The Effects of Bromine Additives on the Recyclability of Injection Molded Electronic Waste Polymers.

Excessive waste amounts, such as waste electrical and electronic equipment (WEEE) and plastic waste, have increased simultaneously with the development of society. Despite the increased material amounts, the recycling rates are too low and those have a great potential to contribute actions toward a circular economy. A certain restricted factor for recycling is the heterogenous nature of materials, such as WEEE-included additives. This study investigates the effects of a WEEE polymer including bromine on recycling ability, analyzing its physical and mechanical features. The study demonstrates that polymer sorting is profitable for WEEE polymers from the material qualitative perspective, because various processability and material features are achieved in the study between material categories, and especially unidentified polymers have the weakest features in the studied tests. The separation of bromine concentration is also recommended because bromine-free materials have more advanced features that can be confirmed by statistical analyses. The achieved results support the idea that novel circular economy actions have the potential for effective, efficient WEEE polymer recycling processes with technological innovations, especially when all variables (e.g., recycling cycles and process parameters) are observed and it enables an option to reduce the need for virgin plastic.

Esterified Lignin from Construction and Demolition Waste (CDW) as a Versatile Additive for Polylactic-Acid (PLA) Composites-The Effect of Artificial Weathering on its Performance.

Demand for sustainable packaging and building materials has increased the need for biobased additives. Biocomposites can often be exposed to different weather conditions and UV irradiation. Thus, additives to prevent the negative impact of weathering are generally added to composites. This study aims to evaluate using esterified lignin as an additive against weathering effects in polylactic-acid (PLA) composites. Lignin is extracted from construction and demolition waste (CDW) wood using a deep eutectic solvent then esterified and tested as an additive in the fabrication of bio-based composites. For comparison, lignin from birch is used as a raw material for an additive. Esterification is confirmed by solid-state NMR analysis. Samples are exposed to artificial weathering for 700 hours and their impact strength and color change properties are measured. The results indicate that esterified lignin from CDW (CDW e-lignin) as an additive protects the biocomposite from the weathering impact. The sample containing the CDW e-lignin as an additive suffers only a 4.3% of reduction of impact strength, while the samples that contain commercial additives lose clearly more of their impact strength (from 23.1% to 61.1%). Based on the results CDW e-lignin is a good additive to prevent weathering. As a conclusion, the esterified lignin from CDW, is a versatile additive for composite production.

Assessment of critical factors in waste electrical and electronic equipment (WEEE) plastics on the recyclability: A case study in Finland.

Excessive waste is continually accumulating owing to increased consumption, and an excellent example is the consumption of electrical and electronic equipment (EEE), which are eventually transformed into waste from electrical and electronic equipment (WEEE). WEEE is an interesting material stream because it includes various valuable materials that have great potential for recycling and reutilization. To maximize recycling and utilization potential, all fractions in WEEE must be reviewed from a sustainable perspective. Several WEEE contain plastic, which comprises approximately one-third of the total WEEE composition; thus, this plastic content is a good target for recycling purposes. However, the recycling of WEEE plastics might include some challenges, such as the treatment of harmful substances in the material, which can prevent effective and high-quality material recycling. This study investigates the polymer composition and critical elements of the material stream of WEEE polymer. These polymers were identified using portable near-infrared (NIR) spectroscopy and energy-dispersive X-ray spectroscopy (EDS) at an elemental level. The results showed that among various other polymers, acrylonitrile butadiene styrene (ABS) was the main polymer identified in WEEE. The proportion of unidentified polymers was alarmingly large; specifically, when the presence of bromine was positively correlated with the presence of an unidentified WEEE polymer. This study also corroborated that bromine is actually not present in bromine-free plastics, demonstrating that industrial classification works with WEEE polymers.

Re-Processing of Multilayer Plastic Materials as a Part of the Recycling Process: The Features of Processed Multilayer Materials.

The weight of packaging materials will be increased with advanced innovations, such as multilayer plastic. The consequence of the advanced innovations is challenges in the following reuse activities. This study aimed to investigate the properties of multilayer plastic materials after recycling processes and will increase the awareness of plastic packaging material for reuse options. In this research, the materials were produced from food packages by crushing them and treating them with injection molding equipment. The implementation of materials in the processing was tested, and the structural and mechanical characteristics of the produced plastic materials was evaluated and discussed. Based on the completed tests, plastic materials used in food packages have the clearest differences in the material features, for instance, the melt flow rate and elongation rate in the tensile test that varied between 2.96-48.4 g/10min and 2-289%, respectively. The variation in the characterizations ranged widely between the material structures. The results indicate that solid plastic packaging materials have better mechanical features compared to foil materials. The structural analysis of materials showed that multilayer plastic includes a wide spectrum of different elements within materials, creating a challenge for future recycling.

The Effect of Construction and Demolition Waste Plastic Fractions on Wood-Polymer Composite Properties.

Construction and demolition waste (CDW), including valuable materials such as plastics, have a remarkable influence on the waste sector. In order for plastic materials to be re-utilized, they must be identified and separated according to their polymer composition. In this study, the identification of these materials was performed using near-infrared spectroscopy (NIR), which identified material based on their physical-chemical properties. Advantages of the NIR method are a low environmental impact and rapid measurement (within a few seconds) in the spectral range of 1600-2400 nm without special sample preparation. Limitations include its inability to analyze dark materials. The identified polymers were utilized as a component for wood-polymer composite (WPC) that consists of a polymer matrix, low cost fillers, and additives. The components were first compounded with an agglomeration apparatus, followed by production by extrusion. In the agglomeration process, the aim was to compound all materials to produce uniformly distributed and granulated materials as pellets. During the agglomeration process, the polymer (matrix) was melted and fillers and other additives were then mixed into the melted polymer, being ready for the extrusion process. In the extrusion method, heat and shear forces were applied to a material within the barrel of a conical counter-rotating twin-screw type extruder, which reduces the risk of burning the materials and lower shear mixing. The heated and sheared mixture was then conveyed through a die to give the product the desired shape. The above-described protocol proved the potential for re-utilization of CDW materials. Functional properties must be verified according to the standardized tests, such as flexural, tensile, and impact strength tests for the material.

Composition of Plastic Fractions in Waste Streams: Toward More Efficient Recycling and Utilization.

Reuse of materials is a significant global goal that contributes to sustainable development. Polymer-specific plastic identification from the waste stream is examined in this study to achieve environmentally optimistic reuse of plastic material in secondary applications. Two diverse waste streams, 86.11 kg of construction and demolition waste (CDW) plastic and 57.74 kg of mechanically sorted plastic, were analyzed by using a handheld tool whose identification technology was based on the near-infrared spectrum. The study indicates a significant effect of human and single fraction on manual separation. The polymer composition in the plastic waste stream varied depending on the source, but the most common plastic grades, polypropylene (PP) and polyethylene (PE), were represented in every waste stream. The waste stream also included unidentified and unfavorable wastes, which indicates that identification of the plastic fractions is needed and more studies should be done in this field in the future.