occurs, are consistent with previously reported measurements.
