Integrating adsorption and in situ advanced oxidation for the treatment of organic wastewater by 3D carbon aerogel embedded with Fe-doped carbonitrides.

Wastewater containing organic pollutants with high toxicity and poor biodegradability poses a considerable threat to human health and the ecosystem. Although adsorption and advanced oxidation processes (AOPs) are currently the most widely used technologies for wastewater treatment, limitations of these two independent processes make the treatment effect unsatisfactory. Herein, a system of integrating adsorption and subsequent in situ AOPs is established by a 3D carbon aerogel embedded with Fe-doped carbonitrides (Fe-NC/CAG). The SEM and BET analysis demonstrate that Fe-NC/CAG possesses porous structures with a specific surface area of 518.7 m2/g. The XRD result indicates the formation of Fe0 and Fe3O4 in Fe-NC/CAG. The impacts of operational parameters such as Fe-NC/CAG dosage, pollutants concentration, temperature, initial pH, and inorganic ions on the adsorption efficiency are investigated. The adsorption kinetics is predominantly based on the pseudo-second-order model. After adsorbing organic pollutants, the Fe-NC/CAG is immersed in peroxymonosulfate (PMS) solution. The adsorbed pollutants are in situ degraded by PMS-based AOPs, leading to the regeneration of Fe-NC/CAG. At optimum conditions, the integrating process established by Fe-NC/CAG achieves over 90% removal of antibiotics, phenolics, and dyes as well as keeps stable performance even after 6 cycles. This integrating adsorption and AOPs system is expected to open up a rich field for wastewater treatment.

Enhancing the anti-oxidation stability of vapor-crystallized arsenic crystals via introducing iodine.

The oxidation of arsenic restricts its application in high-performance electronic devices and functional materials. Herein, a removable iodine-regulation method was proposed for the first time to enhance the anti-oxidation behavior of arsenic. In a gradient of 500-650 â„ƒ, the introduction of 0.6-5.0 at% iodine into arsenic vapor could regulate an arsenic crystal. The oxygen content on the regulated arsenic crystal surface was lowered below 2.5 at% after exposure to ambient conditions for 96 h, reducing over 90% compared with the control group. The residual iodine barrier, which was mainly in the As-I2 state, suppressed the long-term oxidation of arsenic. First-principles calculation suggested that the adsorbed I2 weakened the delocalization of lone-pair electrons and inhibited charge transfer from the arsenic surface. Iodine regulation stabilized arsenic surface, which preferred (003) or (012) facets. Their surface energies were 22.4 meV and 47.6 meV, respectively. The synergistic effect of surface stabilization and I2 passivation lowered the surface energy and continuously slowed the oxidation of arsenic. Therefore, iodine regulation comprehensively enhanced the anti-oxidation properties of arsenic. Moreover, heating at 200 â„ƒ left the arsenic surface iodine content below 0.1 at% with little variation in structure. The improved anti-oxidation property of arsenic preserves resources for further advanced applications.

Complete Genome Sequence of a Halophilic Bacterium, Halomonas sp. Strain NyZ770, from Mariana Trench Sediment.

Halomonas sp. strain NyZ770 is a bacterium that was isolated from Mariana Trench sediment. Here, the complete genome sequence of this strain is reported. The genome was sequenced with the Illumina NovaSeq and Pacific Biosciences Sequel sequencing platforms and consists of a single chromosome of 4,024,853 bp, with a G+C content of 60.21%.

Streptomyces geranii sp. nov., a novel endophytic actinobacterium isolated from root of Geranium carolinianum L.

A novel endophytic actinomycete, designated A301T, was isolated from the root of Geranium carolinianum Linn collected from Mount Emei in China and characterized using a polyphasic approach. Growth occurred at 10-37 °C, pH 6-11 and in the presence of 0-5 % NaCl (w/v). Strain A301T contained ll-diaminopimelic acid as the diagnostic diamino acid in the cell-wall peptidoglycan. The whole-cell hydrolysates included galactose and ribose. The predominant menaquinones were MK-9(H6) and MK-9(H8). The major cellular fatty acids were C15 : 0, C16 :  0, anteiso-C15 : 0 and iso-C16 : 0. The polar lipid profile consisted of diphosphatidylglycerol, phosphatidylethanolamine, phosphatidylinositol, two unidentified phospholipids, three unidentified lipids and two unidentified aminophospholipids. Strain A301T shared the highest 16S rRNA gene sequence similarity to Streptomyces cinereorubersubsp. fructofermentans NBRC 15396T (98.1 %) and Streptomyces turgidiscabies ATCC 700248T (98.1 %). The DNA-DNA relatedness values between strain A301T and the two above-mentioned members of the genus Streptomyces were 42.6 % and 47.2 %, respectively. The G+C content of the DNA was 70.5 mol%. On the basis of the polyphasic approach and DNA-DNA hybridization data, strain A301T represents a novel species within the genus Streptomyces, for which the name Streptomyces geranii sp. nov. is proposed. The type strain is A301T (=CGMCC 4.7422T=JCM 32177T).