1.
Org Lett
; 14(8): 2134-7, 2012 Apr 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22494389
RESUMO
Fluoro-homoneplanocin A (4) was synthesized from d-ribose, via the enyne ring-closing metathesis of 9, the stereoselective opening of epoxide 23a with fluoride, and a simultaneous oxidation-elimination reaction. The key intermediate 8 is expected to serve as a versatile intermediate for the synthesis of carbanucleosides.