RESUMO
We uncover a novel phenomenon from a recent artificial light-harvesting experiment [P.-Z. Chen et al., Angew. Chem., Int. Ed. Engl. 55, 2759 (2016)ACIEAY0570-083310.1002/anie.201510503] on organic nanocrystals of self-assembled difluoroboron chromophores. A resonant confinement of a polariton under strong photon-exciton coupling is predicted to exist within the microcavity of the crystal's own natural boundaries. Moreover, the radiative energy of a localized exciton falls into the spectrum of confinement. Hence, in the experiment, the spontaneous emission of an excited pigment would undergo a two-step process. It should first decay to an excitonic polariton trapped by the cavity resonance. The intermediate polariton could then funnel the energy directly to a doped acceptor, leading to the over 90% transfer efficiency observed at less than 1/1000 acceptor/donor ratio. The proposed mechanism is supported by parameter-free analyses entirely based on experiment data. Our finding may imply possible polariton-mediated pathways for energy transfers in biological photosynthesis.
Assuntos
Modelos Químicos , Nanopartículas/química , Fotossíntese , Materiais Biomiméticos/química , Compostos de Boro/química , Transferência de Energia , Complexos de Proteínas Captadores de Luz/químicaRESUMO
Macroscopic realism is the name for a class of modifications to quantum theory that allow macroscopic objects to be described in a measurement-independent manner, while largely preserving a fully quantum mechanical description of the microscopic world. Objective collapse theories are examples which aim to solve the quantum measurement problem through modified dynamical laws. Whether such theories describe nature, however, is not known. Here we describe and implement an experimental protocol capable of constraining theories of this class, that is more noise tolerant and conceptually transparent than the original Leggett-Garg test. We implement the protocol in a superconducting flux qubit, and rule out (by â¼84 s.d.) those theories which would deny coherent superpositions of 170 nA currents over a â¼10 ns timescale. Further, we address the 'clumsiness loophole' by determining classical disturbance with control experiments. Our results constitute strong evidence for the superposition of states of nontrivial macroscopic distinctness.
RESUMO
Following a brief review of the "two-level (tunneling) systems" model of the low-temperature properties of amorphous solids ("glasses"), we ask whether it is in fact the unique explanation of these properties as is usually assumed, concluding that this is not necessarily the case. We point out that (a) one specific form of the model is already experimentally refuted and (b) that a definitive test of the model in its most general form, while not yet carried out, would appear to be now experimentally feasible.
RESUMO
We extend the Mermin-Wagner theorem to a system of lattice spins which are spin coupled to itinerant and interacting charge carriers. We use the Bogoliubov inequality to rigorously prove that neither (anti-) ferromagnetic nor helical long-range order is possible in one and two dimensions at any finite temperature. Our proof applies to a wide class of models including any form of electron-electron and single-electron interactions that are independent of spin. In the presence of Rashba or Dresselhaus spin-orbit interactions (SOI) magnetic order is not excluded and intimately connected to equilibrium spin currents. However, in the special case when Rashba and Dresselhaus SOIs are tuned to be equal, magnetic order is excluded again. This opens up a new possibility to control magnetism electrically.
RESUMO
We present a variational analysis for a half-quantum vortex (HQV) in the equal-spin-pairing superfluid state which, under suitable conditions, is believed to be realized in Sr(2)RuO(4) and (3)He-A. Our approach is based on a description of the HQV in terms of a BCS-like wave function with a spin-dependent boost. We predict a novel feature: the HQV, if stable, should be accompanied by a nonzero spin polarization. Such a spin polarization would exist in addition to the one induced by the Zeeman coupling to the external field and hence may serve as an indicator in experimental search for HQV.
RESUMO
The element helium comes in two (stable) forms, 4He and 3He; at low temperatures and pressures both form liquids rather than solids. The liquid phase of the common isotope, 4He, was realized nearly a century ago, and since 1938 has been known to show, at temperatures below about 2K, the property of superfluidity--the ability to flow through the narrowest capillaries without apparent friction. The light isotope, 3He, is believed to be of quite a different nature; however, because of its similarity to the electrons in metals, which at low temperatures sometimes form "Cooper pairs" and thereby become superconducting, theorists in the 1960s and early 1970s had speculated that something similar might happen in liquid 3He, which would then also show superfluidity though for reasons rather different than 4He. In 1972 nuclear magnetic resonance (NMR) experiments at Cornell University revealed the existence, below 3 millidegrees, if two new phases, one of which displayed extraordinary NMR properties. Anthony Leggett is one of the theorists who succeeded in fitting the experimental properties into the "Cooper-pairing" scenario; in particular, he explained the NMR behavior and predicted further novel NMR phenomena which were subsequently found.